Strange Particle Production in $p+p$ Collisions at $\sqrt{s}$= 200GeV (open access)

Strange Particle Production in $p+p$ Collisions at $\sqrt{s}$= 200GeV

We present strange particle spectra and yields measured atmid-rapidity in sqrt text s=200 GeV proton-proton (p+p) collisions atRHIC. We find that the previously observed universal transverse mass(mathrm mT \equiv\sqrt mathrm p_T 2+\mathrm m2) scaling of hadronproduction in p+p collisions seems to break down at higher \mt and thatthere is a difference in the shape of the \mt spectrum between baryonsand mesons. We observe mid-rapidity anti-baryon to baryon ratios nearunity for Lambda and Xi baryons and no dependence of the ratio ontransverse momentum, indicating that our data do not yet reach thequark-jet dominated region. We show the dependence of the mean transversemomentum (\mpt) on measured charged particle multiplicity and on particlemass and infer that these trends are consistent with gluon-jet dominatedparticle production. The data are compared to previous measurements fromCERN-SPS, ISR and FNAL experiments and to Leading Order (LO) and Next toLeading order (NLO) string fragmentation model predictions. We infer fromthese comparisons that the spectral shapes and particle yields from $p+p$collisions at RHIC energies have large contributions from gluon jetsrather than quark jets.
Date: July 31, 2006
Creator: Abelev, B. I.; Adams, J.; Aggarwal, M. M.; Ahammed, Z.; Amonett, J.; Anderson, B. D. et al.
System: The UNT Digital Library
Electronic Properties of LiFePO4 and Li doped LiFePO4 (open access)

Electronic Properties of LiFePO4 and Li doped LiFePO4

LiFePO{sub 4} has several potential advantages in comparison to the transition metal oxide cathode materials used in commercial lithium-ion batteries. However, its low intrinsic electronic conductivity ({approx} 10{sup -9} S/cm) is problematic. We report here a study by soft x-ray absorption/emission spectroscopy of the electronic properties of undoped LiFePO{sub 4} and Li-doped LiFePO{sub 4} in which Li{sup +} ions are substituted for Fe{sup 2+} ions in an attempt to increase the intrinsic electronic conductivity. The conductivities of the Li{sub 1+x}Fe{sub 1-x}PO{sub 4} samples were, however, essentially unchanged from that of the undoped LiFePO{sub 4}. Nonetheless, evidence for changing the electronic properties of LiFePO{sub 4} by doping with excess Li+ was observed by the XAS/XES spectroscopy. New pre-edge features the O-1s XAS spectrum of Li{sub 1.05}Fe{sub 0.95}PO4 is a direct indication that the charge compensation for substitution of Fe{sup 2+} by Li{sup +} resides in the unoccupied O-2p orbitals. A charge transfer (CT) excitation was also observed in the doped material implying that the unoccupied O-2p orbitals created by doping are strongly hybridized with unoccupied Fe-3d orbitals of neighboring sites. However, the strong covalent bonding within the (PO{sub 4}){sup 3-} anions and the large separation of the Fe cations means that …
Date: May 31, 2006
Creator: Allen, J.L.; Zhuang, G.V.; Ross, P.N.; Guo, J.-H. & Jow, T.R.
System: The UNT Digital Library
A broadband high-resolution elliptical crystal x-ray spectrometer for high energy density physics experiments (open access)

A broadband high-resolution elliptical crystal x-ray spectrometer for high energy density physics experiments

Spectroscopic investigation of high temperature laser produced plasmas in general, and x-ray opacity experiments in particular, often requires instruments with both a broad coverage of x-ray energies and high spectral, spatial, and temporal resolution. We analyze the design, model the response, and report the commissioning of a spectrometer using elliptical crystals in conjunction with a large format, gated microchannel plate detector. Measurements taken with this instrument at the JANUS laser facilities demonstrate the designed spectral range of 0.24 to 5.8 keV, and spectral resolution E/{Delta}E > 500, resulting in 2 to 3 times more spectral data than achieved by previous spectrometer designs. The observed 100 picosecond temporal resolution and 35 {micro}m spatial resolution are consistent with the requirements of high energy density opacity experiments.
Date: March 31, 2006
Creator: Anderson, S G; Heeter, R F; Booth, R; Emig, J; Fulkerson, S; McCarville, T et al.
System: The UNT Digital Library
Spin coherence transfer in chemical transformations monitoredNMR (open access)

