At Lawrence Livermore National Laboratory, we are studying above ground oil shale retorting and have developed the LLNL Hot-Recycled-Solid (HRS) process as a generic second-generation, rapid pyrolysis retorting system in which recycled shale is the solid heat carrier. In 1984--1987, we operated a 1 tonne-per-day HRS pilot plant to study retorting chemistry in an actual recirculation loop. In 1989 we upgraded our laboratory pilot plant to process 4 tonne-per-day of commercially sized shale, allowing us, for the first time, to study pyrolysis and combustion using the full particle size. With the new facility we are able to produce enough oil for detailed characterization studies, can evaluate environmental consequences, and begin answering the many bulk solid handling questions concerning scale-up of the HRS process. In this paper we report on operations of our laboratory (4TU) pilot plant and plans for a field test unit (FTU) at approximately 100 tonne-per-day scale to be sited in the western United States. 3 refs., 11 figs.

Highlights of significant accomplishments for the Federal program are given as follows: leasing of Federal lands; resource identification, assessment, and exploration; hydrothermal industrialization; hydrothermal technology development; geopressured resources; hot dry rock resources; geosciences research; environment, Federal use of geothermal energy, international activities, program coordination, and state government activities.

The overall project objective is to demonstrate the high efficiency of the Adams Counter-Current shale oil recovery process. The efficiency will first be demonstrated on a small scale, in the current phase, after which the demonstration will be extended to the operation of a small pilot plant. Thus the immediate project objective is to obtain data on oil shale retorting operations in a small batch rotary kiln that will be representative of operations in the proposed continuous process pilot plant. Although an oil shale batch sample is sealed in the batch kiln from the start until the end of the run, the process conditions for the batch are the same as the conditions that an element of oil shale would encounter in a continuous process kiln. Similar chemical and physical conditions (heating, mixing, pyrolysis, oxidation) exist in both systems.The two most important data objectives in this phase of the project are to demonstrate (1) that the heat recovery projected for this project is reasonable and (2) that an oil shale kiln will run well and not plug up due to sticking and agglomeration. The following was completed this quarter. (1) Twelve pyrolysis runs were made on five different oil shales. …

This report consists of a group of slides describing the compact ignition tokamak (CIT). Several drawings present the layout of the facility. Concerns about radiation effects are mentioned. (JDH)

This report, from the Chemical Processing Department at HAPO, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations; facilities engineering; research; and employee relations.

The simplest explanation for these shifts in the infrared spectra is there exists in coal single electron donors which are capable of transferring an electron to TCNQ in the ground state. All of the TCNQ placed in the coal appears to be converted to the radical anion as displayed in the IR spectrum for all of the coals except for the 100% loading.

This study started on 1 June 1989 and ended 14 November 1991. Two moored in situ natural fluorometers were deployed in January 1990 to collect bio-optical data for one year, making ground truth measurements around the mooring during 4 cruises. This one-year time series would investigate how the short-term physical forcing aliases the long-term primary production record such that the apparent, larger interannual variability in the record is in reality ``noise`` due to short-term fluctuations in the rate of nutrient input to the euphotic zone. These continuous measurements from moored bio-optical instruments would also allow better estimates of the mean and variance in primary production in these waters than has previously been available from shipboard measurements, as well as, phytoplankton response to short-term physical events. Ancillary measurements that were made were: (1) characterization of the apparent and inherent optical properties, (2) photosynthetic pigment distributions using both HPLC and standard fluorometric methods, (3) carbon, hydrogen and nitrogen content of suspended particulate matter, (4) primary production using conventional {sup 14}C methods from simulated in situ experiments.

