Quarterly report discussing fuel cell research and development work at Argonne National Laboratory (ANL). This report describes efforts directed toward (1) evaluating the dissolution of NiO cathodes in molten carbonate fuel cells and (2) seeking alternative cathode materials. Solubility data were taken for NiO in a cathode environment, and previously operated cells were examined for nickel transfer. A literature search was made for prospective alternative cathode materials, and synthesis of new materials was begun. Apparatus was assembled for conductivity measurements on cathode materials.

This report summarizes the information base that was collected and reviewed in preparation for carrying out an analysis of the compatibility with regulations of waste management technologies for disposal of Hydrogen-3, Iodine-129, Carbon-14, and Krypton-85. Based on the review of this literature, summaries are presented here of waste-form characteristics, packaging, transportation, and disposal methods. Also discussed are regulations that might apply to all operations involved in disposal of the four nuclides, including the processing of irradiated fuel in a fuel reprocessing plant, packaging, storage, transport, and final disposal. The compliance assessment derived from this information is reported in a separate document.

A robust and efficient numerical scheme has been developed for the solution of the finite-differenced pressure linked fluid flow equations. The algorithm solves the set of nonlinear simultaneous equations by a combination of Newton's method and efficient sparse matrix techniques. In tests on typical recirculating flows the method is rapidly convergent. The method does not require any under-relaxation or other convergence-enhancing techniques employed in iterative schemes. It is currently described for two-dimensional steady state flows but is extendible to three dimensions and mildly time-varying flows. The method is robust to changes in Reynolds number, grid aspect ratio, and mesh size. This paper reports the algorithm and the results of calculations performed.

Quarterly report of the Argonne National Laboratory Chemical Engineering Division regarding activities related to properties and handling of radioactive materials, operation of nuclear reactors, and other relevant research.

Abstract: Automated time-difference measurements at the picosecond level have been achieved. The system described combines the best properties of three common methods: the single heterodyne measurement technique, the frequency divider, and the dual-mixer time-difference measurement system. This particular system combines two instrumentation standards, ANSI/IFEE-583 and ANSI/IEEE-488 with new, modular dual-mixer time-difference measurement hardware. The modular, standardized hardware together with the new measurement techniques permit the data acquisition modules to be contained in a standard CAMAC crate. This system, along with an external controller, is capable of measuring eiqht clocks, at the present time, and is expandable to twenty-four clocks with modified software and additional measurement modules. The system noise performance is described by a (rT = 3 x 10^-12 t^-1 for time difference measurements.

Abstract: A reaction oriented list of references is provided for published papers and reports containing rate data or information on mechanism for reactions of ozone with various substrates in aqueous solutions. Catalyzed, as well as uncatalyzed, reactions are included. One hundred and sixty-four papers are listed. The period covered extends from 1913 to 1981.

A fully coupled solution algorithm for pressure-linked fluid flow equations earlier found to be rapidly convergent in laminar flows has been extended to calculate turbulent flows. The governing mean flow equations are solved in conjunction with a two-equation (k - epsilon) turbulence model. A number of two-dimensional recirculating flows have been computed and it is shown that the calculation procedure is rapidly convergent in all the cases. The calculations have been compared with published experimental data; their agreement is in accord with other published experiences with the (k - epsilon) model in similar flows.

The following report is the fourth in a series of reports on rare and uncommon elements prepared by the Geological Survey. This report covers columbius and tantalus, two chemical elements belonging to the fifth group of the periodic table and quinquevalent in most of their compounds.

Abstract: Procedures are presented in detail of two methods for the determination of very small percentages or uranium (down to 0.0025). The methods are applicable to a wide variety of materials. Notes on the methods and confirmatory experiments are also given.

From introduction: This report presents a complete and concise record of tag recoveries for the adult Hawaiian green turtle, Chelonia mydas, made from 1973 through 1982 in association with the breeding colony of French Frigate Shoals (FFS).

From purpose and scope: The purpose of this study was to update hydrologic data and refine understanding of the hydrologic system within the San Dieguito, San Elijo, and San Pasqual hydrologic subareas in San Diego County, Calif., and to evaluate the suitability of these areas for reclaimed water use.