Degree Discipline

Degree Level

Novel Cyclotron-Based Radiometal Production (open access)

Novel Cyclotron-Based Radiometal Production

Accomplishments: (1) Construction of prototype solution target for radiometal production; (2) Testing of prototype target for production of following isotopes: a. Zr-89. Investigation of Zr-89 production from Y-89 nitrate solution. i. Defined problems of gas evolution and salt precipitation. ii. Solved problem of precipitation by addition of nitric acid. iii. Solved gas evolution problem with addition of backpressure regulator and constant degassing of target during irradiations. iv. Investigated effects of Y-89 nitrate concentration and beam current. v. Published abstracts at SNM and ISRS meetings; (3) Design of 2nd generation radiometal solution target. a. Included reflux chamber and smaller target volume to conserve precious target materials. b. Included aluminum for prototype and tantalum for working model. c. Included greater varicosities for improved heat transfer; and, (4) Construction of 2nd generation radiometal solution target started.
Date: October 31, 2013
Creator: DeGrado, Timothy R.
Object Type: Report
System: The UNT Digital Library
Seismic Soil-Structure Interaction Analyses of a Deeply Embedded Model Reactor – SASSI Analyses (open access)

Seismic Soil-Structure Interaction Analyses of a Deeply Embedded Model Reactor – SASSI Analyses

This report summarizes the SASSI analyses of a deeply embedded reactor model performed by BNL and CJC and Associates, as part of the seismic soil-structure interaction (SSI) simulation capability project for the NEAMS (Nuclear Energy Advanced Modeling and Simulation) Program of the Department of Energy. The SASSI analyses included three cases: 0.2 g, 0.5 g, and 0.9g, all of which refer to nominal peak accelerations at the top of the bedrock. The analyses utilized the modified subtraction method (MSM) for performing the seismic SSI evaluations. Each case consisted of two analyses: input motion in one horizontal direction (X) and input motion in the vertical direction (Z), both of which utilized the same in-column input motion. Besides providing SASSI results for use in comparison with the time domain SSI results obtained using the DIABLO computer code, this study also leads to the recognition that the frequency-domain method should be modernized so that it can better serve its mission-critical role for analysis and design of nuclear power plants.
Date: October 31, 2013
Creator: J., Nie; J., Braverman & Costantino, M.
Object Type: Report
System: The UNT Digital Library
SOLVENT HOLD TANK SAMPLE RESULTS FOR MCU-13-189, MCU-13-190, AND MCU-13-191: QUARTERLY SAMPLE FROM SEPTEMBER 2013 (open access)

SOLVENT HOLD TANK SAMPLE RESULTS FOR MCU-13-189, MCU-13-190, AND MCU-13-191: QUARTERLY SAMPLE FROM SEPTEMBER 2013

Savannah River National Laboratory (SRNL) analyzed solvent samples from Modular Caustic-Side Solvent Extraction Unit (MCU) in support of continuing operations. A quarterly analysis of the solvent is required to maintain solvent composition within specifications. Analytical results of the analyses of Solvent Hold Tank (SHT) samples MCU-13-189, MCU-13-190, and MCU-13-191 received on September 4, 2013 are reported. The results show that the solvent (remaining heel in the SHT tank) at MCU contains excess Isopar� L and a deficit concentration of modifier and trioctylamine when compared to the standard MCU solvent. As with the previous solvent sample results, these analyses indicate that the solvent does not require Isopar� L trimming at this time. Since MCU is switching to NGS, there is no need to add TOA nor modifier. SRNL also analyzed the SHT sample for {{sup 137}Cs content and determined the measured value is within tolerance and the value has returned to levels observed in 2011.
Date: October 31, 2013
Creator: Fondeur, F. & Taylor-Pashow, K.
Object Type: Report
System: The UNT Digital Library
Transactional Network Platform: Applications (open access)

