The work described in this report was done to determine the path of decomposition of plutonium (IV) oxalate and to determine the factors affecting the reactivity of the oxide with the hydrogen fluoride.

An experiment designed to evaluate the in-pile performance of the U-Mg fuel material when irradiated to high burnups has been completed. Twelve specimens of the fuel material which contained uranium particles that packed 50 volume per cent, (91.5 weight per cent), uranium in a magnesium matrix were canned in Zircaloy cans and irradiated in the Materials Testing Reactor to 0.1 (1000 MWD/T), 0.3 (5000 MWD/T), 1.0 (10000 MWD/T) and 2.0 20000 MWD/T) per cent burnup of the total uranium atoms; more exactly, 1 MWD/T = 1.16 x 10⁻⁴ per cent burnup of the total uranium atoms. Irradiation of the twelve capsules began on August 1, 1954. The burnup figures used in this report are calculated values assuming a conversion ratio for the capsules of 1.0. Because of the lack of confirmed experimental burnup data for exposures of this magnitude, there is a possible error in the calculated values of about 20 per cent at 2.0 per cent burnup. However, recent results based on chemical analysis for cesium indicate that the calculated values of burnup agree quite closely for the higher exposures. Burnup estimates based on the results of the chemical analysis will be published when they become available. Six of …

A report based on a study about the factors which affect the amount of chemical reaction between water and Zircaloy 2 at high temperatures. Also, experimental programs for the measurement of radiation emissivity, chemical reaction rates, and diffusion rates have been completed.