Search for Second-Class Currents in tau- -> omega.pi-.nu_tau (open access)

Search for Second-Class Currents in tau- -> omega.pi-.nu_tau

We report an analysis of {tau}{sup -} decaying into {omega}{pi}{sup -} {nu}{sub {tau}} with {omega} {yields} {pi}{sup +}{pi}{sup -}{pi}{sup 0} using a data sample containing nearly 320 million {tau} pairs collected with the BABAR detector at the PEP-II B-Factory. We find no evidence for second-class currents and we set an upper limit of 0.69% at 90% confidence level for the fraction of second-class currents in this decay mode.
Date: April 22, 2009
Creator: Aubert, B.
System: The UNT Digital Library
Decamethylytterbocene Complexes of Bipyridines and Diazabutadienes: Multiconfigurational Ground States and Open-Shell Singlet Formation (open access)

Decamethylytterbocene Complexes of Bipyridines and Diazabutadienes: Multiconfigurational Ground States and Open-Shell Singlet Formation

Partial ytterbium f-orbital occupancy (i.e., intermediate valence) and open-shell singlet formation are established for a variety of bipyridine and diazabutadiene adducts with decamethylytterbocene, (C5Me5)2Yb, abbreviated as Cp*2Yb. Data used to support this claim include ytterbium valence measurements using Yb LIII-edge X-ray absorption near-edge structure spectroscopy, magnetic susceptibility, and complete active space self-consistent field (CASSCF) multiconfigurational calculations, as well as structural measurements compared to density functional theory calculations. The CASSCF calculations indicate that the intermediate valence is the result of a multiconfigurational ground-state wave function that has both an open-shell singlet f13(?*)1, where pi* is the lowest unoccupied molecular orbital of the bipyridine or dpiazabutadiene ligands, and a closed-shell singlet f14 component. A number of other competing theories for the unusual magnetism in these materials are ruled out by the lack of temperature dependence of the measured intermediate valence. These results have implications for understanding chemical bonding not only in organolanthanide complexes but also for f-element chemistry in general, as well as understanding magnetic interactions in nanoparticles and devices.
Date: April 22, 2009
Creator: Booth, Corwin H.; Walter, Marc D.; Kazhdan, Daniel; Hu, Yung-Jin; Lukens, Wayne W.; Bauer, Eric D. et al.
System: The UNT Digital Library
Importance of Plasma Response to Non-axisymmetric Perturbations in Tokamaks (open access)

Importance of Plasma Response to Non-axisymmetric Perturbations in Tokamaks

Tokamaks are sensitive to deviations from axisymmetry as small as δB=B0 ~ 10-4. These non-axisymmetric perturbations greatly modify plasma confinement and performance by either destroying magnetic surfaces with subsequent locking or deforming magnetic surfaces with associated non-ambipolar transport. The Ideal Perturbed Equilibrium Code (IPEC) calculates ideal perturbed equilibria and provides important basis for understanding the sensitivity of tokamak plasmas to perturbations. IPEC calculations indicate that the ideal plasma response, or equiva- lently the effect by ideally perturbed plasma currents, is essential to explain locking experiments on National Spherical Torus eXperiment (NSTX) and DIII-D. The ideal plasma response is also important for Neoclassical Toroidal Viscosity (NTV) in non-ambipolar transport. The consistency between NTV theory and magnetic braking experiments on NSTX and DIII-D can be improved when the variation in the field strength in IPEC is coupled with generalized NTV theory. These plasma response effects will be compared with the previous vacuum superpositions to illustrate the importance. However, plasma response based on ideal perturbed equilibria is still not suffciently accurate to predict the details of NTV transport, and can be inconsistent when currents associated with a toroidal torque become comparable to ideal perturbed currents.
Date: April 22, 2009
Creator: Jong-kyu Park, Allen H. Boozer, Jonathan E. Menard, Andrea M. Garofalo, Michael J. Schaffer, Richard J. Hawryluk, Stanley M. Kaye, Stefan P. Gerhardt, Steve A. Sabbagh, and the NSTX Team
System: The UNT Digital Library
Bounding CKM Mixing with a Fourth Family (open access)

