Preliminary design concepts are presented for a wire scanner for experimentally evaluating spatial variations of neutron flux in the SM-l reactor core. Results of a literature search and determination of optimum criteria for flux mapping the core in minimum time dictated requirements for design concepts and specifications. The utility of both manually instrumented and automatically instrumented wire scanners was analyzed with respect to rapidity of measurement, selectivity of detector location, cost, value of data, plant downtime, and additional factors. (auth)

Uranium feed materials, depending on the production process, have been found to contain arsenic (As) as a contaminant. Analyses show the As to be present as As pentafluoride (AsF{sub 5}) and/or hexafluoroarsenic acid (HAsF{sub 6}) and enter the enrichment cycle through contaminated hydrogen fluoride (HF). Problems related to corrosion of cylinder valves and plugging of feed lines and valves have been attributed to the As. Techniques to separate AsF{sub 5} from uranium hexafluoride (UF{sub 6}) using sodium fluoride (NaF) as a trapping media were successful and will be discussed. Procedures to significantly reduce (up to 97%) the level of As in HF will also be reported. 5 figs., 9 tabs.

This report summarizes our current effort and ideas toward the development of a model for the planetary boundary layer using the finite element technique. As an initial step, the finite element methodology is applied to simpler version of the boundary layer equations given by the two-dimensional, constant-property, incompressible conservation equations (Navier-Stokes equations). Solution procedures for both the steady-state and transient equations are discussed. For the transient problem, a variable time-step, trapezoid-rule algorithm with dynamic time-truncation error control is presented. The resulting system of nonlinear algebraic equations is solved by a Newton iteration procedure with a frontal solution scheme used for the linear set of equations. The need to develop a suitable linear equation solver, with respect to minimization of computer storage and execution costs, particularly for large (three-dimensional) finite element problems, is also discussed.

The hazard matrix is our gross identifier of potential solar collector subsystem hazards. The matrix will be used as a hazard reference in the accomplishment of the preliminary design hazard analysis, and to assist system design engineers in the evaluation of the specific subsystem design.

The purpose of the present program is to develop soluble analogs of surface confined catalysts that can be impregnated directly into the coal structure at low temperatures. This approach should avoid problems related to surface area dependence, a two phase (surface-liquid) reaction system and, mass transport limitations.

The goal of this activity has been to develop and implement S-20 photocathode processing techniques at Lawrence Livermore National Laboratory (LLNL) in order to study the physical properties of the photocathode films. The present work is the initial phase of a planned activity in understanding cathode fabrication techniques and the optical/electrical characterization of these films.

This report presents results from the RINGBEARER II linearized monopole/dipole particle simulation for an intense relativistic electron beam propagating in a gas near three types of channels: (1) pre-existing conductivity, (2) density, and (3) density with pre-existing conductivity. Comparisons are made with earlier analytic results for the initial conditions for the pre-existing conductivity channel.

The Coal Project was able to make considerable progress in understanding the evolving energy situation in Asia and the future role of coal and Clean Coal Technologies. It is clear that there will be major growth in consumption of coal in Asia over the next two decades -- we estimate an increase of 1.2 billion metric tons. Second, all governments are concerned about the environmental impacts of increased coal use, however enforcement of regulations appears to be quite variable among Asian countries. There is general caution of the part of Asian utilities with respect to the introduction of CCT's. However, there appears to be potential for introduction of CCT's in a few countries by the turn of the century. It is important to emphasize that it will be a long term effort to succeed in getting CCT's introduced to Asia. The Coal Project recommends that the US CCT program be expanded to allow the early introduction of CCT's in a number of countries.

I have investigated trigger requirements for the intermediate tracking system of the SDC detector, using muons in the final states of some physics processes of interest and relevance to the program envisaged to be pursued at the SSC. The study is done at the physics event generator level with the PYTHIA package, augmented by a very simplistic simulation of the momentum measurement expected from the intermediate tracking system. For the range in pseudorapidity of {vert bar}{eta}{vert bar} = 1.7--2.5, I find a subdivision into four basic bins sufficient to ensure that the width of the transverse momentum trigger threshold will not be dominated by the lack of knowledge of the polar angle. In addition, the azimuthal resolution has be better than 1 mrad to allow transverse momentum thresholds from p{sub t}{approx}10 GeV/c up to and beyond p{sub t}=20 GeV/c to be implemented which are needed to accomplish the physics goals. 10 figs., 1 tab.