Transactional Network Platform: Applications

In FY13, Pacific Northwest National Laboratory (PNNL) with funding from the Department of Energy’s (DOE’s) Building Technologies Office (BTO) designed, prototyped and tested a transactional network platform to support energy, operational and financial transactions between any networked entities (equipment, organizations, buildings, grid, etc.). Initially, in FY13, the concept demonstrated transactions between packaged rooftop air conditioners and heat pump units (RTUs) and the electric grid using applications or "agents" that reside on the platform, on the equipment, on a local building controller or in the Cloud. The transactional network project is a multi-lab effort with Oakridge National Laboratory (ORNL) and Lawrence Berkeley National Laboratory (LBNL) also contributing to the effort. PNNL coordinated the project and also was responsible for the development of the transactional network (TN) platform and three different applications associated with RTUs. This document describes two applications or "agents" in details, and also summarizes the platform. The TN platform details are described in another companion document.
Date: October 31, 2013
Creator: Katipamula, Srinivas; Lutes, Robert G.; Ngo, Hung & Underhill, Ronald M.
Object Type: Report
System: The UNT Digital Library
Transition Core Properties during Conversion of the NBSR from HEU to LEU Fuel (open access)

Transition Core Properties during Conversion of the NBSR from HEU to LEU Fuel

The transition of the NBSR from HEU to LEU fuel is challenging due to reactivity constraints and the need to maintain an uninterrupted science program, the mission of the NBSR. The transition cannot occur with a full change of HEU to LEU fuel elements since the excess reactivity would be large enough that the NBSR would violate the technical specification for shutdown margin. Manufacturing LEU fuel elements to represent irradiated fuel elements would be cost prohibitive since 26 one-of-a-kind fuel elements would need to be manufactured. For this report a gradual transition from the present HEU fuel to the proposed LEU fuel was studied. The gradual change approach would follow the present fuel management scheme and replace four HEU fuel elements with four LEU fuel elements each cycle. This manuscript reports the results of a series of calculations to predict the neutronic characteristics and how the neutronics will change during the transition from HEU to LEU in the NBSR.
Date: October 31, 2013
Creator: L., Hanson A. & D., Diamond
Object Type: Report
System: The UNT Digital Library
VOLTTRON Lite: Integration Platform for the Transactional Network (open access)

VOLTTRON Lite: Integration Platform for the Transactional Network

In FY13, Pacific Northwest National Laboratory (PNNL) with funding from the Department of Energy’s (DOE’s) Building Technologies Office (BTO) designed, prototyped and tested a transactional network platform. The platform is intended to support energy, operational and financial transactions between any networked entities (equipment, organizations, buildings, grid, etc.). Initially, in FY13, the concept demonstrated transactions between packaged rooftop units (RTUs) and the electric grid using applications or “agents” that reside on the platform, on the equipment, on local building controller or in the Cloud. This document describes the core of the transactional network platform, the Volttron Lite™ software and associated services hosted on the platform. Future enhancements are also discussed. The appendix of the document provides examples of how to use the various services hosted on the platform.
Date: October 31, 2013
Creator: Haack, Jereme N.; Katipamula, Srinivas; Akyol, Bora A. & Lutes, Robert G.
Object Type: Report
System: The UNT Digital Library
Water Management Strategies for Improved Coalbed Methane Production in the Black Warrior Basin (open access)

Water Management Strategies for Improved Coalbed Methane Production in the Black Warrior Basin

The modern coalbed methane industry was born in the Black Warrior Basin of Alabama and has to date produced more than 2.6 trillion cubic feet of gas and 1.6 billion barrels of water. The coalbed gas industry in this area is dependent on instream disposal of co-produced water, which ranges from nearly potable sodium-bicarbonate water to hypersaline sodium-chloride water. This study employed diverse analytical methods to characterize water chemistry in light of the regional geologic framework and to evaluate the full range of water management options for the Black Warrior coalbed methane industry. Results reveal strong interrelationships among regional geology, water chemistry, and gas chemistry. Coalbed methane is produced from multiple coal seams in Pennsylvanian-age strata of the Pottsville Coal Interval, in which water chemistry is influenced by a structurally controlled meteoric recharge area along the southeastern margin of the basin. The most important constituents of concern in the produced water include chlorides, ammonia compounds, and organic substances. Regional mapping and statistical analysis indicate that the concentrations of most ionic compounds, metallic substances, and nonmetallic substances correlate with total dissolved solids and chlorides. Gas is effectively produced at pipeline quality, and the only significant impurity is N{sub 2}. Geochemical analysis …
Date: October 31, 2013
Creator: Pashin, Jack; McIntyre-Redden, Marcella; Mann, Steven & Merkel, David
Object Type: Report
System: The UNT Digital Library
X-ray Thomson scattering as a temperature probefor gigabar shock experime (open access)