Bounding CKM Mixing with a Fourth Family

CKM mixing between third family quarks and a possible fourth family is constrained by global fits to the precision electroweak data. The dominant constraint is from nondecoupling oblique corrections rather than the vertex correction to Z {yields} {bar b}b used in previous analyses. The possibility of large mixing suggested by some recent analyses of FCNC processes is excluded, but 3-4 mixing of the same order as the Cabbibo mixing of the first two families is allowed.
Date: April 22, 2009
Creator: Chanowitz, Michael S.
System: The UNT Digital Library
Little Supersymmetry and the Supersymmetric Little Hierarchy Problem (open access)

Little Supersymmetry and the Supersymmetric Little Hierarchy Problem

The current experimental lower bound on the Higgs mass significantly restricts the allowed parameter space in most realistic supersymmetric models, with the consequence that these models exhibit significant fine-tuning. We propose a solution to this `supersymmetric little hierarchy problem'. We consider scenarios where the stop masses are relatively heavy - in the 500 GeV to a TeV range. Radiative stability of the Higgs soft mass against quantum corrections from the top quark Yukawa coupling is achieved by imposing a global SU(3) symmetry on this interaction. This global symmetry is only approximate - it is not respected by the gauge interactions. A subgroup of the global symmetry is gauged by the familiar SU(2) of the Standard Model. The physical Higgs is significantly lighter than the other scalars because it is the pseudo-Goldstone boson associated with the breaking of this symmetry. Radiative corrections to the Higgs potential naturally lead to the right pattern of gauge and global symmetry breaking. We show that both the gauge and global symmetries can be embedded into a single SU(6) grand unifying group, thereby maintaining the prediction of gauge coupling unification. Among the firm predictions of this class of models are new states with the quantum numbers …
Date: April 22, 2004
Creator: Birkedal, Andreas; Chacko, Z. & Gaillard, Mary K.
System: The UNT Digital Library
Local structure and site occupancy of Cd and Hg substitutions in CeTIn_5 (T=Co, Rh, Ir) (open access)

Local structure and site occupancy of Cd and Hg substitutions in CeTIn_5 (T=Co, Rh, Ir)

The CeTIn_5 superconductors (T=Co, Rh, or Ir) have generated great interest due to their relatively high transition temperatures, non-Fermi liquid behavior, and their proximity to antiferromagnetic order and quantum critical points. In contrast to small changes with the T-species, electron doping in CeT(In_1-x M_x)_5 with $M$=Sn and hole doping with Cd or Hg have a dramatic effect on the electronic properties at very low concentrations. The present work reports local structure measurements usingthe extended x-ray absorption fine-structure (EXAFS) technique that address the substituent atom distribution as a function of T, M, and x, in the vicinity of the superconducting phase. Together with previous measurements for M=Sn, the proportion of the $M$ atom residing on the In(1) site, f_\textrm In(1), increases in the order M=Cd, Sn, and Hg, ranging from about 40\percent to 70percent, showing a strong preference for each of these substituents to occupy the In(1) site (random occupation = 20percent). In addition, f_In(1) ranges from 70percent to 100percent for M=Hg in the order T=Co,Rh, and Ir. These fractions track the changes in the atomic radii of the various species, and help explain the sharp dependence of $T_c$ on substituting into the In site. However, it is difficult to reconcile …
Date: April 22, 2009
Creator: Booth, Corwin H.; Bauer, Eric. D.; Bianchi, Andrea D.; Ronning, Fillip; Thompson, Joe D.; Sarrao, John L. et al.
System: The UNT Digital Library
The Influence of Linker Geometry on Uranyl Complexation by Rigidly-Linked Bis(3-hydroxy-N-methyl-pyridin-2-one) (open access)

The Influence of Linker Geometry on Uranyl Complexation by Rigidly-Linked Bis(3-hydroxy-N-methyl-pyridin-2-one)

