The adsorption of acetic and oleic acids on the surface of thoria was studied by means of infrared spectroscopy. An infrared analysis of the adsorbates before and after adsorption using differential double bean methods indicated that the adsorption of organic acids on thoria surfaces occurs by an esterification reaction between the organic acid and the hydroxylated thoria surface. Ammonia vapor will not adsorb on thoria, indicated the basic character of the hydroxylated surface.

The attached list of publications is submitted as a year to year and final report of progress on work accomplished under Contract AT(11-1)-159 from 1950 to 1959. Work was initiated on this project in the spring of 1950 and is still in progress as of the date of this report.

The adsorption on activated charcoal of pure He3 at 2.5 and 3°K, and of pure He4 at 4°K has been measured. The volume of gas necessary to form a monolayer is approximately the same for the two isotopes. It is shown that capillary condensation does not occur in this adsorbent at low saturations. The data have been analyzed by a number of methods with consistent results.

A pilot model of an Aerodynamic Raindrop Sorter was constructed along the lines suggested by mathematical analysis. The function of the analyzer is to sort natural rain according to drop size and to collect the sorted drops for further analysis. The pilot model, a small wind tunnel inclined at 45 deg to the horizontal, demonstrated the feasibility of aerodynamic rain drop sorting over a wide range of drop sizes. (auth)

A wet collection system for aerosols has been developed using fibrous media. Tests show the performance to be in accord with recently developed theory of collection by fibrous media. The effects of varying aerosol particle size, particle density, and gas velocity have indicated that inertial impaction is the primary collection mechanism. Three-year operating experience on several full scale plant installations shows reliable performance.

"The data obtained by a-c polarography, when used to determine electrode parameters such as heterogeneous rate constant and when used as an analytical tool, are evaluated. Certain aspects of the experimental approach both in measurement and calculation are reviewed. The importance and means of correcting for the series resistance of the cell system itself and of using equations which take into account the phase differences between the faradaic and capacitive currents are developed. Other topics reviewed include the nature of the dependence of the peak a-c on depolarizer concentration, effect of adsorption of depolarizer and electrode, and a simplified procedure for quantitative analysis."

"The resonant frequencies of the magnet power supply are investigated. It is found that there are eleven resonant modes in addition to the desired mode of operation with six additional resonant frequencies. From measurements of the choke model, it appears that the frequencies of some of the spurious modes may lie in the same range as the desired mode of operation."

A simple method of solving for the phase shifts of the pion-proton scattering is presented. The rapid solution afforded can be utilized, as the Ashkin diagrams have been employed, to give starting values to an electronic computer or alternatively to analyze with more ease the variation of the phase shifts as a function of the input data in terms of the coefficients of the angular distributions. A new plot of a function of the total cross section versus the pion energy is introduced. The nearly straight line resulting should help to evaluate the experimental data.

Ilford D1 and Eastman NTC nuclear emulsions have been loaded with a solution of uranium acetate and them exposed to the X-ray beam of the Case betatron operated at 18 Mev. The developed plates have been searched wit a Zeiss type microscope. A total number of 1062 fission tracks have been measured and analyzed and the angular distribution of the fission fragments in center of mas system has been obtained.

This technical report constitutes a brief review of the work undertaken, entirely or in part, under the Contract AT(30-1)-1772 with eh United States Atomic Energy Commission. The work published during 1959 is listed at the end of this report and copies of the reprints or reports are attached where available. These investigations have been concerned with the examination of defect production and behavior as it may be observed by high frequency ultrasonic attenuation and velocity (modulus) changes in such materials as quartz, silicon, germanium, alkali halides (especially NaCl and XCl), high purity aluminum, and glass containing boron. The irradiations used are cobalt 60 gamma-ray irradiation and the reactor irradiation obtained in the Brookhaven National Laboratory graphite reactor.

"The objective of this program is to conduct a broad basic program of analytical and experimental research into the fundamental behavior of gas- lubricated bearings and to establish general design criteria for these bearings. The work to date has included both theoretical and experimental phases of hydrodynamic and hydrostatic lubrication phenomena, supplemented by a digital computer program."