X-ray Thomson scattering as a temperature probefor gigabar shock experime

None
Date: October 31, 2013
Creator: Doeppner, T
Object Type: Article
System: The UNT Digital Library
Integrated Advanced Reciprocating Internal Combustion Engine System for Increased Utilization of Gaseous Opportunity Fuels (open access)

Integrated Advanced Reciprocating Internal Combustion Engine System for Increased Utilization of Gaseous Opportunity Fuels

The project is addressing barriers to or opportunities for increasing distributed generation (DG)/combined heat and power (CHP) use in industrial applications using renewable/opportunity fuels. This project brings together novel gas quality sensor (GQS) technology with engine management for opportunity fuels such as landfill gas, digester gas and coal bed methane. By providing the capability for near real-time monitoring of the composition of these opportunity fuels, the GQS output can be used to improve the performance, increase efficiency, raise system reliability, and provide improved project economics and reduced emissions for engines used in distributed generation and combined heat and power.
Date: August 31, 2013
Creator: Pratapas, John; Zelepouga, Serguei; Gnatenko, Vitaliy; Saveliev, Alexei; Jangale, Vilas; Li, Hailin et al.
Object Type: Report
System: The UNT Digital Library
Lightweight Composite Materials for Heavy Duty Vehicles (open access)

Lightweight Composite Materials for Heavy Duty Vehicles

The main objective of this project is to develop, analyze and validate data, methodologies and tools that support widespread applications of automotive lightweighting technologies. Two underlying principles are guiding the research efforts towards this objective: • Seamless integration between the lightweight materials selected for certain vehicle systems, cost-effective methods for their design and manufacturing, and practical means to enhance their durability while reducing their Life-Cycle-Costs (LCC). • Smooth migration of the experience and findings accumulated so far at WVU in the areas of designing with lightweight materials, innovative joining concepts and durability predictions, from applications to the area of weight savings for heavy vehicle systems and hydrogen storage tanks, to lightweighting applications of selected systems or assemblies in light–duty vehicles.
Date: August 31, 2013
Creator: Pruez, Jacky; Shoukry, Samir; Williams, Gergis & Shoukry, Mark
Object Type: Report
System: The UNT Digital Library
Low-Cost Illumination-Grade LEDs (open access)

Low-Cost Illumination-Grade LEDs

Solid State Lighting is a cost-effective, energy-conserving technology serving a rapidly expand- ing multi-billion dollar market. This program was designed to accelerate this lighting revolution by reducing the manufacturing cost of Illumination-Grade LEDs. The technical strategy was to investigate growth substrate alternatives to standard planar sapphire, select the most effective and compatible option, and demonstrate a significant increase in Lumen/$ with a marketable LED. The most obvious alternate substrate, silicon, was extensively studied in the first two years of the program. The superior thermal and mechanical properties of Si were expected to improve wavelength uniformity and hence color yield in the manufacture of high-power illumination- grade LEDs. However, improvements in efficiency and epitaxy uniformity on standard c-plane sapphire diminished the advantages of switching to Si. Furthermore, the cost of sapphire decreased significantly and the cost of processing Si devices using our thin film process was higher than expected. We concluded that GaN on Si was a viable technology but not a practical option for Philips Lumileds. Therefore in 2012 and 2013, we sought and received amendments which broadened the scope to include other substrates and extended the time of execution. Proprietary engineered substrates, off-axis (non-c-plane) sapphire, and c-plane patterned sapphire …
Date: August 31, 2013
Creator: Epler, John
Object Type: Report
System: The UNT Digital Library
Low Cost Sorbent for Capturing CO{sub 2} Emissions Generated by Existing Coal-fired Power Plants (open access)