A series of bis(3-hydroxy-N-methyl-pyridin-2-one) ligands was synthesized, and their respective uranyl complexes were characterized by single crystal X-ray diffraction analyses. These structures were inspected for high-energy conformations and evaluated using a series of metrics to measure co-planarity of chelating moieties with each other and the uranyl coordination plane, as well as to measure coordinative crowding about the uranyl dication. Both very short (ethyl, 3,4-thiophene and o-phenylene) and very long ({alpha},{alpha}{prime}-m-xylene and 1,8-fluorene) linkers provide optimal ligand geometries about the uranyl cation, resulting in planar, unstrained molecular arrangements. The planarity of the rigid linkers also suggests there is a degree of pre-organization for a planar coordination mode that is ideal for uranyl-selective ligand design. Comparison of intramolecular N{sub amide}-O{sub phenolate} distances and {sup 1}H NMR chemical shifts of amide protons supports earlier results that short linkers provide the optimal geometry for intramolecular hydrogen bonding.
Date: April 22, 2010
Creator: Szigethy, Geza & Raymond, Kenneth
System: The UNT Digital Library
Epithermal Neutron Source for Neutron Resonance Spectroscopy (NRS) using High Intensity, Short Pulse Lasers (open access)

Epithermal Neutron Source for Neutron Resonance Spectroscopy (NRS) using High Intensity, Short Pulse Lasers

A neutron source for neutron resonance spectroscopy (NRS) has been developed using high intensity, short pulse lasers. This measurement technique will allow for robust measurements of interior ion temperature of laser-shocked materials and provide insight into equation of state (EOS) measurements. The neutron generation technique uses protons accelerated by lasers off of Cu foils to create neutrons in LiF, through (p,n) reactions with {sup 7}Li and {sup 19}F. The distribution of the incident proton beam has been diagnosed using radiochromic film (RCF). This distribution is used as the input for a (p,n) neturon prediction code which is compared to experimentally measured neutron yields. From this calculation, a total fluence of 1.8 x 10{sup 9} neutrons is infered, which is shown to be a reasonable amount for NRS temperature measurement.
Date: April 22, 2010
Creator: Higginson, D. P.; McNaney, J. M.; Swift, D. C.; Bartal, T.; Hey, D. S.; Pape, S. L. et al.
System: The UNT Digital Library
Parallelizing Heavyweight Debugging Tools with MPIecho (open access)

Parallelizing Heavyweight Debugging Tools with MPIecho

None
Date: April 22, 2011
Creator: Rountree, B L; Cobb, G X; Gamblin, G T; Schulz, M W; de Supinski, B R & Tufo, H M
System: The UNT Digital Library
NEXT GENERATION SOLAR COLLECTORS FOR CSP (open access)

NEXT GENERATION SOLAR COLLECTORS FOR CSP

ADVANCED REFLECTIVE FILMS AND PANELS FOR NEXT GENERATION SOLAR COLLECTORS
Date: April 22, 2013
Creator: Molnar, Attila & O'Neill, Mark
System: The UNT Digital Library
Fermi Large Area Telescope Observations of the Active Galaxy 4C 55.17: Steady, Hard Gamma-Ray Emission and its Implications (open access)

Fermi Large Area Telescope Observations of the Active Galaxy 4C 55.17: Steady, Hard Gamma-Ray Emission and its Implications

None
Date: April 22, 2013
Creator: McConville, W.; Ostorero, L.; Moderski, R.; Stawarz, L.; Cheung, C. C.; Ajello, M. et al.
System: The UNT Digital Library
Extension of the Empire Code to the Resonance Region (open access)

Extension of the Empire Code to the Resonance Region

The preliminary version of a new module has been developed to be added to a nuclear reaction model code EMPIRE to allow for an evaluation of neutron cross sections in a resonance region. It automates most of the evaluation procedures and can be executed within EMPIRE or as a stand-alone program. The module includes a graphic user interface (GUI) and a number of codes and scripts that read individual, as well as average, resonance parameters from the Atlas of Neutron Resonances and other physical constants from RIPL-2, perform an analysis of the available resonances, carry out statistical distributions, and compute cross sections in resolved and unresolved resonance regions which are then compared with experimental data. The module also provides an ENDF-formatted file for a resonance region and various plots allowing for a verification of the procedure. The formatted file can be integrated later into the final ENDF-6 file as generated by the EMPIRE code. However, as a preliminary version, extensive testing and further improvements are needed before this new capability can be incorporated into the production version of EMPIRE.
Date: April 22, 2007
Creator: Cho, Y. S.; Herman, M.; Mughabghab, S. F.; Oblozinsky, P.; Rochman, D. & Lee, Y. O.
System: The UNT Digital Library
NEW ENDF/B-VII.0 LIBRARY (open access)

