From abstract: "Bis(di-n-hexylphosphinyl)methane, HDPM, [(C6H13)2P(O)]2CH2, has been studied as an extractant for a variety of metals. HDPM was evaluated as an extractant for uranium(VI) and compared with tri-n-octylphosphine oxide, TOPO, (C8H13)3PO. In nonpolar solvents, HDPM forms a polymeric-like substance with compounds of uranium(VI). Viscosity measurements indicate that the molecular weight of this polymeric-like substance is about 100 times greater than the corresponding complex with TOPO. Polymer formation occurs only when nonpolar solvents are used as diluents for HDPM and is easily avoided by using polar solvents such as 1,2-aichlorobenzene. HDPM forms 1:1 and 2:1 complexes with uranium(VI) nitrate. Equilibrium constants for these complexes as well as that for the 2:1 TOPO complex were calculated and it was shown that the over-all constant is at least ten times larger for the HDPM complex than for the TOPO complex. The effect of concentration of various mineral acids, extractant concentration, temperature, and diluents on the extraction of uranium are discussed."

A method to determine the correction to Grüneisen's law corresponding to the effect of the electrons at high pressure. It is assumed that the lattice contribution to the pressure is small and that the equation of state of the solid can be approximated by results of the statistical Thomas-Fermi atom model for the electron pressure.

The technique of high-frequency titrimetry has been applied to the determination of thorium, uranium, sulfate, and free acid. In Part I of this report, the reproducibility of the method for the titration of standard solutions which contained 50mg of thorium in the absence of interferences is established. The coefficient of variation of the method, under these conditions, was found to be less than one per cent. In Part II, the effect of uranium on the high-frequency titration of thorium, as well as the application of the method to actual samples, is discussed. Uranium in a ratio of 5 to 1 to thorium can be tolerated. When the method is applied to the analysis of representative samples, the coefficient of variation is one per cent.

"Results of tests indicate that the nucerite-bearium seal system is compatible. This combination was operated as long as 9 hours without serious damage. In other work, the test rig was modified to eliminate pressure fluctuations and extraneous dirt, and Type IIA seal parts were designed."

Over the last decade, several computational methods have been developed and used to examine reactor flow transients caused by pump outage. The variations in system character which have been analyzed are sufficiently diverse that it appears worthwhile to compile them into a single report.

Quarterly report documenting progress on a project to determine an improved zirconium alloy for service in superheated water and steam. This report describes the results of approximately 75 compositions that were prepared prior, and presently are being arc-melted and fabricated into corrosion specimens, continuing the investigations of the effect of zirconium purity and heat treatment on corrosion and resistance.

The following report is one of a series of quarterly reports following the progress and development of improved zirconium alloys for service in superheated water and steam. This report covers the period between January 1 to March 31, 1961.

This report summarizes the operational experience and the data obtained on the 2AW Purex type process stream. The performance of an in-line alpha monitor for continuously monitoring Plutonium in Purex Process waste streams is described. The instrument has a lower limit of measurement of 1 x 10⁻⁶ grams of Plutonium per liter and can measure concentrations as high as 7.9 x 10⁻² grams/liter.

This report describes a completed counter experiment to measure the attenuation of K+ mesons in various materials.

This report is a corrected copy of the authors "rapporteur talk" at the 1959 Kiev Conference on High Energy Physics. It contains data on the rapporteur system and on interactions of strange particles with protons and neutrons, using data from bubble chambers, counters, and emulsions.

Weld rejects have accounted for a large percent of the total rejects in the production of fuel elements, and consequently, the investigation of the causes of these rejects was a desirable undertaking. Although previous investigations had made possible a satisfactory standardization of the welding process, it was felt of value to more sharply define the causes of weld rejects and to facilitate the control of these causes.

The following report discusses technical problems with ion cyclotron waves, and to suggest a possible application to ion magnetron work.

The state of polonium in aqueous solutions was investigated by means of ion exchange equilibrium studies. The distribution of the polonium between the solid and liquid phases was determined for solutions of various compositions using both a cation and an anion exchanges. These studies show that in the absence of a complexing agent polonium is hydrolyzed to such a degree that it forms monovalent cations and anions whose charge was not investigated in this study.