Spin coherence transfer in chemical transformations monitoredNMR

We demonstrate the use of micro-scale nuclear magneticresonance (NMR) for studying the transfer of spin coherence innon-equilibrium chemical processes, using spatially separated NMRencoding and detection coils. As an example, we provide the map ofchemical shift correlations for the amino acid alanine as it transitionsfrom the zwitterionic to the anionic form. Our method is unique in thesense that it allows us to track the chemical migration of encodednuclear spins during the course of chemical transformations.
Date: July 31, 2006
Creator: Anwar, Sabieh M.; Hilty, Christian; Chu, Chester; Bouchard,Louis-S.; Pierce, Kimberly L. & Pines, Alexander
System: The UNT Digital Library
Search for B+ to X(3872) K+, X(3872) to J/psi gamma (open access)

Search for B+ to X(3872) K+, X(3872) to J/psi gamma

In a study of B{sup +} {yields} J/{psi}{gamma}K{sup +} decays, they find evidence for the radiative decay X(3872) {yields} J/{psi}{gamma} with a statistical significance of 3.4{sigma}. They measure the product of branching fractions {Beta}(B{sup +} {yields} X(3872)K{sup +}) {center_dot} {Beta}(X(3872) {yields} J/{psi}{gamma}) = (3.3 {+-} 1.0 {+-} 0.3) x 10{sup -6}, where the uncertainties are statistical and systematic, respectively. They also measure the branching fraction {Beta}(B{sup +} {yields} {chi}{sub c1}K{sup +}) = (4.9 {+-} 0.20 {+-} 0.4) x 10{sup -4}. These results are obtained from (287 {+-} 3) million B{bar B} decays collected at the {Upsilon}(4S) resonance with the BABAR detector at the PEP-II B Factory at SLAC.
Date: July 31, 2006
Creator: Aubert, B.
System: The UNT Digital Library
Searches for B0 Decays to eta K0, eta eta,eta' eta', eta phi, and eta'phi (open access)

Searches for B0 Decays to eta K0, eta eta,eta' eta', eta phi, and eta'phi

The authors search for B{sup 0} meson decays into two-body combinations of K{sup 0}, {eta}, {eta}', and {phi} mesons in 324 million B{bar B} pairs collected with the BABAR detector at the PEP-II asymmetric-energy e{sup +}e{sup -} collider at SLAC. They measure the following branching fractions (upper limits at 90% confidence level) in units of 10{sup -6}: {Beta}(B{sup 0} {yields} {eta}K{sup 0}) = 1.8{sub -0.6}{sup +0.7} {+-} 0.1 (< 2.9), {Beta}(B{sup 0} {yields} {eta}{eta}) = 1.1{sub -0.4}{sup +0.5} {+-} 0.1(< 1.8), {Beta}(B{sup 0} {yields} {eta}{phi}) = 0.1 {+-} 0.2 {+-} 0.1(< 0.6), {Beta}(B{sup 0} {yields} {eta}'{phi}) = 0.2{sub -0.3}{sup +0.4} {+-} 0.1(< 1.0), and {Beta}(B{sup 0} {yields} {eta}'{eta}') = 1.0{sub -0.6}{sup +0.8} {+-} 0.1 (< 2.4), where the first error is statistical and the second systematic.
Date: July 31, 2006
Creator: Aubert, B.
System: The UNT Digital Library
Vector-Tensor and Vector-Vector Decay AmplitudeAnalysis of B0 to phi K*0 (open access)

Vector-Tensor and Vector-Vector Decay AmplitudeAnalysis of B0 to phi K*0

We perform an amplitude analysis of the decays B{sup 0} {yields} {phi}K*{sub 2}(1430){sup 0}, {phi}K*(892){sup 0}, and {phi}(K{pi}){sub S-wave}{sup 0} with a sample of about 384 million B{bar B} pairs recorded with the BABAR detector. The fractions of longitudinal polarization f{sub L} of the vector-tensor and vector-vector decay modes are measured to be 0.853{sub -0.069}{sup +0.061} {+-} 0.036 and 0.506 {+-} 0.040 {+-} 0.015, respectively. Overall, twelve parameters are measured for the vector-vector decay and seven parameters for the vector-tensor decay, including the branching fractions and parameters sensitive to CP-violation.
Date: October 31, 2006
Creator: Aubert, B.
System: The UNT Digital Library
Observation of a Broad Structure at an Invariant Massof 4.32 GeV in the Reaction e+e- to pi+pi-psi(2S) Measured at BaBar (open access)

