The corrosion behavior of aluminum, copper, and iron in inhibited ethylene glycol-ASTM corrosive water solutions was evaluated in a laboratory loop under isothermal and heat-flux conditions for 1000 h at temperatures between 378 and 413 degrees K, in static autoclave tests at 450 degrees K for 500 h, and by potentiodynamic polarization measurements at temperatures between 298 and 348 degrees K. The effect of time, temperature, and ethylene glycol concentration of the heat-transfer fluid on the extent of inhibitor depletion was determined from analyses of the reserve alkalinity, pH, and inhibitor content of the solutions. The performance of an electrochemical sensor as a monitor of fluid quality was also evaluated. A heat flux of 0.4 to 1.0 kW/m sq. did not have a significant effect on the corrosion behavior of the various materials at temperatures between 378 and 413 degrees K. The corrosion rates of aluminum, copper, and iron in the 50 volume percent inhibited ethylene glycol-corrosive water solution decreased as a function of time during the 1000-h test. At 413 degrees K, the corrosion rate of copper was considerably higher than that of iron or aluminum at low flow velocity. Significant degradation of the fluid quality, as indicated by …

SACO is a fast-running computer code that simulates hypothetical accidents in liquid-metal fast breeder reactors to the point of permanent subcriticality or to the initiation of a prompt-critical excursion. In the tradition of the SAS codes each sub-assembly is modeled by a representative fuel pin with three distinct axial regions to simulate the blanket and core regions. However, analytic and integral models are used wherever possible to cut down the computing time and storage requirements. The physical models and basic equations are described in detail.

Large-scale efforts are in progress to develop advanced batteries for utility energy storage systems. Realization of the full benefits available from those systems requires development, not only of the batteries themselves, but also the ac/dc power converter, the bulk power interconnecting equipment, and the peripheral electric balance of plant equipment that integrate the battery/converter into a properly controlled and protected energy system. This study addresses these overall system aspects; although tailored to a 20-MW, 100-MWh lithium/sulfide battery system, the technology and concepts are applicable to any battery energy storage system.

Quarterly report of the Argonne National Laboratory Chemical Engineering Division regarding activities related to properties and handling of radioactive materials, operation of nuclear reactors, and other relevant research. Fuel cycle work reported for this period includes testing of hydraulic performance and extraction efficiency of eight-stage centrifugal contactors, testing of a flowsheet for the Aralex process, evaluation of ruthenium and zirconium extraction in a miniature centrifugal contactor, study of zirconium aging in the organic phase and its effect on zirconium extraction and hydraulic testing of the 9-cm-ID contactor.

The second addition is a substantial revision of the original work. A new chapter on latent heat storage, an appendix on units and conversions, and an index have been added. The purpose for this manual is to provide information on the design and installation of thermal energy storage in solar heating systems. It is intended for contractors, installers, solar system designers, engineers, architects, and manufacturers who intend to enter the solar energy business. The reader should have general knowledge of how solar heating systems operate and knowledge of construction methods and building codes. Knowledge of solar analysis methods such as f-chart, SOLCOST, DOE-1, or TRNSYS would be helpful. The information contained in the manual includes sizing storage, choosing a location for the storage device, and insulation requirements. Both air-based and liquid-based systems are covered with topics on designing rock beds, tank types, pump and fan selection, installation, costs, and operation and maintenance. Topics relevant to latent heat storage include properties of phase-change materials, sizing the storage unit, insulating the storage unit, available systems, and cost. Topics relevant to heating domestic water include safety, single- and dual-tank systems, domestic water heating with air- and liquid-based space heating systems, and stand alone …

Quarterly report of the Argonne National Laboratory Chemical Engineering Division regarding activities related to properties and handling of radioactive materials, operation of nuclear reactors, and other relevant research.

A preliminary estimate has been made of the manufacturing cost for lithium/iron sulfide cells for stationary energy-storage and electric-vehicle applications. This preliminary cost analysis indicated that the manufacturing cost (in 1979 dollars) is $24 to 41/kW-h for stationary energy-storage cells and $31 to 55/kW-h for electric-vehicle cells. The materials cost was found to contribute between 52 and 65% of this manufacturing cost. The most expensive materials and components were lithium (metal and compounds), $4.61 to $14.26/kW-h; BN felt, $4.00 to 8.50/kW-h; feed-through components, $2.40/kW-h; positive current collectors, $1.48 to 2.20/kW-h; and aluminum, $1.43 to 1.66/kW-h. The projected lithium requirements were determined for use in lithium/iron sulfide batteries and conventional uses to the year 2006. The results showed that the lithium requirements were about 275,000 short tons by 2006, which is equivalent to about 51% of presently known US resources. Of this amount, about 33% would be used in battery production and 67% consumed in conventional uses. It is expected that the lithium used in battery production would be recycled.

Quarterly report of the Argonne National Laboratory Chemical Engineering Division regarding activities related to properties and handling of radioactive materials, operation of nuclear reactors, and other relevant research.