Low Cost Sorbent for Capturing CO{sub 2} Emissions Generated by Existing Coal-fired Power Plants

TDA Research, Inc. has developed a novel sorbent based post-combustion CO{sub 2} removal technology. This low cost sorbent can be regenerated with low-pressure (ca. 1 atm) superheated steam without temperature swing or pressure-swing. The isothermal and isobaric operation is a unique and advantageous feature of this process. The objective of this project was to demonstrate the technical and economic merit of this sorbent based CO{sub 2} capture approach. Through laboratory, bench-scale and field testing we demonstrated that this technology can effectively and efficiently capture CO{sub 2} produced at an existing pulverized coal power plants. TDA Research, Inc is developing both the solid sorbent and the process designed around that material. This project addresses the DOE Program Goal to develop a capture technology that can be added to an existing or new coal fired power plant, and can capture 90% of the CO{sub 2} produced with the lowest possible increase in the cost of energy. .
Date: August 31, 2013
Creator: Elliott, Jeannine
Object Type: Report
System: The UNT Digital Library
Nanoscience Research Internships in Illinois (open access)

Nanoscience Research Internships in Illinois

NanoBusiness Talent Project Summary Report The NanoBusiness Alliance created the NanoBusiness Talent Program to ensure the future vitality of domestic scientists and entrepreneurs by engaging advanced high school students in cutting-edge nanotechnology development. This program commenced on September 1, 2008 and ran through August 31, 2010 with a very successful group of students. Several of these students went on to Stanford, Harvard and Yale, as well as many other prestigious Universities. We were able to procure the cooperation of several companies over the entire run of the program to voluntarily intern students at their companies and show them the possibilities that exist for their future. Companies ranged from NanoInk and Nanosphere to QuesTek and NanoIntegris all located in northern Illinois. During the 9-week internships, students worked at nanotechnology companies studying different ways in which nanotechnology is used for both commercial and consumer use. The students were both excited and invigorated at the prospect of being able to work with professional scientists in fields that previously may have just been a dream or an unreachable goal. All the students worked closely with mentors from each company to learn different aspects of procedures and scientific projects that they then used to present …
Date: August 31, 2013
Creator: Kronshage, Alisa
Object Type: Report
System: The UNT Digital Library
The Potential Impacts of OTEC Intakes on Aquatic Organisms at an OTEC Site under Development on Kauai, HI (open access)

The Potential Impacts of OTEC Intakes on Aquatic Organisms at an OTEC Site under Development on Kauai, HI

Ocean thermal energy conversion (OTEC) is a marine renewable energy technology with the potential to contribute significantly to the baseload power needs of tropical island communities and remote U.S. military installations. As with other renewable energy technologies, however, there are potential challenges to its commercialization: technological, financial, social, and environmental. Given the large volumes of seawater required to drive the electricity-producing cycle, there is potential for the intakes to negatively impact the marine resources of the source waterbody through the impingement and entrainment of marine organisms. The goal of this project was to identify feasible warm water intake designs for a land-based OTEC facility proposed for development in Port Allen, Kauai and to characterize the populations of ichthyoplankton near the proposed warm water intake location that could be at risk of entrainment. The specific objectives of this project were to: • Complete a site-specific assessment of available and feasible warm water intake technologies to determine the best intake designs for minimizing impacts to aquatic organisms at the proposed land-based OTEC site in Port Allen, Kauai. • Complete a field sampling program to collect biological data to characterize the baseline populations of ichthyoplankton near the sites being considered for the warm …
Date: August 31, 2013
Creator: Oney, Stephen K.; Hogan, Timothy & Steinbeck, John
Object Type: Report
System: The UNT Digital Library
RADIOLYTIC GAS PRODUCTION RATES OF POLYMERS EXPOSED TO TRITIUM GAS (open access)