Observation of a Broad Structure at an Invariant Massof 4.32 GeV in the Reaction e+e- to pi+pi-psi(2S) Measured at BaBar

The authors measure the cross section for the process e{sup +}e{sup -} {yields} {pi}{sup +}{pi}{sup -}{psi}(2S) from threshold up to 8 GeV center-of-mass energy using events containing initial-state radiation, produced at the PEP-II e{sup +}e{sup -} storage rings. The study is based on 298 fb{sup -1} of data recorded with the BABAR detector. A structure is observed in the cross-section not far above threshold, near 4.32 GeV. This structure is not compatible with the Y(4260) previously reported by this experiment. A single resonance is adequate to describe the cross-section in the low-energy region (< 5.7 GeV).
Date: October 31, 2006
Creator: Aubert, B.; Barate, R.; Bona, M.; Boutigny, D.; Couderc, F.; Karyotakis, Y. et al.
System: The UNT Digital Library
4-D XRD for strain in many grains using triangulation (open access)

4-D XRD for strain in many grains using triangulation

Determination of the strains in a polycrystalline materialusing 4-D XRD reveals sub-grain and grain-to-grain behavior as a functionof stress. Here 4-D XRD involves an experimental procedure usingpolychromatic micro-beam X-radiation (micro-Laue) to characterizepolycrystalline materials in spatial location as well as with increasingstress. The in-situ tensile loading experiment measured strain in a modelaluminum-sapphire metal matrix composite using the Advanced Light Source,Beam-line 7.3.3. Micro-Laue resolves individual grains in thepolycrystalline matrix. Results obtained from a list of grains sorted bycrystallographic orientation depict the strain states within and amongindividual grains. Locating the grain positions in the planeperpendicular to the incident beam is trivial. However, determining theexact location of grains within a 3-D space is challenging. Determiningthe depth of the grains within the matrix (along the beam direction)involved a triangulation method tracing individual rays that producespots on the CCD back to the point of origin. Triangulation wasexperimentally implemented by simulating a 3-D detector capturingmultiple diffraction images while increasing the camera to sampledistance. Hence by observing the intersection of rays from multiple spotsbelonging to the corresponding grain, depth is calculated. Depthresolution is a function of the number of images collected, grain to beamsize ratio, and the pixel resolution of the CCD. The 4DXRD methodprovides grain morphologies, strain …
Date: December 31, 2006
Creator: Bale, Hrishikesh A.; Hanan, Jay C. & Tamura, Nobumichi
System: The UNT Digital Library
Deducing the 237U destruction cross-sections using the Surrogate Ratio Method (open access)

Deducing the 237U destruction cross-sections using the Surrogate Ratio Method

We have deduced the destruction cross section of {sup 237}U via the (n, {gamma}) and (n,2n) reactions over an equivalent neutron energy range of 0 to 20 MeV using a new form of the Surrogate Ratio method [1-4] . The relative fission and neutron-evaporation decay probabilities of excited {sup 238}U populated via the ({alpha},{alpha}{prime}) inelastic scattering were measured using the silicon telescope array for reaction studies (STARS) coupled to the Livermore Berkeley array for collaborative experiments (LIBERACE). These relative probabilities were then combined with the {sup 237} U(n,f) cross section deduced by Burke et al., [4] to deduce the (n, {gamma}) and (n,2n) cross sections in a model independent fashion. These cross sections are then compared to the compound reaction cross section calculated using an optical model calculation tuned to reproduce scattering data in the transactinide region. Our results presented and the prospects for using this technique to deduce (n,x) cross sections on radioactive nuclei are discussed.
Date: March 31, 2006
Creator: Bernstein, L. A.; Burke, J. T.; Ahle, L.; Church, J. A.; Escher, J.; Dietrich, F. S. et al.
System: The UNT Digital Library
X-ray Digital Radiography and Computed Tomography of ICF and HEDP Materials, Subassemblies and Targets (open access)

X-ray Digital Radiography and Computed Tomography of ICF and HEDP Materials, Subassemblies and Targets