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The In-Tank Precipitation process (ITP) receives High Level Waste (HLW) supernatant liquid containing radionuclides in waste processing tank 48H. Sodium tetraphenylborate, NaTPB, and monosodium titanate (MST), NaTi{sub 2}O{sub 5}H, are added for removal of radioactive Cs and Sr, respectively. In addition to removal of radio-strontium, MST will also remove plutonium and uranium. The majority of the feed solutions to ITP will come from the dissolution of supernate that had been concentrated by evaporation to a crystallized salt form, commonly referred to as saltcake. The concern for criticality safety arises from the adsorption of U and Pt onto MST. If sufficient mass and optimum conditions are achieved then criticality is credible. The concentration of u and Pt from solution into the smaller volume of precipitate represents a concern for criticality. This report supplements WSRC-TR-93-171, Nuclear Criticality Safety Bounding Analysis For The In-Tank-Precipitation (ITP) Process. Criticality safety in ITP can be analyzed by two bounding conditions: (1) the minimum safe ratio of MST to fissionable material and (2) the maximum fissionable material adsorption capacity of the MST. Calculations have provided the first bounding condition and experimental analysis has established the second. This report combines these conditions with canyon facility data to evaluate …

This ICERVS Phase II Subsystem Design Report describes the detailed software design of the Phase II Interactive Computer-Enhanced Remote Viewing System (ICERVS). ICERVS is a computer-based system that provides data acquisition, data visualization, data analysis, and model synthesis to support robotic remediation of hazardous environments. Due to the risks associated with hazardous environments, remediation must be conducted remotely using robotic systems, which, in turn, must rely on 3D models of their workspace to support both task and path planning with collision avoidance. Tools such as ICERVS are vital to accomplish remediation tasks in a safe, efficient manner. The 3D models used by robotic systems are based on solid modeling methods, in which objects are represented by enclosing surfaces (polygons, quadric surfaces, patches, etc.) or collections of primitive solids (cubes, cylinders, etc.). In general, these 3D models must be created and/or verified by actual measurements made in the robotics workspace. However, measurement data is empirical in nature, with typical output being a collection of xyz triplets that represent sample points on some surface(s) in the workspace. As such, empirical data cannot be readily analyzed in terms of geometric representations used in robotic workspace models. The primary objective of ICERVS is to …

This document provides a discussion of the technical progress on DOE-PETC Project Number AC22-92PC91338, ``High Efficiency SO{sub 2} Removal Testing,`` for the time period from January 1 through March 31, 1993. The project involves testing at full-scale utility flue gas desulfurization (FGD) systems to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO{sub 2} removal efficiency. The options to be evaluated primarily involve the addition of organic acid buffers to the FGD systems. The ``base`` project involves testing at one site, Tampa Electric Company`s Big Bend Station. Up to five optional sites may be added to the program at the discretion of DOE-PETC. By March 31, 1993, four of those five options had been exercised. The options include testing at Hoosier Energy`s Merom Station (Option I), Southwestern Electric Power Company`s (SWEPCo) Pirkey Station (Option II), PSI Energy`s Gibson Station (Option III), and Duquesne Light`s Elrama Station (Option IV). The remainder of this document is divided into three sections. Section 2, Project Summary, provides a brief overview of the technical efforts on this project during the quarter. Section 3, Results, summarizes the outcome of those technical efforts. Results for the Base Program and for …

This report summarizes the results of ABLE`s design study of the FORTE deployable log periodic antenna. The resulting Baseline Design of the antenna is the basis for ABLE`s proposal for Phase II of this program. ABLE`s approach to meeting the requirements is to use a coilable ABLE mast as the deployable structure ``backbone`` of the antenna and to use deployable tubes for. the log periodic dipole elements of the antenna. This general approach was adopted at the outset of the Phase I Design Study. The remainder of the study was devoted to detailed design and analysis to properly size these types of mast and antenna elements and to design their deployment mechanisms. Demonstration models of the mast and antenna element deployer were fabricated as part of Phase I study. The study showed that ABLE`s design approach is feasible and can meet all the specified design requirements except the mass limit of 13.5 kg. Results of the design and analysis studies are summarized in this report. The mast and dipole element deployer are to be demonstrated to LANL personnel at the conclusion of this Phase I study.