NEW ENDF/B-VII.0 LIBRARY

We describe the new version of the Evaluated Nuclear Data File, ENDF/B-VII.0, of recommended nuclear data for advanced nuclear science and technology applications. The library, produced by the U.S. Cross Section Evaluation Working Group, was released in December 2006. The library contains data in 14 sublibraries, primarily for reactions with incident neutrons, protons and photons, based on the experimental data and nuclear reaction theory predictions. The neutron reaction sublibrary contains data for 393 materials. The new library was extensively tested and shows considerable improvements over the earlier ENDF/B-VI.8 library.
Date: April 22, 2007
Creator: OBLOZINSKY,P.
System: The UNT Digital Library
NUCLEAR DATA NEEDS FOR ADVANCED REACTOR SYSTEMS. A NEA NUCLEAR SCIENCE COMMITTEE INITIATIVE. (open access)

NUCLEAR DATA NEEDS FOR ADVANCED REACTOR SYSTEMS. A NEA NUCLEAR SCIENCE COMMITTEE INITIATIVE.

The Working Party on Evaluation Cooperation (WPEC) of the OECD Nuclear Energy Agency Nuclear Science Committee has established an International Subgroup to perform an activity in order to develop a systematic approach to define data needs for Gen-IV and, in general, for advanced reactor systems. A methodology, based on sensitivity analysis has been agreed and representative core configurations for Sodium, Gas and Lead cooled Fast Reactors (SFR, GFR, LFR) have been defined as well as a high burn-up VHTR and a high burn-up PWR. In the case of SFRs, both a TRU burner (called in fact SFR) and a core configuration with homogeneous recycling of not separated TRU (called EFR) have been considered.
Date: April 22, 2007
Creator: SALVATORES,J.M.; ALIBERTI, G.; PALMIOTTI, G.; ROCHMAN, D.; OBLOZINSKY, P.; HERMANN, M. et al.
System: The UNT Digital Library
The Aims and Activities of the International Network of Nuclear Structure and Decay Data Evaluators. (open access)

The Aims and Activities of the International Network of Nuclear Structure and Decay Data Evaluators.

International Network of Nuclear Structure and Decay Data (NSDD) Evaluators consists of a number of evaluation groups and data service centers in several countries that appreciate the merits of working together to maintain and ensure the quality and comprehensive content of the ENSDF database (Evaluated Nuclear Structure Data File). Biennial meetings of the network are held under the auspices of the International Atomic Energy Agency (IAEA) to assign evaluation responsibilities, monitor progress, discuss improvements and emerging difficulties, and agree on actions to be undertaken by individual members. The evaluated data and bibliographic details are made available to users via various media, such as the journals ''Nuclear Physics A'' and ''Nuclear Data Sheets'', the World Wide Web, on CD-ROM, wall charts of the nuclides and ''Nuclear Wallet Cards''. While the ENSDF master database is maintained by the US National Nuclear Data Center at the Brookhaven National Laboratory, these data are also available from other nuclear data centers including the IAEA Nuclear Data Section. The Abdus Salam International Centre for Theoretical Physics (ICTP), Trieste, Italy, in cooperation with the IAEA, organizes workshops on NSDD at regular intervals. The primary aims of these particular workshops are to provide hands-on training in the data …
Date: April 22, 2007
Creator: Nichols, A. L. & Tuli, J. K.
System: The UNT Digital Library
DEFORMATION DEPENDENT TUL MULTI-STEP DIRECT MODEL (open access)

