Discussion of laboratory tests to reduce uranium corrosion.

Report on the determination of several physical properties, pertinent to uranium extraction, for a number of ethers and related compounds.

From abstract: "This report describes a functional mercury vapor detector which is a portable, self-contained, survey instrument, and had a minimum range from zero to two-tenths milligram of mercury per cubic meter of air."

From abstract: The planes and modes of fracture as a result of the mixture of beryllium and other elements were investigated.

From abstract: "The variation of the reactivity of a pile as a function of width of a transverse gap is obtained. The method involves first finding the boundary condition satisfied by the flux at the gap face. This, in principle, provides enough information for a complete solution of the pile equations. A method for calculating the reactivity change is presented. The calculated reactivity is compared with experiment and a brief discussion of the validity of the approximations is given."

From summary: "The influence of the structure of phosphate esters on the distribution coefficient of uranium between solutions of these esters in carbon tetrachloride and aqueous nitrate solutions has been studied. Esters of secondary alcohols showed higher distribution coefficients than primary alcohols. Phenyl esters extracted less uranium than alkyl esters, and the presence of other negative groups also resulted in less extraction. Compounds containing carbon to phosphorus bonds gave higher distribution coefficients than the corresponding esters, and the distribution coefficients increased with the number of such carbon to phosphorus bonds. Tributyl phosphine oxide (with three carbon to phosphorus bonds) showed high distribution coefficients with many salts, including uranyl nitrate, uranyl sulfate, uranyl chloride, thorium nitrate, plutonium (IV) nitrate and some of the fission products in nitrate solution. It is planned to study these and similar compounds further."

From abstract: "On the 86-inch cyclotron a 41-kw beam has been calorimetered at a net ion loading efficiency of 40%; the average proton current was 1.85 ma at 22.5 Mev. Practical specific yields have been determined for (p,2n) reactions on zinc and bismuth. The investigation of products of proton-induced fission of uranium has been continued and new techniques are being used in measuring angular distribution of reaction products. The 63-inch heavy particle cyclotron is now in operation; N+++ particles have been accelerated to ~25 Mev. In preliminary tests, induced activities have been detected in carbon, nitrogen, and oxygen targets. A hot-cathode ion source is ready for test operation. The 22-inch cyclotron is being used in an investigation of the problems associated with the use of rf and dc electrodes for the acceleration of protons from the ion source into the dees. Radiation-induced corrosion in Inconel tubing containing #21 eutectic (ANP) has been produced by proton irradiation in the 86-inch cylclotron; it is shown that the corrosion was not due to thermal effects. Approximately 150 grams of highly purified U 238 (< 5 ppm U 235) have been prepared, and two grams of thorium 230 (ionium) has been enriched to 90.6%."

Abstract: "The analysis of an immobilized plasma is here extended to the case where the geometry is cylindrical rather than Cartesian. (This report, UCRL-4439 (Rev, 4 constitutes Part II of the report series (UCRL-4466, Parts I, III, and IV) dealing with this general problem.)"

Abstract: Mine mapping of the tyuyamunite-type deposits In the Salt Wash member of the Jurassic Morrison formation of the Lukachukai Mountains, Apache County, Arizona revealed recognizable spatial relationships between ore mineralization and: fractured areas, sedimentary features, and interstitial carbonate.

Subject: This report presents an investigation of a reportedly large low-grade ore body in the vicinity of Cameron, Arizona.

Proceedings of the 1958 Nuclear Merchant Ship Symposium.

Abstract: The concept of a tapered fluidized bed is explored briefly. Data are given showing that in bench scale apparatus a tapered bed gives better fluidization with some materials that are difficult to fluidize in a conventional cylindrical bed.

Abstract: The objective of Project 32.3 was to evaluate some operational characteristics of a radiological shelter and to determine values for some countermeasures-system parameters.

Abstract The phase diagram of the uranium-rhenium alloy system is presented along with a discussion on transformation kinetics of the uranium solid solutions. The phase diagram is of the double eutectic type with the intermediate phase having the composition URe2. This phase exhibits allotropy at 180°C and melts congruently at 2200°C. URe2 reacts sluggishly with the uranium solid solutions below 750°C to form the peritectoid compound U2Re. Eutectic reactions occur at 1105° and 2105°C at respective compositions of 10.5 and 65.5 wt. % Re. Eutectoid reactions occur at 643° and 681°C at compositions of 1.4 and 6 wt. % Re, respectively. The maximum solubility of rhenium in α uranium is about 0.4 wt. % at 643°C and in β uranium is 1.9 wt. % at 681°C. The solubility of rhenium in γ uranium is 6 wt. % at 681°C and increases to about 7 wt. % at 975°C. The solubility of uranium in rhenium is 0.6 wt. % at room temperature with little variation up to 2000°C. Alloys of β and γ uranium containing more than about 1.2 and 7 wt. % Re respectively, can be readily supercooled to room temperature. Rapid cooling of γ alloys containing less than about …

The following report on the nuclear synthesis of technetium is based on work performed under contract No. W-7405-eng-26 for the Atomic Energy Project at Oak Ridge National Laboratory.

The following report discusses the renewed element 43, or eka-manganese, whose discovery was heralded in 1925, but whose chemical properties remained unreported until the radiochemical investigations of Perrier and Segre."

From summary: Graphs of various gamma radiation spectra, taken by plotting data from a single channel pulse height analyzer, are compared with photographs of gamma radiation spectra presented on the tube face of the Hughes Memoscope Model 104.

Abstract: "A method of recovering the tuballoy from the trap washes of the high temperature salvage chlorinator is described."

From abstract: "A simple electronic circuit is described, the use of which greatly improves the temperature regulations obtainable with Beta equipment. The circuit utilizes the time derivative of the temperature to counteract oscillation and overshoot. No other changes are required in existing equipment for installation of the stabilizer."

Abstract: Twenty-two metallic oxides were refluxed with hexachloropropylene. The anhydrous chlorides or other products formed are described for each oxide. The reactions were particularly vigorous with higher valent oxides of the fifth and sixth group elements.

The following report measures a shield mockup in three regions: the first made almost entire of iron; the second, transition, region is made of various thicknesses of B4C; and the third region was borated water. The iron samples used in the experiments were made in the form of rectangular plates and place in the lid tank; however, the plates were not completely flat and created a water gap that was measured in this report.

An attempt to apply quantitatively the equation of state of a free electron gas to relatively low temperatures in order to emphasize correlation effects.

The following report describes the crystal structures of NpC and Pu2O3 identified by x-ray diffraction.

Abstract: The radiations of U²³⁷ have been studied using a magnetic lens beta ray spectrometer and scintillation spectrometers for betas and gammas singly and in coincidence. A beta with an end point energy of 245 keV was found along with evidence for the existence of lower energy components. Gammas of energy 27, 42, 49, 59, 166, 208, 269, 354, 431, and 467 keV were found, and probably a gamma of 102 keV. The decay scheme constructed gives a total decay energy for this isotope of 512 keV.