Cation Exchange Separation of Divalent Metal Ions From Rare Earths (open access)

Cation Exchange Separation of Divalent Metal Ions From Rare Earths

From abstract: "The divalent metal ions of calcium, magnesium, nickel, and strontium are eluted from a cation exchange column with 1.5M nitric acid and separated from trivalent rare earths, aluminum and yttrium. Prior sequential elution of other metal ions with hydrochloric acid in acetone-water or with dilute hydrofluoric acid does not interfere with the present separation method."
Date: June 6, 1962
Creator: Fritz, James S. (James Sherwood), 1924- & Garralda, Barbara B.
System: The UNT Digital Library
Acid-Base Equilibria in Tertiary Butyl Alcohol (open access)

Acid-Base Equilibria in Tertiary Butyl Alcohol

From abstract: "The dissociation of acids in tertiary butyl alcohol has been studied by potentiometric, spectrophotometric, and conductimetric methods. Values for the over-all dissociation of perchloric and picric acids and several tetrabutylammonium salts were estimated by the Fuoss-Kraus treatment of conductance data. Potentiometric studies were carried out at constant ionic strength in order to minimize activity coefficient variations. An acidity scale was established from potentiometric measurements at a glass electrode, and conductance values of dissociation constants. A method was developed for the evaluation of the over-all dissociation constant of weak acids using potentiometric data for hydrogen ion activities and conductance data for the corresponding anion activities. Over-all dissociation constants are reported for perchloric acid, picric acid, 2,4-dinitrophenol, and benzoic acid. Apparent dissociation constants from potentiometric measurements at a constant ionic strength were determined for hydrobromic, nitric, hydrochloric, picric, and p-toluenesulfonic acids."
Date: August 6, 1962
Creator: Marple, Leland & Fritz, James S. (James Sherwood), 1924-
System: The UNT Digital Library