Inertial confinement fusion (ICF) and high energy density physics (HEDP) research are being conducted at large laser facilities, such as the University of Rochester's Laboratory for Laser Energetics OMEGA facility and the Lawrence Livermore National Laboratory's (LLNL) National Ignition Facility (NIF). At such facilities, millimeter-sized targets with micrometer structures are studied in a variety of hydrodynamic, radiation transport, equation-of-state, inertial confinement fusion and high-energy density experiments. The extreme temperatures and pressures achieved in these experiments make the results susceptible to imperfections in the fabricated targets. Targets include materials varying widely in composition ({approx}3 < Z < {approx}82), density ({approx}0.03 to {approx}20 g/cm{sup 3}), geometry (planar to spherical) and embedded structures (joints to subassemblies). Fabricating these targets with structures to the tolerances required is a challenging engineering problem the ICF and HEDP community are currently undertaking. Nondestructive characterization (NDC) provides a valuable tool in material selection, component inspection, and the final pre-shot assemblies inspection. X-rays are a key method used to NDC these targets. In this paper we discuss X-ray attenuation, X-ray phase effects, and the X-ray system used, its performance and application to characterize low-temperature Raleigh-Taylor and non-cryogenic double-shell targets.
Date: May 31, 2006
Creator: Brown, W. D. & Martz, H. E., Jr.
System: The UNT Digital Library
Transgenic Medicago truncatula plants obtained from Agrobacterium tumefaciens-transformed roots and Agrobacterium rhizogenes-transformed hairy roots (open access)

Transgenic Medicago truncatula plants obtained from Agrobacterium tumefaciens-transformed roots and Agrobacterium rhizogenes-transformed hairy roots

Article on transgenic Medicago truncatula plants obtained from Agrobacterium tumefaciens-transformed roots and Agrobacterium rhizogenes-transformed hairy roots.
Date: January 9, 2006
Creator: Crane, Cynthia; Wright, Elane; Dixon, R. A. & Wang, Z.-Y. (Zeng-Yu), 1963-
System: The UNT Digital Library
Kinetic and Prediction of Hydrogen Outgassing from Lithium Hydride (open access)

Kinetic and Prediction of Hydrogen Outgassing from Lithium Hydride

In most industrial or device applications, LiH is placed in either an initially dry or a vacuum environment with other materials that may release moisture slowly over many months, years, or even decades. In such instances, the rate of hydrogen outgassing from the reaction of LiH with H{sub 2}O can be reasonably approximated by the rate at which H{sub 2}O is released from the moisture containing materials. In a vacuum or dry environment, LiOH decomposes slowly with time into Li{sub 2}O even at room temperature according to: 2LiOH(s) {yields} Li{sub 2}O(s) + H{sub 2}O(g) (1). The kinetics of the decomposition of LiOH depends on the dryness/vacuum level and temperature. It was discovered by different workers that vacuum thermal decomposition of bulk LiOH powder (grain sizes on the order of tens to hundreds of micrometers) into Li{sub 2}O follows a reaction front moving from the surface inward. Due to stress at the LiOH/vacuum interface and defective and missing crystalline bonding at surface sites, lattice vibrations at the surfaces/interfaces of most materials are at frequencies different than those in the bulk, a phenomenon observed in most solids. The chemical reactivity and electronic properties at surfaces and interfaces of materials are also different …
Date: August 31, 2006
Creator: Dinh, L. N.; Schildbach, M. A.; Smith, R. A.; Balazs, B. & McLean, W., II
System: The UNT Digital Library
2006 Molecular and Ionic Clusters Conference - to be held February 19-24, 2006 (open access)

2006 Molecular and Ionic Clusters Conference - to be held February 19-24, 2006

The Gordon Research Conference (GRC) on MOLECULAR & IONIC CLUSTERS was held at Crowne Plaza from 2/19/2006 thru 2/24/2006. The Conference was well-attended with 89 participants (attendees list attached). The attendees represented the spectrum of endeavor in this field coming from academia, industry, and government laboratories, both U.S. and foreign scientists, senior researchers, young investigators, and students. In designing the formal speakers program, emphasis was placed on current unpublished research and discussion of the future target areas in this field. There was a conscious effort to stimulate lively discussion about the key issues in the field today. Time for formal presentations was limited in the interest of group discussions. In order that more scientists could communicate their most recent results, poster presentation time was scheduled. Attached is a copy of the formal schedule and speaker program and the poster program. In addition to these formal interactions, ''free time'' was scheduled to allow informal discussions. Such discussions are fostering new collaborations and joint efforts in the field.
Date: July 31, 2006
Creator: Duncan, Michael A.
System: The UNT Digital Library
The Value of Distributed Generation under Different TariffStructures (open access)