The objective of this project is to develop a comprehensive, interdisciplinary, quantitative characterization of a fluvial-deltaic reservoir which will allow realistic interwell and reservoir-scale modeling to be used for improved oil-field development in similar reservoirs world wide. The geological and petrophysical properties of the Cretaceous Ferron Sandstone in east-central Utah will be quantitatively determined. Both new and existing data will be integrated into a 3-D representation of spatial variations in porosity, storativity, and tensorial rock permeability at a scale appropriate for interwell to regional-scale reservoir simulation. Results could improve reservoir management through proper infill and extension drilling strategies, reduce economic risks, increase recovery from existing oil fields, and provide more reliable reserve calculations. Transfer of the project results to the petroleum industry will be an integral component of the project. The technical progress is divided into several sections corresponding to subtasks outlined in the Regional Stratigraphy Task and the Case Studies Task of the original proposal. The primary objective of the Regional Stratigraphy Task is to provide a more detailed interpretation of the stratigraphy of the Ferron Sandstone outcrop belt from Last Chance Creek to Ferron Creek. The morphological framework established from the case studies will be used to generate …

Sierra Energy Company, in consultation with Rim Companies, concluded that additional work was required for Subtask 2.1.4 -- Interpret data, of Task 2.1 - Acquire 3-D seismic data. The goal of this subtask was to interpret the 3-D seismic data, using a workstation, in order to locate the surface and subsurface positions for the slant and horizontal wellbores. Although this goal had been reached, more work was needed for plotting maps and seismic sections. Furthermore, it was determined that an additional look at the amplitude distribution in the Frontier sands would greatly benefit the interpretation.

The effectiveness of the product and process control strategies that will be utilized by the Defense Waste Processing Facility (DWPF) was demonstrated during a campaign in the Shielded Cells Facility (SCF) of the Savannah River Technology Center (SRTC). The remotely operated process included the preparation of the melter feed, vitrification in a slurry-fed 1/100th scale melter and analysis of the glass product both for its composition and durability. The campaign processed approximately 10 kg (on a dry basis) of radioactive sludge from Tank 51. This sludge is representative of the first batch of sludge that will be sent to the DWPF for immobilization into borosilicate glass. Additions to the sludge were made based on calculations using the Product Composition Control System (PCCS). Analysis of the glass produced during the campaign showed that a durable glass was produced with a composition similar to that predicted using the PCCS.

The tests conducted on the /sup 1///sub 5/-scale BWR Mark I pressure suppression test facility simulate the three-dimensional transient conditions that are encountered in a wetwell pressure suppression system during a hypothetical loss-of-coolant accident (LOCA). Specifically, the nitrogen (N/sub 2/)-driven air clearing phase tests discussed were performed to obtain the air/water-induced dynamic vertical load function and to determine the response of a 90/sup 0/ sector of a 360/sup 0/ torus structure.

The authors present the results from an analysis of Hubble Space Telescope High Resolution Camera data for the Large Magellanic Cloud microlensing event MACHO-LMC-5. By determining the parallax and proper motion of this object they find that the lens is an M dwarf star at a distance of 578{sub -53}{sup +65}pc with a proper motion of 21.39 {+-} 0.04 mas/yr. Based on the kinematics and location of this star is it more likely to be part of the Galactic thick disk than thin disk population. They confirm that the microlensing event LMC-5 is a jerk-parallax microlensing event.