DEFORMATION DEPENDENT TUL MULTI-STEP DIRECT MODEL

The Multi-Step Direct (MSD) module TRISTAN in the nuclear reaction code EMPIRE has been extended in order to account for nuclear deformation. The new formalism was tested in calculations of neutron emission spectra emitted from the {sup 232}Th(n,xn) reaction. These calculations include vibration-rotational Coupled Channels (CC) for the inelastic scattering to low-lying collective levels, ''deformed'' MSD with quadrupole deformation for inelastic scattering to the continuum, Multi-Step Compound (MSC) and Hauser-Feshbach with advanced treatment of the fission channel. Prompt fission neutrons were also calculated. The comparison with experimental data shows clear improvement over the ''spherical'' MSD calculations and JEFF-3.1 and JENDL-3.3 evaluations.
Date: April 22, 2007
Creator: WIENKE,H.; CAPOTE, R.; HERMAN, M. & SIN, M.
System: The UNT Digital Library
Hydromechanical modeling of pulse tests that measure both fluidpressure and fracture-normal displacement of the Coaraze Laboratory site,France (open access)

Hydromechanical modeling of pulse tests that measure both fluidpressure and fracture-normal displacement of the Coaraze Laboratory site,France

In situ fracture mechanical deformation and fluid flowinteractions are investigated through a series of hydraulic pulseinjection tests, using specialized borehole equipment that cansimultaneously measure fluid pressure and fracture displacements. Thetests were conducted in two horizontal boreholes spaced one meter apartvertically and intersecting a near-vertical highly permeable faultlocated within a shallow fractured carbonate rock. The field data wereevaluated by conducting a series of coupled hydromechanical numericalanalyses, using both distinct-element and finite-element modelingtechniques and both two- and three-dimensional model representations thatcan incorporate various complexities in fracture network geometry. Oneunique feature of these pulse injection experiments is that the entiretest cycle, both the initial pressure increase and subsequent pressurefall-off, is carefully monitored and used for the evaluation of the insitu hydromechanical behavior. Field test data are evaluated by plottingfracture normal displacement as a function of fluid pressure, measured atthe same borehole. The resulting normal displacement-versus-pressurecurves show a characteristic loop, in which the paths for loading(pressure increase) and unloading (pressure decrease) are different. Bymatching this characteristic loop behavior, the fracture normal stiffnessand an equivalent stiffness (Young's modulus) of the surrounding rockmass can be back-calculated. Evaluation of the field tests by couplednumerical hydromechanical modeling shows that initial fracture hydraulicaperture and normal stiffness vary by a …
Date: April 22, 2006
Creator: Cappa, F.; Guglielmi, Y.; Rutqvist, J.; Tsang, C-F. & Thoraval, A.
System: The UNT Digital Library
New Endf/B-Vii.0 Evaluations of Neutron Cross Sections for 32 Fission Products. (open access)

New Endf/B-Vii.0 Evaluations of Neutron Cross Sections for 32 Fission Products.

Neutron cross sections for fission products play important role not only in the design of extended burnup core and fast reactors, but also in the study of the backend fuel cycle and the criticality analysis of spent fuel. New evaluations in both the resonance and fast neutron regions were performed by the KAERI-BNL collaboration for 32 fission products. These were {sup 95}Mo, {sup 101}Ru, {sup 103}Rh, {sup 105}Pd, {sup 109}Ag, {sup 131}Xe, {sup 133}Cs, {sup 141}Pr, and complete isotope chains of {sup 142-148,150}Nd, {sup 144,147,148-154}Sm, and {sup 156,158,160-164}Dy. The evaluations cover a large amount of reaction channels, including all those needed for neutronics calculations. Also, they cover the entire energy range, from 10{sup -5} eV to 20 MeV, including the thermal, resolved, and unresolved resonance regions, and the fast neutron region.
Date: April 22, 2007
Creator: Kim, H.; Lee, Y. O.; Herman, M.; Mughabghab, S. F.; Oblozinsky, P. & Rochman, D.
System: The UNT Digital Library
EXTENSION OF THE NUCLEAR REACTION MODEL CODE EMPIRE TO ACTINIDES NUCLEAR DATA EVALUATION. (open access)

EXTENSION OF THE NUCLEAR REACTION MODEL CODE EMPIRE TO ACTINIDES NUCLEAR DATA EVALUATION.