RADIOLYTIC GAS PRODUCTION RATES OF POLYMERS EXPOSED TO TRITIUM GAS

Data from previous reports on studies of polymers exposed to tritium gas is further analyzed to estimate rates of radiolytic gas production. Also, graphs of gas release during tritium exposure from ultrahigh molecular weight polyethylene (UHMW-PE), polytetrafluoroethylene (PTFE, a trade name is Teflon®), and Vespel® polyimide are re-plotted as moles of gas as a function of time, which is consistent with a later study of tritium effects on various formulations of the elastomer ethylene-propylene-diene monomer (EPDM). These gas production rate estimates may be useful while considering using these polymers in tritium processing systems. These rates are valid at least for the longest exposure times for each material, two years for UHMW-PE, PTFE, and Vespel®, and fourteen months for filled and unfilled EPDM. Note that the production “rate” for Vespel® is a quantity of H{sub 2} produced during a single exposure to tritium, independent of length of time. The larger production rate per unit mass for unfilled EPDM results from the lack of filler- the carbon black in filled EPDM does not produce H{sub 2} or HT. This is one aspect of how inert fillers reduce the effects of ionizing radiation on polymers.
Date: August 31, 2013
Creator: Clark, E.
Object Type: Report
System: The UNT Digital Library
Ab Initio Many-Body Calculations Of Light-Ion Reactions (open access)

Ab Initio Many-Body Calculations Of Light-Ion Reactions

None
Date: July 31, 2013
Creator: Romero-Redondo, C; Navratil, P; Quaglioni, S; Hupin, G; Langhammer, J; Calci, A et al.
Object Type: Article
System: The UNT Digital Library
Addendum to the Closure Report for Corrective Action Unit 547: Miscellaneous Contaminated Waste Sites, Nevada National Security Site, Nevada (open access)

Addendum to the Closure Report for Corrective Action Unit 547: Miscellaneous Contaminated Waste Sites, Nevada National Security Site, Nevada

This addendum to the Closure Report for Corrective Action Unit 547: Miscellaneous Contaminated Waste Sites, Nevada National Security Site, Nevada, DOE/NV--1480, dated July 2012, documents repairs of erosion and construction of engineered erosion protection features at Corrective Action Site (CAS) 02-37-02 (MULLET) and CAS 09-99-06 (PLAYER). The final as-built drawings are included in Appendix A, and photographs of field work are included in Appendix B. Field work was completed on March 11, 2013.
Date: July 31, 2013
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Advanced Rooftop Control (ARC) Retrofit: Field-Test Results (open access)

Advanced Rooftop Control (ARC) Retrofit: Field-Test Results

The multi-year research study was initiated to find solutions to improve packaged equipment operating efficiency in the field. Pacific Northwest National Laboratory (PNNL), with funding from the U.S. Department of Energy’s (DOE’s) Building Technologies Office (BTO) and Bonneville Power Administration (BPA) conducted this research, development and demonstration (RD&D) study. Packaged equipment with constant speed supply fans is designed to provide ventilation at the design rate at all times when the fan is operating as required by building code. Although there are a number of hours during the day when a building may not be fully occupied or the need for ventilation is lower than designed, the ventilation rate cannot be adjusted easily with a constant speed fan. Therefore, modulating the supply fan in conjunction with demand controlled ventilation (DCV) will not only reduce the coil energy but also reduce the fan energy. The objective of this multi-year research, development and demonstration project was to determine the magnitude of energy savings achievable by retrofitting existing packaged rooftop air conditioners with advanced control strategies not ordinarily used for packaged units. First, through detailed simulation analysis, it was shown that significant energy (between 24% and 35%) and cost savings (38%) from fan, cooling …
Date: July 31, 2013
Creator: Wang, Weimin; Katipamula, Srinivas; Ngo, Hung; Underhill, Ronald M.; Taasevigen, Danny J. & Lutes, Robert G.
Object Type: Report
System: The UNT Digital Library
DEVELOPMENT OF ANALYTICAL METHODS FOR DETERMINING SUPPRESSOR CONCENTRATION IN THE MCU NEXT GENERATION SOLVENT (NGS) (open access)