The Value of Distributed Generation under Different TariffStructures

Distributed generation (DG) may play a key role in a modern energy system because it can improve energy efficiency. Reductions in the energy bill, and therefore DG attractiveness, depend on the electricity tariff structure; a system created before widespread adoption of distributed generation. Tariffs have been designed to recover costs equitably amongst customers with similar consumption patterns. Recently, electric utilities began to question the equity of this electricity pricing structure for standby service. In particular, the utilities do not feel that DG customers are paying their fair share of transmission and distribution costs - traditionally recovered through a volumetric($/kWh) mechanism - under existing tariff structures. In response, new tariff structures with higher fixed costs for DG have been implemented in New York and in California. This work analyzes the effects of different electricity tariff structures on DG adoption. First, the effects of the new standby tariffs in New York are analyzed in different regions. Next generalized tariffs are constructed, and the sensitivity to varying levels of the volumetric and the demand ($/kW, i.e. maximum rate) charge component are analyzed on New York's standard and standby tariff as well as California's standby tariff. As expected, DG profitability is reduced with standby …
Date: May 31, 2006
Creator: Firestone, Ryan; Magnus Maribu, Karl & Marnay, Chris
System: The UNT Digital Library
El Nino - La Nina Implications on Flood Hazard Mitigation (open access)

El Nino - La Nina Implications on Flood Hazard Mitigation

The effects of El Nino and La Nina periods on the maximum daily winter period depths of precipitation are examined using records from five precipitation gages on the Nevada Test Site. The potential implications of these effects are discussed.
Date: March 31, 2006
Creator: French, R. & Miller, J.
System: The UNT Digital Library
Sensitivity Enhancement by Exchange Mediated MagnetizationTransfer of the Xenon Biosensor Signal (open access)

Sensitivity Enhancement by Exchange Mediated MagnetizationTransfer of the Xenon Biosensor Signal

Hyperpolarized xenon associated with ligand derivitized cryptophane-A cages has been developed as a NMR based biosensor. To optimize the detection sensitivity we describe use of xenon exchange between the caged and bulk dissolved xenon as an effective signal amplifier. This approach, somewhat analogous to 'remote detection' described recently, uses the chemical exchange to repeatedly transfer spectroscopic information from caged to bulk xenon, effectively integrating the caged signal. After an optimized integration period, the signal is read out by observation of the bulk magnetization. The spectrum of the caged xenon is reconstructed through use of a variable evolution period before transfer and Fourier analysis of the bulk signal as a function of the evolution time.
Date: August 31, 2006
Creator: Garcia, Sandra; Chavez, Lana; Lowery, Thomas J.; Han, Song-I; Wemmer, David E. & Pines, Alexander
System: The UNT Digital Library
Study of Vacuum Insulator Flashover for Pulse Lengths of Multi-Microseconds (open access)

Study of Vacuum Insulator Flashover for Pulse Lengths of Multi-Microseconds

We are studying the flashover of vacuum insulators for applications where high voltage conditioning of the insulator and electrodes is not practical and for pulse lengths on the order of several microseconds. The study is centered about experiments performed with a 100-kV, 10-ms pulsed power system and supported by a combination of theoretical and computational modeling. The base line geometry is a cylindrically symmetric, +45{sup o} insulator between flat electrodes. In the experiments, flashovers or breakdowns are localized by operating at field stresses slightly below the level needed for explosive emissions with the base line geometry. The electrodes and/or insulator are then seeded with an emission source, e.g. a tuft of velvet, or a known mechanical defect. Various standard techniques are employed to suppress cathode-originating flashovers/breakdowns. We present the results of our experiments and discuss the capabilities of modeling insulator flashover.
Date: July 31, 2006
Creator: Houck, T. L.; Goerz, D. A.; Javedani, J. B.; Lauer, E. J.; Tully, L. K. & Vogtlin, G. E.
System: The UNT Digital Library
Comparison of ALINGAAS/GAAS Superlattice Photocathodes Having Low Conduction Band Offset (open access)

Comparison of ALINGAAS/GAAS Superlattice Photocathodes Having Low Conduction Band Offset

The main advantage of superlattice (SL) structures as spin polarized electron emitters is the ability to provide a large splitting between the heavy hole (HH) and light hole (LH) valence bands (VB) over a large active thickness compared to single strained layers. Two important depolarization mechanisms in these structures are the scattering effects during the transit of the electrons in the active region and the depolarization that takes place in the band bending region (BBR) near the surface. In this paper, we systematically study the effects of the electron mobility and transit time by using an InAlGaAs/GaAs SL with a flat conduction band (CB). Initial results by the SPTU-SLAC collaboration using such structures grown by the Ioffe Institute showed polarization and quantum yield (QE) of 92% and 0.2% respectively. We report measurements using similar structures grown by SVT Associates. The results (polarization up to 90%) are also compared with simulations.
Date: March 31, 2006
Creator: Ioakeimidi, K.; Maruyama, T.; Clendenin, J. E.; Brachmann, A.; Garwin, E. L.; Kirby, R. E. et al.
System: The UNT Digital Library
H(curl) Auxiliary Mesh Preconditioning (open access)

