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Regulating C2H2/CO2 adsorption selectivity by electronic-state manipulation of iron in metal-organic frameworks (open access)

Regulating C2H2/CO2 adsorption selectivity by electronic-state manipulation of iron in metal-organic frameworks

Article reports a metal electronic-state manipulation strategy to construct a pair of isostructural and interconvertible Fe-MOFs featuring open Fe centers with different electron densities for efficient C₂H₂/CO₂ separation. The authors show that the presence of Fe[II] centers with a medium-spin-state trail plays a crucial role in the enhanced C₂H₂ selective adsorption.
Date: July 20, 2022
Creator: Chen, Cheng-Xia; Pham, Tony; Tan, Kui; Krishna, Rajamani; Lan, Pui Ching; Wang, Longfei et al.
Object Type: Article
System: The UNT Digital Library
Elgin Courier (Elgin, Tex.), Vol. 132, No. 29, Ed. 1 Wednesday, July 20, 2022 (open access)

Elgin Courier (Elgin, Tex.), Vol. 132, No. 29, Ed. 1 Wednesday, July 20, 2022

Weekly newspaper from Elgin, Texas that includes local, state, and national news along with advertising.
Date: July 20, 2022
Creator: Hodges, Julianne
Object Type: Newspaper
System: The Portal to Texas History