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Ion sensitive field effect transistors applied to the measurement of the pH of brines (open access)

Ion sensitive field effect transistors applied to the measurement of the pH of brines

The ability to measure the pH (the negative logarithm of the hydrogen ion activity) of harsh fluids such as geothermal oil field brines is important, since pH is a fundamental property; as one chemist stated: ``very often pH is a critical test because its accuracy lays the foundation for other measurements``. In our research, we focus on the analysis of brines similar to those found in underground geothermal reservoirs. Since the brines are deep under the ground, the values of the pressure and the temperature are high (up to 14 Mpa and 150{degrees}C); therefore the usual methods of pH measurement, e.g., glass electrode, are not applicable. The hydrogen ion sensitive ISFET (Ion Selective Field Effect Transistor) was studied as a pH sensor in this research. An ISFET can detect the electrochemical potential difference between the solution and the semiconductor due to the concentration of H{sup +} ions in the solution. Because of its solid state construction, an ISFET should work properly under high pressure and high temperature conditions. Earlier results, have indicated that it is possible to use ISFETs under the harsh conditions presented by geothermal brines.
Date: December 31, 1991
Creator: Chen, J.
System: The UNT Digital Library
An experimental investigation of two-phase crossflow over rigidly and flexibly mounted tubes (open access)

An experimental investigation of two-phase crossflow over rigidly and flexibly mounted tubes

Two-phase crossflow over heat exchanger tubes induces vibrations which contribute greatly to the wear on the tubes. Of the three mechanisms leading to two-phase flow-induced vibrations which have been identified, fluid-elastic instability has been recognized as that which leads to the vibrations with the largest amplitude. The mass damping parameter is used to predict the onset of fluid-elastic instability, and the mean drag coefficient is used to calculate the mass damping parameter. In this thesis, the drag coefficient measured over single tubes and tubes within array, in single-phase and two-phase flow at various Reynolds numbers, is discussed. The drag coefficient was measured by two methods. For flexibly mounted tubes, strain gages were mounted on cantilever beams which held the tube in place and allowed it to vibrate in the direction parallel to the flow only. For both rigidly and flexibly mounted tubes, pressure distributions were measured around the perimeter of the tube. Forces, and then the drag coefficient, could be calculated from this information. The drag coefficient was not found to depend upon the flexibility of the tube mounting. As the void fraction of the flow increases, the drag coefficient over the tube increases. This effect was found to be …
Date: December 31, 1991
Creator: Gerhart, S.M.
System: The UNT Digital Library
Mass and charge distributions in chlorine-induced nuclear reactions (open access)

Mass and charge distributions in chlorine-induced nuclear reactions

Projectile-like fragments were detected and characterized in terms of A, Z, and energy for the reactions {sup 37}Cl on {sup 40}Ca and {sup 209}Bi at E/A = 7.3 MeV, and {sup 35}Cl, on {sup 209}Bi at E/A = 15 MeV, at angles close to the grazing angle. Mass and charge distributions were generated in the N-Z plane as a function of energy loss, and have been parameterized in terms of their centroids, variances, and coefficients of correlation. Due to experimental problems, the mass resolution corresponding to the {sup 31}Cl on {sup 209}Bi reaction was very poor. This prompted the study and application of a deconvolution technique for peak enhancement. The drifts of the charge and mass centroids for the system {sup 37}Cl on {sup 40}Ca are consistent with a process of mass and charge equilibration mediated by nucleon exchange between the two partners, followed by evaporation. The asymmetric systems show a strong drift towards larger asymmetry, with the production of neutron-rich nuclei. It was concluded that this is indicative of a net transfer of protons from the light to the heavy partner, and a net flow of neutrons in the opposite direction. The variances for all systems increase with energy …
Date: December 31, 1991
Creator: Marchetti, A. A.
System: The UNT Digital Library
Cross flow induced vibrations in staggered arrays of cylindrical structures (open access)

Cross flow induced vibrations in staggered arrays of cylindrical structures

Flow induced vibrations cause by instability is the subject of this investigation. The bulk of the work performed is theoretical in nature, the comparison with some of existing experimental data is given for each of four models described. First model encompasses the effects of prescribed motion on the cylinder. Such circumstances occur in the case of vortex shedding initiated instability. The reduced velocity within the cylinder array is low and there is no coupling between the adjacent cylinders. Second model assumes certain form of vibration and corresponding behavior of the perturbed velocity field in temporal and one of spatial coordinates thus transforming partial differential equations into ordinary differential equations and takes into account the motion of the neighboring cylinder. This corresponds to fluid elastic controlled instabilities. The resulting equations are solved analytically. The model is used for better understanding of the equations of cylinder motion as well as for quick estimates of threshold of instability. Third model relaxes an assumption about the form of vibration in spatial direction and uses the vorticity formulation of equation of fluid motion to account for fluid-solid interaction. This model analysis is of two phase (air-water mixture) flow. The void fraction distribution is found to …
Date: December 31, 1991
Creator: Marn, J.
System: The UNT Digital Library