Bi-Pb eutectic and pure Bi penetration of graphites of various densities under 300 degrees C and pressures up to 20 psi was found be of the order of magnitude of 1.0 g/cm(2) and was uniform throughout the graphite. Bi was absorbed less than the eutectic but the oxidation rate of Bi would be prohibitive. There was heavy nitriding in N atmospheres with the Bi and the eutectic.

An approximate calculation is made of the variations of the flexibility of a long cartridge with the length of the slug used, assuming that the jacket slides without friction.

Effect of aquadag coating on noise reduction in polyethylene coaxial cable was tested. A satisfactory combination of coaxial cables and connectors interconnecting sources of small ion currents or ionizing impulses with the measuring device is described.

Technical report that attempts to bring together the various chemical procedures which proved most useful in studying the results of cyclotron bombardment or small scale neutron bombardments of heavy element targets. The report is limited to the elements of the "actinide", or second rare earth series, starting with thorium and including the newly discovered elements of atomic number 95 and 96. Every attempt is made to include all details necessary so this report can serve as a practical laboratory guide. The report covers separation problems, time factors, and dealing with dangerously radioactive targets.

The work described in this technical report was undertaken as part of a larger program dealing with a systematic investigation of changes in the physical prosperities of artificial graphite due to neutron bombardment. Very pronounced among those changes is the increase in the elastic modulus. Since there is a general relationship between the elastic modulus of a given substance and its specific heat, it was expected that corresponding changes will occur in the specific heat. In conclusion, the experiments determined that it appears that the low temperature specific heat measurements of strongly bombarded samples will be helpful for the understanding of the nature and the mechanism of the changes produced by neutron bombardment and annealing.

Technical report describing two experiments performed to compare the amounts of fission gases swept out of UNH solution with those amounts swept out of PU solution under idential condiditons. The charge wire technique was used. The essential date and the results are given in tables in the report.

Introduction. the colorimetric determination of iron based on the formation of the colored ferrous-1,10-phenanthroline complex has been used successfully by a number of investigators. In this technical report, its adaptation to the routine determination of iron in cerium, thorium, and beryllium metals and their compounds is described.

Abstract. In addition to the hexagonal and monoclinic bismuth phosphate precipitates, whose structures are now known, a third crystalline phase has been found to appear in BiPO4 precipitates after (a) extremely long digestion in concentrated nitric acid; (b) oven drying at 800 degrees to 1000 degrees. Thought very small single crystals of the component have been isolated, nor crushed sample contained less than 30% of the beta-form. The cell size and symmetry of the crystal indicates that there ae two bismuth atoms in the cell, and there is no evidence that the compound is not BiPO4. It is suggested that this maty be a third form of BiPO4, stable over a short range of conditions, and tending to revert to the beta-form.

Abstract: Experiments on colloid milling and pumping show that uranium trioxide, when carefully dehydrated, can be dispersed in water to form a relatively stable slurry, suitable for a homogeneous slurry pile. At temperatures considerably below those of anticipated pile operation particle size growth occurs attended by increase in settling rate and decrease in viscosity. Theses properties of the slurries may be strongly affected by impurities present as well as by special operating conditions.

Abstract: Pure UO2F2 is made by reaction between anhydrous HF and pure UO3. Although it is difficult to prepare free of water, it is not very hygroscopic. Prolonged heating at 100-105 degrees releases 99.9% of the water in an aqueous solution; the rate of loss of water is very small after saturation is reached. X-ray diffraction data give a density of 6.2 for the solid. The density of a 1.004 M solution is 1.274; the density of a saturated solution (5.130 M) is 2.400. The densities of F-9 solutions have been calculated from the densities of ordinary aqueous solutions, and the values are compared graphically. Data on the solubility indicate that there is a small increase in the range 25-100 degrees. Recovery of pure F-9 from a solution is hampered by hydrolysis of U)2F2 to give HF. The HF may be held back by addition of UO3 or CaO; the use of the latter, however, makes more difficult the recovery of all the F-9. Molar conductivities of UO2F2 solutions at 25 degrees, as well as the specific conductivities of a 1 molar solution containing various concentrations of UO3, have been determined. The addition of UO3 lowers the conductivity. The low …

Abstract: Part I: A series of extraction experiments has been performed to determine the distribution coefficient of uranium(VI) between dilute perchloric acid and benzene solutions of TTA. The data are interpreted to show that the principal species in the acid phase is a doubly charged ion, UO2++. The discrepancies revealed in previous work(1) were not found. Part II: The spectrophotometric method of analysis developed for use in Part I has shown the existence of previously unreported species of uranium(VI) in the presence of TTA: UO2K2-HK in benzene, and UO2K+ in dilute acid. The absorption spectra of all the principal species are reported.