DEVELOPMENT OF ANALYTICAL METHODS FOR DETERMINING SUPPRESSOR CONCENTRATION IN THE MCU NEXT GENERATION SOLVENT (NGS)

Savannah River National Laboratory (SRNL) was tasked with identifying and developing at least one, but preferably two methods for quantifying the suppressor in the Next Generation Solvent (NGS) system. The suppressor is a guanidine derivative, N,N',N"-tris(3,7-dimethyloctyl)guanidine (TiDG). A list of 10 possible methods was generated, and screening experiments were performed for 8 of the 10 methods. After completion of the screening experiments, the non-aqueous acid-base titration was determined to be the most promising, and was selected for further development as the primary method. {sup 1}H NMR also showed promising results from the screening experiments, and this method was selected for further development as the secondary method. Other methods, including {sup 36}Cl radiocounting and ion chromatography, also showed promise; however, due to the similarity to the primary method (titration) and the inability to differentiate between TiDG and TOA (tri-n-ocytlamine) in the blended solvent, {sup 1}H NMR was selected over these methods. Analysis of radioactive samples obtained from real waste ESS (extraction, scrub, strip) testing using the titration method showed good results. Based on these results, the titration method was selected as the method of choice for TiDG measurement. {sup 1}H NMR has been selected as the secondary (back-up) method, and additional …
Date: July 31, 2013
Creator: Taylor-Pashow, K.; Fondeur, F.; White, T.; Diprete, D. & Milliken, C.
Object Type: Report
System: The UNT Digital Library
Distributed Sensor Coordination for Advanced Energy Systems (open access)

Distributed Sensor Coordination for Advanced Energy Systems

The ability to collect key system level information is critical to the safe, efficient and reli- able operation of advanced energy systems. With recent advances in sensor development, it is now possible to push some level of decision making directly to computationally sophisticated sensors, rather than wait for data to arrive to a massive centralized location before a decision is made. This type of approach relies on networked sensors (called “agents” from here on) to actively collect and process data, and provide key control deci- sions to significantly improve both the quality/relevance of the collected data and the as- sociating decision making. The technological bottlenecks for such sensor networks stem from a lack of mathematics and algorithms to manage the systems, rather than difficulties associated with building and deploying them. Indeed, traditional sensor coordination strategies do not provide adequate solutions for this problem. Passive data collection methods (e.g., large sensor webs) can scale to large systems, but are generally not suited to highly dynamic environments, such as ad- vanced energy systems, where crucial decisions may need to be reached quickly and lo- cally. Approaches based on local decisions on the other hand cannot guarantee that each agent performing its task …
Date: July 31, 2013
Creator: Tumer, Kagan
Object Type: Report
System: The UNT Digital Library
Experimental Determination of the 12 rad Line Around Bldg 332 from a Maximum Credible Criticality Accident (open access)

Experimental Determination of the 12 rad Line Around Bldg 332 from a Maximum Credible Criticality Accident

None
Date: July 31, 2013
Creator: Hankins, D E
Object Type: Report
System: The UNT Digital Library
Hydrate Research Activities That Both Support and Derive From the Monitoring Station/Sea-Floor Observatory, Mississippi Canyon 118, Northern Gulf of Mexico (open access)

Hydrate Research Activities That Both Support and Derive From the Monitoring Station/Sea-Floor Observatory, Mississippi Canyon 118, Northern Gulf of Mexico