Quantitative recovery of carrier‐free 10−9 M manganese (II) is possible from weakly acidic solutions. The use of lead dioxide as either a non-isotopic carrier or a chemical displacing agent makes possible high recoveries from more acidic solutions.

Separation processes for production of pure rare earth oxides in useful quantities are discussed. A review of applications of these oxides in the ceramic industry in production of glasses, glazes, porcelain enamels, refractories, abrasives, electronic ceramics, and nuclear ceramics is also presented. 46 references.

"Study of the ADFR concept included experimental work on fuel dust suspension stability and redispersibility, erosion, and dust deposition using the fuel dust circulation loop. Some theoretical work was done in the areas of reactor safety and breeding."

"Work has begun on the ADFR, a reactor using a new fuel form -- fissionable dust carried in an inent gas. Temperatures in the range 2,000 to 3,000 deg F appear feasible in an all-ceramic system. Experimental study of the fuel form was initiated, and a loop to circulate the fuel dust was constructed. Initial operation is encouraging. Theoretical studies were carried on in the areas of reactor physics, heat transfer, and safety."

Attempts to secure a high degree of synchronization of cell division of the Krebs mouse ascites carcinoma, by combined use of aminopterin and citrovorum factor, and by use of colchicine and N-acetyl colchinol, were unsuccessful. In the course of the work, a new method for securing smears of ascites tumor cells was out, which we believe will be found useful

During the past year, three papers covering results of a major series of experiments on intergenotype of blood-forming tissue have appeared, demonstrating successful implantation of isologues normal cells in anemic hosts, permanently correcting their genetic defect in hematopoiesis, both with and without irradiation of the host. Heavy host irradiation was shown ineffective as preparations for implantation of homologous cells of widely different antigenic types.

Ceramic investigators often find it desirable to know the weight of reactants either immediately after a given heating period or while the specimen is still at the elevated reacting temperature. The conventional gravimetric methods render either of these goals difficult if not actually impossible. Specimens often gain weight through adsorption of water or other reactions upon cooling to room temperature. Desiccators are employed but are not completely satisfactory. Repeated heating and weighing are necessary before a "constant weight" value is obtained. Research in the field of rates for various ceramic reactions, as for example, dehydration of clays, has been hampered by the lack of a simple continuous method of obtaining the required data. While the differential thermal analysis methods have proven somewhat effective for some applications there still remain ample areas for improvements. it was for the above reasons that this research was undertaken.

The objectives of this research program are to determine bond strength under dynamic loading, to compare bond strengths under static and dynamic loading, and to test the adequacy of ACI Building Code bond requirements for structural elements subjected to blast loads. The tests have shown that local static bond strengths may be as high as 0.75 fc and that under dynamic loading this strength increases to fc. For all practical lengths of embedment of bars, steel failure is to be expected both under static and dynamic loading. Such bars loaded dynamically will carry a larger load than bards loaded statically, this increase in load carrying capacity of bars being sole due to the increase of steel strength under dynamic loading.

Experiments are described which show that magnetic fields can exert a controlling influence on the operating characteristics of point contact transistors. The effect is especially evident when the transistor is operated in its negative resistance region. The frequency of an oscillator can be varied, or a switch made to trigger by applying a magnetic field to the transistor. Some applications of the principle are suggested; many more are evident.

A gage employing a narrow "pencil" of beta-rays has been developed to determine the thickness of films used a cyclotron targets. The instrument, pictured in Figure 1, allows an estimate of the evenness of films a few mg/cm thick by reproducibly scanning the sample with a collimated beta-ray beam 3/32 in. in diameter.

"Expressions are found to relate DELTA gamma to the n-errors.'' It is demonstrated that the integral n-value concept'' is of no use in the present case. A modification of integrated n-value'' is suggested."

"Formulas are given to express the general particle trajectory and the equilibrium orbit for a slightly disturbed synchrotron in terms of the amplitude and phase functions for the ideal machine. If these functions are known, orbit computations can be carried out by simple integration procedures. The formalism is expected to be useful especially for considerations such as beam alignment or generation of an external electron beam. Some equations given earlier are repeated for completeness."

Progress reports from four divisions are included: (1) Division of Biophysics; (2) Division of Clinical Investigation; (3) Division of Nucleoprotein Chemistry; and (4) Radiochemistry Section.