Recent extensions and improvements of the EMPIRE code system are outlined. They add new capabilities to the code, such as prompt fission neutron spectra calculations using Hauser-Feshbach plus pre-equilibrium pre-fission spectra, cross section covariance matrix calculations by Monte Carlo method, fitting of optical model parameters, extended set of optical model potentials including new dispersive coupled channel potentials, parity-dependent level densities and transmission through numerically defined fission barriers. These features, along with improved and validated ENDF formatting, exclusive/inclusive spectra, and recoils make the current EMPIRE release a complete and well validated tool for evaluation of nuclear data at incident energies above the resonance region. The current EMPIRE release has been used in evaluations of neutron induced reaction files for {sup 232}Th and {sup 231,233}Pa nuclei in the fast neutron region at IAEA. Triple-humped fission barriers and exclusive pre-fission neutron spectra were considered for the fission data evaluation. Total, fission, capture and neutron emission cross section, average resonance parameters and angular distributions of neutron scattering are in excellent agreement with the available experimental data.
Date: April 22, 2007
Creator: CAPOTE,R.; SIN, M.; TRKOV, A.; HERMAN, M.; CARLSON, B.V. & OBLOZINSKY, P.
System: The UNT Digital Library
Internal Conversion Coefficients - How Good Are They Now? (open access)

Internal Conversion Coefficients - How Good Are They Now?

Internal conversion coefficients involving atomic electrons (ICC) and electron-positron pairs (IPC) are often required to determine transition multipolarities and total transition rates. A new internal conversion coefficient data base, BrIcc has been developed which integrates a number of tabulations on ICC and IPC, as well as {Omega}(E0) electronic factors. To decide which theoretical internal conversion coefficient table to use, the accurately determined experimental {alpha}{sub K}, {alpha}{sub L}, {alpha}{sub Total} and {alpha}{sub K}/{alpha}{sub L} values were compared with the new Dirac-Fock calculations using extreme assumptions on the effect of the atomic vacancy. While the overall difference between experiment and theory is less than 1%, our analysis shows preference towards the so called ''Frozen Orbital'' approximation, which takes into account the effect of the atomic vacancy.
Date: April 22, 2007
Creator: Kibedi, T.; Burrows, T. W.; Trzhaskovskaya, M. B.; Nestor, C. W. Jr. & Davidson, P. M.
System: The UNT Digital Library
Seismoelectric Phenomena in Fluid-Saturated Sediments (open access)

Seismoelectric Phenomena in Fluid-Saturated Sediments

Seismoelectric phenomena in sediments arise from acoustic wave-induced fluid motion in the pore space, which perturbs the electrostatic equilibrium of the electric double layer on the grain surfaces. Experimental techniques and the apparatus built to study this electrokinetic (EK) effect are described and outcomes for studies of seismoelectric phenomena in loose glass microspheres and medium-grain sand are presented. By varying the NaCl concentration in the pore fluid, we measured the conductivity dependence of two kinds of EK behavior: (1) the electric fields generated within the samples by the passage of transmitted acoustic waves, and (2) the electromagnetic wave produced at the fluid-sediment interface by the incident acoustic wave. Both phenomena are caused by relative fluid motion in the sediment pores--this feature is characteristic of poroelastic (Biot) media, but not predicted by either viscoelastic fluid or solid models. A model of plane-wave reflection from a fluid-sediment interface using EK-Biot theory leads to theoretical predictions that compare well to the experimental data for both sand and glass microspheres.
Date: April 22, 2005
Creator: Block, G I & Harris, J G
System: The UNT Digital Library
High temperature degradation by erosion-corrosion in bubbling fluidized bed combustors (open access)

High temperature degradation by erosion-corrosion in bubbling fluidized bed combustors