Progress made in the following studies is reported: low-energy electron scattering; variable-angle photoelectron spectroscopy; laser photochemistry and spectroscopy; and collisions in crossed molecular beams.

This information, intended for distribution at the dedication ceramonies for HGP Well No. 1, included: objectives, participants, chronology, objectives of the testing programs, budget, and the HGP advisory committee. (MHR)

Objectives of the project are to discover and evaluate novel catalytic systems for the conversion of methane or by-product light hydrocarbon gases either indirectly (through intermediate light gases rich in C{sub 2}'s) or directly to liquid hydrocarbon fuels, and to evaluate, from an engineering perspective, different conceptualized schemes. The approach is to carry out catalyst testing on several specific classes of potential catalysts for the conversion of methane selectively to C{sub 2} products. Promoted metal oxide catalysts were tested. Several of these exhibited similar high ethylene to ethane ratios and low carbon dioxide to carbon monoxide ratios observed for the NaCl/{alpha}-alumina catalyst system reported earlier. Research on catalysts containing potentially activated metals began with testing of metal molecular sieves. Silver catalysts were shown to be promising as low temperature catalysts. Perovskites were tested as potential methane coupling catalysts. A layered perovskite (K{sub 2}La{sub 2}Ti{sub 3}O{sub 10}) gave the highest C{sub 2} yield. Work continued on the economic evaluation of a hypothetical process converting methane to ethylene. An engineering model of the methane coupling system has been prepared. 47 refs., 17 figs., 57 tabs.

The Emergency Core Cooling System (ECCS) for the LOFT reactor may need to be disabled for modifications or repairs of hardware or instrumentation or for component testing during periods when the reactor system is hot and pressurized, or it may be desirable to enable the ECCS to be disabled without the necessity of cooling down and depressurizing the reactor. A policy involves disabling the automatic-actuation of the LOFT ECCS, but still retaining the manual actuation capability. Disabling of the automatic actuation can be safely utilized, without subjecting the fuel cladding to unacceptable temperatures, when the LOFT power decays to 33 kW; this power level permits a maximum delay of 20 minutes following a LOCA for the manual actuation of ECCS. For the operating power of the L2-2 Experiment, the required decay-periods (with operating periods of 40 and 2000 hours) are about 21 and 389 hours, respectively. With operating periods of 40 and 2000 hours at Core-I full power, the required decay-periods are about 42 and 973 hours, respectively. After these decay periods the automatic actuation of the LOFT ECCS can be disabled assuming a maximum delay of 20 minutes following a LOCA for the manual actuation of ECCS. The automatic …

This report has been prepared in response to the request by the House Appropriations Committee to address the permanent isolation and containment/removal of the contaminants associated with the seepage basins at the Savannah River Site (SRS). Many of the activities regarding groundwater monitoring and status referred to in this report will be discussed in detail in a companion report on the Groundwater Monitoring Program at the SRS [(U), WSRC-RP-89-889].

This document provides the Readiness Assessment Plan (RAP) for the Project W-025 (Radioactive Mixed Waste Land Disposal Facility) Readiness Assessment (RA). The RAP documents prerequisites to be met by the operating organization prior to the RA. The RAP is to be implemented by the RA Team identified in the RAP. The RA Team is to verify the facility`s compliance with criteria identified in the RAP. The criteria are based upon the {open_quotes}Core Requirements{close_quotes} listed in DOE Order 5480.31, {open_quotes}Startup and Restart of Nuclear Facilities{close_quotes}.

The Coal Project was able to make considerable progress in understanding the evolving energy situation in Asia and the future role of coal and Clean Coal Technologies. It is clear that there will be major growth in consumption of coal in Asia over the next two decades -- we estimate an increase of 1.2 billion metric tons. Second, all governments are concerned about the environmental impacts of increased coal use, however enforcement of regulations appears to be quite variable among Asian countries. There is general caution of the part of Asian utilities with respect to the introduction of CCT`s. However, there appears to be potential for introduction of CCT`s in a few countries by the turn of the century. It is important to emphasize that it will be a long term effort to succeed in getting CCT`s introduced to Asia. The Coal Project recommends that the US CCT program be expanded to allow the early introduction of CCT`s in a number of countries.