A quarterly report consisting of reports published on Transuranic Elements from the University of California Radiation Laboratory. Each report is a brief one to two page summaries of the article submitted for publication during the months of September-November, 1948.

From abstract: "This report describes methods used for radiochemical analysis of fission products most used in the Experimental Biology Section. The report includes methods of analysis of Sr89, Ba140-La140, Zr95-Cb95, Ce144-Pr144, and Y91 by standard chemical procedures. In addition, a method of analysis by use of an absorption curve is described in some detail for Zr95-Cb95 mixtures. The absorption curve method makes possible rapid determination of percentage composition of a mixture of isotopes with a minimum of chemical manipulation by utilizing the differences in absorption characteristics of the emitted rays."

Abstract: The counting accuracy of the Chicago Scalers, Models 961A and 961B, is a function of the bias setting of the limiter (V2). this report gives quantitative data supporting this thesis. A method of making bias settings is suggested. These tests were run at the suggestion of Mr. V. C. Hanson.

From abstract: "A sensitive method for measuring the intensity of weak neutron sources by measuring induced Mn56 beta activity after concentration by a Szilard-Chalmers process has been developed. The practical detection efficiency for Ra-Be neutron is 7.8%; the procedure is capable of detecting a neutron intensity of about one neutron per second."

From introductory paragraph: "The study of the counting techniques of gamma-emitting radioisotopes is of a great deal of interest to workers in the field of radiochemistry. Of particular interest to the long-lived gamma emitting isotope of yttrium which is commonly prepared by a deuteron bombardment of strontium and is reported to decay by K-capture. This isotope, which is of interest in the fields of biochemistry and metallurgy was tentatively assigned to mass 86. Since a 2.0 hour activity was observed from a neutron irradiation of yttrium, the assignment was considered fixed. Subsequent work indicated a possibility of a long-lived gamma emitting activity arising in the fast neutron irradiation of yttrium. The published data did not agree with theoretical calculations as to the possibility of these two activities being isomers. This work was undertaken to study the characteristics of the radiations from the isotopes; to have data available on the long-lived activity; and, to attempt to fix the mass assignment."

Abstract: "A method is described for the identification and quantitative determination of trace amounts of rare earths in graphite by measurement of the energies and decays of the activities induced by neutron irradiation. The specific rare earth elements identified are europium and samarium. During the development of this method, the half-lives of Eu-152 and Sm-153 were determined. These are reported as 9.32 +/- 0.04 hours and 46.34 +/- 0.23 respectively."

This report is a document summarizing all information available on life aspects of various measures proposed to reduce or eliminate corrosion of Van Stone flanger.

Report discussing a method for the stepwise calculation of the number of transfer units utilized in a given solvent extraction operation. "Use of the method results in a very appreciable saving in time of calculation with an error of 1.5% for the runs tested. The error tends to become smaller with increasing total numbers of transfer units involved."

From introduction: "The present investigation of the properties of boron stainless steel is an outgrowth of a project started in 1947. The problem is to replace the present steel used for drop rods in the Hanford piles with a material much less subject to corrosive attack from the humid atmosphere existing at the location of the rods."

Report detailing values of x-ray lives and limits for trans-uranic elements. Formulas and methods are detailed throughout the report.

Abstract: "The solubility of the solid, UO2C2O4 x rH2O, was measured at various acid and uranyl nitrate concentrations. The results of the measurements prove the existence of the uranyl oxalate complex - UO2C2O4, in solutions containing excess UO2^2."

Abstract: "The results obtained from the tests conducted for the purpose of determining the corrosivity of a 30 percent-solution of uranyl fluoride to various metals indicate that stainless steels (type 302, 304, 321 and 316) have very good resistance; while monel, nickel and aluminum, respectively, exhibit diminishing resistance. Stainless steel, type 316, was the most resistant of the specimen tested."

Report discussing trial runs of a method of recovery of uranium from salvage residue. The method involves hydrofluorination of the residue to remove large quantities of interfering silicates, followed by a fluorination treatment to remove uranium.