Heat-exchanger tubes in fluidized bed combustors (FBCs) often suffer material loss due to combined corrosion and erosion. Most severe damage is believed to be caused by the impact of dense packets of bed material on the lower parts of the tubes. In order to understand this phenomenon, a unique laboratory test rig at Berkeley was designed to simulate the particle hammering interactions between in-bed particles and tubes in bubbling fluidized bed combustors. In this design, a rod shaped specimen is actuated a short distance within a partially fluidized bed. The downward specimen motion is controlled to produce similar frequencies, velocities and impact forces as those experienced by the impacting particle aggregates in practical systems. Room temperature studies have shown that the degradation mechanism is a three-body abrasion process. This paper describes the characteristics of this test rig, reviews results at elevated temperatures and compares them to field experience. At higher temperatures, deposits of the bed material on tube surfaces can act as a protective layer. The deposition depended strongly on the type of bed material, the degree of tube surface oxidation and the tube and bed temperatures. With HCl present in the bed, wastage was increased due to enhanced oxidation …
Date: April 22, 2003
Creator: Hou, Peggy Y.; MacAdam, S.; Niu, Y. & Stringer, J.
System: The UNT Digital Library
Chemically Vapor Deposited Yttria-Stabilized Zirconia (YSZ) for Thermal and Environmental Barrier Coating (open access)

Chemically Vapor Deposited Yttria-Stabilized Zirconia (YSZ) for Thermal and Environmental Barrier Coating

Yttria-stabilized zirconia (YSZ) is used as a thermal barrier coating (TBC) to protect super-alloy blades such as Mar-M247 or Rene-N5 during engine operation. The current method for YSZ fabrication for TBC applications is by air-plasma spraying (APS) or electron beam physical vapor deposition (EB-PVD) (Haynes 1997). APS gives reasonable deposition rates, but has a limited life and aging effects due to its porous and lamellar structure. The EB-PVD coatings are more stable and can accommodate thermomechanical stresses due to their characteristic strain-tolerant, columnar microstructure. EB-PVD, however, is primarily line-of-sight, which often leaves ''hidden areas'' uncoated, has low throughput, and has high capital cost. The process of metal-organic chemical vapor deposition (MOCVD) is investigated here as an economical alternative to EB-PVD and APS, with the potential for better overall coverage as well as the ability to produce thick (100-250 {micro}m), strain-tolerant, columnar coatings. MOCVD of YSZ involves the use of zirconium and yttrium organometallic precursors reacting with an oxygen source. Previous researchers have used diketonate or chloride precursors and oxygen (Wahl et al. 2001a, Wahl et al. 2001b, Yamane and Harai 1989). These precursors have low transport rates due to their low carrier solvent solubility (Varanasi et al. 2003). Solvated zirconium …
Date: April 22, 2003
Creator: Varanasi, V. G.; Besmann, T. M.; Lothian, J. L.; Xu, W. & Starr, T. L.
System: The UNT Digital Library
Hybridization in the Ensatina Ring Species, Strong selection against hybrids at a hybrid zone in the ensatina ring species complex and its evolutionary implications (open access)

Hybridization in the Ensatina Ring Species, Strong selection against hybrids at a hybrid zone in the ensatina ring species complex and its evolutionary implications

The analysis of interactions between lineages at varying levels of genetic divergence can provide insights into the process of speciation through the accumulation of incompatible mutations. Ring species, and especially the Ensatina eschscholtzii system exemplify this approach. The plethodontid salamanders Ensatina eschscholtzii xanthoptica and Ensatina eschscholtzii platensis hybridize in the Central Sierran foothills of California. We compared the genetic structure across two transects (southern and northern Calaveras Co.), one of which was re-sampled over 20 years, and examined diagnostic molecular markers (eight allozyme loci and mitochondrial DNA) and a diagnostic quantitative trait (color pattern). Key results across all studies were: (i) cline centers for all markers were coincident and the zones were narrow, with width estimates of 730m to 2000m; (ii) cline centers at the northern Calaveras transect were coincident between 1981 and 2001, demonstrating repeatability over 5 generations; (iii) there are very few if any putative F1's, but a relatively high number of backcrossed individuals (57-86 percent) in the central portion of transects; (iv) we found substantial linkage disequilibrium in all three studies and strong heterozygote deficit both in northern Calaveras, in 2001, and southern Calaveras. Both linkage disequilibrium and heterozygote deficit show maximum values near the center of …
Date: April 22, 2005
Creator: Alexandrino, Joao; Baird, Stuart J.E.; Lawson, Lucinda; Macey, J. Robert; Moritz, Craig & Wake, David B.
System: The UNT Digital Library