This technical report describes development work done on method of particle separation by the Biology Division of the Oak Ridge National Laboratory and the Oak Ridge Gaseous Diffusion Plant during the period January 1 to June 30, 1963, under the Joint National Institute for Health-Atomic Energy Commission Zonal Centrifuge Development Program. The central effort has been to develop zonal centrifuge systems for the separation of cells and sub-cellular particles, including viruses, and bio-colloids, including proteins and nucleic acids.

The following report is a quarterly report done by the Physics Division of the University of California's Radiation Laboratory, covering the period of November and December of 1953, and January of 1954. This report discusses general physics research and the development and operation of the accelerator.

Abstract: "This quarterly report, ARF 1194-10, covers the work performed in the time period December 15, 1961 to March 14, 1962, on Contract No. AT(11-1)-578. In this period, Phase II, the detailed evaluation of various fields of radioisotope research, has been extended. Preliminary results on the use of radioisotopes in the industrial applications, apparatus and techniques, and metallurgy categories are presented. These preliminary studies indicate the quantity of research, growth rates, and specialized areas of interest in various countries of the world. More detailed evaluations of these categories will be presented in the final report."

The effect of adding small quantities of fuel or poison to the HRT has been estimated using perturbation theory. The results have been reduced to a single relation and a set of graphs which make the estimation of added reactivity relatively simple. The perturbation theory results are compared with multigroup results and reasonable agreement is demonstrated; however, there is some question concerning the prompt neutron lifetime.

"This symposium is concerned with the basic aspects of radiation effects. When we turn to the genetic effects of radiation in mammals, there are so few aspects on which there is any information that the problem of sorting out the fundamental findings has hardly arisen. In this paper it will, therefore, be possible to survey most of what is known and pass on to a consideration of what is needed next. Since one of the purposes of this symposium is an interchange of views between investigators in different fields, an attempt will be made to avoid technical details. Among the practical needs in mammalian radiation genetics is a pressing one for more data on which to base estimates of the genetic hazards of radiation in man. The present paper will be concerned largely with this problem. Our own work is directed primarily in this direction, our objective being to uncover some of the basic facts in at least one mammal-the mouse. Before discussing the experimental work, however, it seems desirable to consider some of the general features of the genetic hazard of radiation."

The main part of this thesis is devoted to the derivation and study of formulas for the probability of survival of the haploid and diploid yeast cell, based on models proposed by Zirkle and Tobias. Some properties of so-called completely monotonic functions are developed, and the results are applied to the investigation of some of the more complicated formulas. Finally the theoretical expressions are compared with the experimental data obtained by Tobias.

The objective of this report is to set forth the design of automatic mechanical equipment developed for use with HAPO nondestructive test instruments.

Quarterly progress on the metabolic properties of various materials, radiation chemistry, biological studies of radiation effects, health chemistry, health physics.

Summary: "The laboratory data collected during the metallurgical evaluation of these rods indicate that lower rolling temperatures increased the ultimate and yield strength, the amount of cold work, and the degree of preferred orientation existing in these uranium rods."

Technical report containing short reports on (1) Mass spectrometer studies; (2) Purification of heavy water; and (3) Equilibration studies.

The methods of analysis given in this report are those which were used in the Analytical Chemistry Division of the Oak Ridge National Laboratory for analyzing samples which were derived from the experimental work on the separation of the isotopes of boron by chemical exchange. The samples consisted principally of boron trifluoride solutions in anisole (methyl phenyl ether, CH30C6H5). The boron concentration ranged from a few parts per million to 5 or 6 per cent. Boron was determined on all samples. During the early stages of the project, iron and copper were occasionally determined, while a limited number of aqueous solutions and water extracts of anisole solutions of BF3 were analyzed for fluoboric and hydroxyfluoboric acids, boric acid, total boron, and total fluoride. Boron was determined by the use of either a spectrophotometric or volumetric method, depending on the amount available. Initially, if the amount of sample and boron concentration were such as to provide a total of at least 2 to 4 mg of boron, the volumetric method was utilized and found to be satisfactory. For smaller amount, the spectrophotometric method was used. Later, because of its greater speed and simplicity, the spectrophotometric method was used for samples in …