The technique of accelerator mass spectrometry (AMS) was validated successfully and utilized to study the pharmacokinetics and disposition in dogs of a preclinical drug candidate (Compound A), after oral and intravenous administration. The primary objective of this study was to examine whether Compound A displayed linear kinetics across sub-pharmacological (microdose) and pharmacological dose ranges in an animal model, prior to initiation of a human microdose study. The AMS-derived disposition properties of Compound A were comparable to data obtained via conventional techniques such as LC-MS/MS and liquid scintillation counting analyses. Thus, Compound A displayed multiphasic kinetics and possessed low plasma clearance (4.4 mL/min/kg), a long terminal elimination half-life (19.4 hr) and high oral bioavailability (82%). Currently there are no published comparisons of the kinetics of a pharmaceutical compound at pharmacological versus sub-pharmacological doses employing microdosing strategies. The present study thus provides the first description of the pharmacokinetics of a drug candidate assessed under these two dosing regimens. The data demonstrated that the pharmacokinetic properties of Compound A were similar following dosing at 0.02 mg/kg as at 1 mg/kg, indicating that in the case of Compound A, the kinetics of absorption, distribution and elimination in the dog appear to be linear across …

In this paper we use numerical simulation to investigate shock-induced ignition and combustion of a hydrocarbon gas. The focus of this paper is on quantifying the effect of fidelity in the chemical kinetics on the overall solution. We model the system using the compressible Navier Stokes equations for a reacting mixture. These equations express conservation of species mass, momentum, total energy.

The U.S Linear Collider Detector R&D program, supported by the DOE and NSF umbrella grants to the University of Oregon, made significant advances on many critical aspects of the ILC detector program. Progress advanced on vertex detector sensor development, silicon and TPC tracking, calorimetry on candidate technologies, and muon detection, as well as on beamline measurements of luminosity, energy, and polarization.

A computer-assisted chemical modeling study of equilibria in flowing brine systems has been undertaken. Equilibria between liquid and volatile components of two-phase fluids have profound effects on such important phenomena as corrosion, scale formation, environmental quality, and the economics of energy extraction. The principal reactions considered are those involving volatiles naturally present in the fluid, including NH/sub 3/, H/sub 2/S and CO/sub 2/. A computer code is described which performs stepwise equilibrium computations at 1/sup 0/C intervals for a unit mass of fluid, between reservoir and reinjection temperatures. The data base used is the quality-temperature function for the brine, the chemical composition, and equilibrium constants for the solubility reactions of gases and dissociation of their aqueous species. Chemical changes that take place during cooling and expansion are illustrated by distribution diagrams. Although the computations were developed for application to the high-saline resource, they are not fluid or system-specific, and should be of general usefulness where a chemical composition and temperature history can be specified.

The effectiveness of the product and process control strategies that will be utilized by the Defense Waste Processing Facility (DWPF) was demonstrated during a campaign in the Shielded Cells Facility (SCF) of the Savannah River Technology Center (SRTC). The remotely operated process included the preparation of the melter feed, vitrification in a slurry-fed 1/100th scale melter and analysis of the glass product both for its composition and durability. The campaign processed approximately 10 kg (on a dry basis) of radioactive sludge from Tank 51. This sludge is representative of the first batch of sludge that will be sent to the DWPF for immobilization into borosilicate glass. Additions to the sludge were made based on calculations using the Product Composition Control System (PCCS). Analysis of the glass produced during the campaign showed that a durable glass was produced with a composition similar to that predicted using the PCCS.

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A TRACE/PARCS input model has been developed in order to be able to analyze anticipated transients without scram (ATWS) in a boiling water reactor. The model is based on one developed previously for the Browns Ferry reactor for doing loss-of-coolant accident analysis. This model was updated by adding the control systems needed for ATWS and a core model using PARCS. The control systems were based on models previously developed for the TRAC-B code. The PARCS model is based on information (e.g., exposure and moderator density (void) history distributions) obtained from General Electric Hitachi and cross sections for GE14 fuel obtained from an independent source. The model is able to calculate an ATWS, initiated by the closure of main steam isolation valves, with recirculation pump trip, water level control, injection of borated water from the standby liquid control system and actuation of the automatic depres-surization system. The model is not considered complete and recommendations are made on how it should be improved.