H(curl) Auxiliary Mesh Preconditioning

This paper analyzes a two-level preconditioning scheme for H(curl) bilinear forms. The scheme utilizes an auxiliary problem on a related mesh that is more amenable for constructing optimal order multigrid methods. More specifically, we analyze the case when the auxiliary mesh only approximately covers the original domain. The latter assumption is important since it allows for easy construction of nested multilevel spaces on regular auxiliary meshes. Numerical experiments in both two and three space dimensions illustrate the optimal performance of the method.
Date: August 31, 2006
Creator: Kolev, T V; Pasciak, J E & Vassilevski, P S
System: The UNT Digital Library
Localized Corrosion Susceptibility Of Alloy 22 In Na-K-Cl_NO3 Brines At 110 To 150?C (open access)

Localized Corrosion Susceptibility Of Alloy 22 In Na-K-Cl_NO3 Brines At 110 To 150?C

Electrochemical cyclic potentiodynamic polarization experiments were conducted to assess crevice corrosion of Alloy 22 in de-aerated aqueous solutions of chloride and nitrate salts of potassium and sodium in the temperature range 110-150 C. The tests were run in neutral and slightly acidic aqueous solutions. The Alloy 22 specimens were multiple creviced weld prisms. No evidence of crevice corrosion was observed in the range 125-150 C. In the 120 to 160 C temperature range, the anionic concentration of stable aqueous solutions is dominated by nitrate relative to chloride. At nominally 120 C, the minimum nitrate to chloride ratio is about 4.5, and it increases to about 22 at nominally 155 C. The absence of localized corrosion susceptibility in these solutions is attributed to the known inhibiting effect of the nitrate anion. Aqueous solution chemistry studies indicate that nitrate to chloride ratios of less than 0.5 are possible for temperatures up to nominally 116 C. At 110 C, aqueous solutions can have dissolved chloride well in excess of nitrate. Localized corrosion was observed at nitrate to chloride ratios up to 1.0, the highest ratio tested. The extent of localized corrosion was confined to the crevice region of the samples, and was limited …
Date: March 31, 2006
Creator: Lian, T; Felker, S J; Hailey, P D; Staggs, K J & Gdowski, G E
System: The UNT Digital Library
Molecular Mechanism of Metal-Chalcogen Bond Formation in theSynthesis of Colloidal II-VI Semiconductor Nanocrystals (open access)

Molecular Mechanism of Metal-Chalcogen Bond Formation in theSynthesis of Colloidal II-VI Semiconductor Nanocrystals

None
Date: July 31, 2006
Creator: Liu, Haitao; Owen, Jonathan S. & Alivisatos, A. Paul
System: The UNT Digital Library
LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles (open access)

LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles

To improve the LSM-YSZ cathode performance of intermediate temperature solid oxide fuel cells (SOFCs), Sm0.6Sr0.4CoO3-sigma (SSC) perovskite nanoparticles are incorporated into the cathodes by a reaction-infiltration process. The SSC particles are {approx}20 to 80nm in diameter, and intimately adhere to the pore walls of the preformed LSM-YSZ cathodes. The SSC particles dramatically enhance single-cell performance with a 97 percent H2+3 percent H2O fuel, between 600 C and 800 C. Consideration of a simplified TPB (triple phase boundary) reaction geometry indicates that the enhancement may be attributed to the high electrocatalytic activity of SSC for electrochemical reduction of oxygen in a region that can be located a small distance away from the strict triple phase boundaries. The implication of this work for developing high-performance electrodes is also discussed.
Date: January 31, 2006
Creator: Lu, Chun; Sholklapper, Tal Z.; Jacobson, Craig P.; Visco, StevenJ. & De Jonghe, Lutgard C.
System: The UNT Digital Library
LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles (open access)

LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles

None
Date: January 31, 2006
Creator: Lu, Chun; Sholklapper, Tal Z.; Jacobson, Craig P.; Visco, StevenJ. & DeJonghe, Lutgard C.
System: The UNT Digital Library