Platinum/iridium and tungsten wires were electronically etched in chloride and caustic solution, respectively, to produce tips with high aspect ratio. A direct relationship between the meniscus and the aspect ratio of etched tips was established. Scanning electron micrographs indicated that higher aspect ratios were obtained by changing the geometry of the meniscus during the etch either by an increase in the applied a.c. voltage or with the addition of a nonpolar layer above the electrolytic solution during the etching process. Above the breakdown voltage, two possible mechanisms appeared to control the etching process by expediting chemical dissolution: cavitation and sparking. Cavitation caused erosion due to the force of evolved gases against the electrode and sparking attacked the surface by vaporizing the metal. Sparking commenced on both wires near 24V. This voltage corresponded to a minimum in the plot of total etch time versus voltage. From light emission studies, sparking on Pt/Ir was associated with the ionization of Pt, Ir, Ca, and Cl. A compositional analysis of insoluble black particles produced during a.c. and d.c. etching of Pt/Ir revealed Pt and Ir as the major constituents of the product. The sparking process was shown to have a potential use in micromachining.

This document provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. This report, Volume 2, presents historical data for the Nation from 1930 to 1992, and by State from 1967 to 1992. The Supplement of this report presents profiles of selected companies.

Our 1993 third quarter report discusses the results of our work on: (1) gas-oil gravity drainage in layered media; and, (2) the influence of viscous forces on gas-oil flow in fractured porous media. For sometime, we have been working on the incorporation of reinfiltration and capillary continuity concepts in a dual-porosity model. A simple and accurate technique has been developed for this purpose. The experiments on gas-oil gravity drainage in layered media are intended to: (1) verify our theoretical analysis; (2) provide more insight; and, (3) provide a guide for the simulation of gas-oil gravity drainage at field scale. On the first objective, the experiments confirm that gas-oil gravity drainage could result in a downward gas fingering phenomenon. Without capillary pressure, downward gas fingering could not realize. The experiments also show that drainage from a less permeable layer would be an extremely slow process. This is similar to the drainage performance of matrix blocks in fractured porous media. Apparently, relative permeability to gas (i.e. gas mobility) may be important for flow in layered porous media. The project on the effect of viscous forces on gas-oil displacement in fractured porous media has taken longer than anticipated. For the first time, in …

Hanford Site tank waste supernatants will be pretreated to separate the low-level and high-level fractions. The low-level waste fraction, containing the bulk of the chemical constituents, must be processed into a vitrified waste product which will be disposed of onsite, in a safe, environmentally sound, and cost effective manner. The high-level waste fraction separated during supernatant pretreatment (primarily cesium) will be recombined with an additional high-level waste fraction generated from pretreatment of the tank waste sludges and solids. This combined high-level waste fraction will be immobilized as glass and disposed in a geological repository. The purpose of this document is to establish the functional requirements baseline for Project W-236B, Initial Pretreatment Module, by defining the level 5 and 6 functions and requirements for the project. A functional analysis approach has been used to break down the program functions and associated physical requirements that each function must meet. As the systems engineering process evolves, the design requirements document will replace this preliminary functions and requirements document. The design requirements document (DRD) will identify key decisions and associated uncertainties that impact the project. A revision of this document to a DRD is not expected to change the performance requirements or open issues. …

Research is focused on bimetallic compounds of late transition metals with carbon dioxide or CO{sub 2}-containing bridging ligands. The compounds are models for catalytic intermediates in CO{sub 2} fixation/activation processes. Thermolysis was studied. Re, Fe, and Sn complexes were studied.

The purpose of the present program is to develop soluble analogs of surface confined catalysts that can be impregnated directly into the coal structure at low temperatures. This approach should avoid problems related to surface area dependence, a two phase (surface-liquid) reaction system and, mass transport limitations.

This report discusses an allocation of $1,320,000 of 02 Reactor and Metallurgy funds which was previously made to the Pacific Northwest Laboratories. The Process Technology work order support which N-Reactor Department expected to provide during FY 1966 was estimated. The R&D allocation was based on the 189 budget proposals which were prepared early in 1965 and program identifications were provided. The integrated five year research and development program was subsequently formulated with the assistance of Pacific Northwest Laboratories and research and development program missions were defined. Revised 189 proposals have been prepared and the work is being reprogrammed in accord with the mission plan. These program discussions outline research and development needs and BNW allocations in accord with the mission requirements. The level of R&D is maintained at the original level specified in reference 1 ($1,320,000), with the exception that $130,000 for the payment of offsite irradiation unit costs is now held within NRD.

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