A permanent observatory has been installed on the seafloor at Federal Lease Block, Mississippi Canyon 118 (MC118), northern Gulf of Mexico. Researched and designed by the Gulf of Mexico Hydrates Research Consortium (GOM-HRC) with the geological, geophysical, geochemical and biological characterization of in situ gas hydrates systems as the research goal, the site has been designated by the Bureau of Ocean Energy Management as a permanent Research Reserve where studies of hydrates and related ocean systems may take place continuously and cooperatively into the foreseeable future. The predominant seafloor feature at MC118 is a carbonate-hydrate complex, officially named Woolsey Mound for the founder of both the GOM-HRC and the concept of the permanent seafloor hydrates research facility, the late James Robert “Bob” Woolsey. As primary investigator of the overall project until his death in mid-2008, Woolsey provided key scientific input and served as chief administrator for the Monitoring Station/ Seafloor Observatory (MS-SFO). This final technical report presents highlights of research and accomplishments to date. Although not all projects reached the status originally envisioned, they are all either complete or positioned for completion at the earliest opportunity. All Department of Energy funds have been exhausted in this effort but, in addition, …
Date: July 31, 2013
Creator: Lutken, Carol
Object Type: Report
System: The UNT Digital Library
Leadership and Stewardship of the Laboratory (Objective 4.1) Notable Outcome - Phase II Alternative Analysis and PNNL Site Plan Recommendation (open access)

Leadership and Stewardship of the Laboratory (Objective 4.1) Notable Outcome - Phase II Alternative Analysis and PNNL Site Plan Recommendation

Pacific Northwest National Laboratory (PNNL) and the Pacific Northwest Site Office (PNSO) have recently completed an effort to identify the current state of the campus and gaps that exist with regards to space needs, facilities and infrastructure. This effort has been used to establish a campus strategy to ensure PNNL is ready to further the United States (U.S.) Department of Energy (DOE) mission. Ten-year business projections and the impacts on space needs were assessed and incorporated into the long-term facility plans. In identifying/quantifying the space needs for PNNL, the following categories were addressed: Multi-purpose Programmatic (wet chemistry and imaging laboratory space), Strategic (Systems Engineering and Computation Analytics, and Collaboration space), Remediation (space to offset the loss of the Research Technology Laboratory [RTL] Complex due to decontamination and demolition), and Optimization (the exit of older and less cost-effective facilities). The findings of the space assessment indicate a need for wet chemistry space, imaging space, and strategic space needs associated with systems engineering and collaboration space. Based on the analysis, a 10-year campus strategy evolved that balanced four strategic objectives, as directed by the DOE Office of Science (DOE-SC): • Mission Alignment - maintain customer satisfaction • Reasonable & Achievable - do …
Date: July 31, 2013
Creator: Pittman, Jeffery P.; Cassidy, Stephen R.; Mosey, Whitney LC; Leitz, Erlan M. & Oukrop, Lanson J.
Object Type: Report
System: The UNT Digital Library
Mass Transfer And Hydraulic Testing Of The V-05 And V-10 Contactors With The Next Generation Solvent (open access)

Mass Transfer And Hydraulic Testing Of The V-05 And V-10 Contactors With The Next Generation Solvent

The Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) facility is actively pursuing the transition from the current BOBCalixC6 based solvent to the Next Generation Solvent (NGS)-MCU solvent. To support this integration of NGS into the MCU facilities, Savannah River Remediation (SRR) requested that Savannah River National Laboratory (SRNL) perform testing of a blend of the NGS (MaxCalix based solvent) with the current solvent (BOBCalixC6 based solvent) for the removal of cesium (Cs) from the liquid salt waste stream. This testing differs from prior testing by utilizing a blend of BOBCalixC6 based solvent and the NGS with the full (0.05 M) concentration of the MaxCalix as well as a new suppressor, tris(3,7dimethyloctyl) guanidine. Single stage tests were conducted using the full size V-05 and V-10 centrifugal contactors installed at SRNL. These tests were designed to determine the mass transfer and hydraulic characteristics with the NGS solvent blended with the projected heel of the BOBCalixC6 based solvent that will exist in MCU at time of transition. The test program evaluated the amount of organic carryover and the droplet size of the organic carryover phases using several analytical methods. Stage efficiency and mass distribution ratios were determined by measuring Cs concentration in …
Date: July 31, 2013
Creator: Herman, D. T.; Duignan, M. R.; Williams, M. R.; Peters, T. B.; Poirier, M. R. & Fondeur, F. F.
Object Type: Report
System: The UNT Digital Library