Under the stimulus of electronic materials development - particularly thin-film studies - and the need for space environmental simulation chambers, a very rapid increase in the availability of industrial-sized vacuum components and systems operable in the ultrahigh vacuum range has taken place in the last three years. It is the purpose of this paper to explore the design considerations of ultrahigh vacuum systems for metallurgical applications.

Nuclear excavation is the name given to the concept of using large scale nuclear explosion craters for useful projects, such as harbors, canals, and roadway cuts. It is one of the principal applications of the Plowshare Program for industrial, or peaceful, uses of nuclear explosives. Plowshare is sponsored by the U.S. Atomic Energy Commission and is under the technical direction of the Lawrence Radiation Laboratory at Livermore, California. The purpose of this paper is to describe cratering concepts and the present state of nuclear excavation technology. The general nature of the safety hazards associated with nuclear excavation are also discussed.

Technical report. From Abstract : "A system has been developed to program a digital computer in much the same manner as an analog computer is programmed. Properties of a general purpose analog computer and a digital differential analyzer are combined to yield a program which employs, as input, standard data cards prepared from a diagram analogous to an analog computer diagram. The capacity of the system is much greater than that of most analog computers, making it applicable to large simulation problems. No scaling is required. The system is compatible with the Fortran symbolic language and may be used as part of a larger digital computer program. It may be applied to the more general types of boundary value problems arising in process simulation in addition to the initial value problems ordinarily solved on analog computers. It is particularly well adapted to non-linear problems and to control problems involving large transport delays. The program operates in basic machine language and, when used by itself, requires no compilation time."

Abstract. By means of the pulse radiolysis technique a short-lived transient species has been observed in irradiated de-aerated ethanol and methanol, exhibiting an optical absorption throughout the visible and near infra-red. This transient is suggested to be the solvated electron on the basis of the nature of the spectrum, the reactivity with hydrogen ion and with various organic electron acceptors, and the formation of mononegative ions of some of these acceptors. The absolute rate constants have been determined for the reactions of the solvated electron with hydrogen ion, oxygen and benzyl chloride in ethanol and methanol. The diphenylide ion was found to be short-lived in ethanol. The absolute rate constant for the first-order decay of the diphenylide ion has been determined.

Technical report. Form Abstract : "Perchlorate is extracted from aqueous solution by n-butyronitrile as ferrous 1,10-phenanthroline perchlorate. The amount of perchlorate is calculated from spectrophotometric measurement of the absorbance of the extract. Moderate to large amounts of chloride, sulfate, or nitrate cause little or no interference. Chlorate is slightly extracted but the interference can be corrected."

Technical report. From Abstract : "The stoichiometric formula of the lower chloride in the BiCl3-Bi system has been established as Bi12Cl14 (BiCl1.167) through a dingle crystal, X-ray determination of its structure. ... Previous studies of the Bi-Cl3-Bi system are re-examined in the light of the structural results."

The following report summarizes an investigation made to determine the extent to which zirconium and zirconium alloys exhibit delayed failure as caused by a combination of absorbed hydrogen and applied stress during the period September 15, 1961, to September 14, 1962.

The alternating-gradient proton synchrotrons at CERN and Brookhaven are very similar in size, design and in their experimental use. For this reason, collaboration between the groups at CERN and Brookhaven has been close throughout the history of these two machines. For the most part this has taken the form of exchanges of visits of individual machine designers and of high-energy physicists. By 1962, however, it appeared that the reciprocal flow of information was not adequate and a more formal meeting was arranged. This meeting took place at Brookhaven during the week of September 10, 1962. CERN sent a representative group of machine physicists and high-energy physicists. The meeting was attended also by observers from several American high-energy installations. The discussion covered a wide range of topics, from operating characteristics of the machines themselves to future trends in design of experimental equipment. Plans for beam ejection were presented, techniques were described for better use of secondary beams from internal targets, progress was summarized on dc and rf particle separators. and future trends in neutrino experimentation were predicted.

Technical report. From Abstract : "Paramagnetic susceptibilities of samarium structure alloys in the systems La-Gd, Nd-Y, Nd-Tm, and Ce-Y were measured from 4.2 - 300°K to determine what effect the formation of this structure has on the magnetic properties of the alloys. Susceptibility maxima were observed in the Nd-Y and Nd-Tm alloys, at 34.5 and 28.5°K, respectively. Slope changes were observed in the curve of 1/x versus T for the La-Gd alloy at 155 and 130°K, and the susceptibility of this alloy remained temperature-independent from 130-7°K. A rather poorly defined region of constant susceptibility was also observed or the Ce-Y alloy, from 26-37°K. Above these transition temperatures, the alloys obeyed the Curie-Weiss law, the susceptibilities of the La-Gd and Ce-Y samples indicating the possibility of electron transfer occurring in these cases."

The Fuel Cycle Program is an integrated program of investigation in the Vallecitos Boiling Water Reactor (VBWR) and other facilities to improve the technological limits of boiling water reactors in several areas. This report presents updates on tasks related to those areas.

Abstract: Distribution coefficients have been measured for the partition of metal ions between cation exchange resin and acetone-water-hydrochloric acid solutions. the differences in distribution coefficients of metal ions are greater in acetone-water media than in aqueous media of the same hydrochloric acid concentration. Using distribution coefficient data, conditions for column separations of mixtures can be selected. Column separations of metal ion mixtures can be effected by eluting with acetone-water-hydrochloric acid solutions of different compositions. Successful separations of a number of mixtures are reported.

From introduction: "The over-all objective of the present study was to determine the nature and extent of the present study was to determine the nature and extent of the corrosion of these materials under a variety of such storage conditions and to determine the ability of several potential protective coatings to retard this corrosion."

Abstract: "Theoretical equations have been derived for calculating heat transfer coefficients for fluids flowing through concentric annuli for the following two cases: (A) constant and equal heat fluxes from both walls, and (B) constant, but unequal, heat fluxes from the walls, with equal wall temperatures at a given axial position along annular channel. In the derivations, the conditions of fully-established flow, and independence of physical properties with temperature variation across the flow channel, were assumed. The only geometrical parameter in this general case is the radius ratio r2/r1, and in the study it was varied from 1.0 to 10.0."

The following report is the first semi-annual report of a literature survey designed to investigate the uses and technology of radioisotopes in the countries of the world from 1955 to the present. This survey includes two phases: 1) involves the direct comparison of radioisotopic work in all fields in various countries as demonstrated at international conferences. 2) involves a more detailed examination and evaluation of the individual fields of interest selected previously (Phase II is also expected to comprise the bulk of the remainder of this investigation).

This report summarizes progress on investigation into improving the technological limits of boiling water reactors, Vallecitos Boiling Water Reactor and other facilities.

This paper reports an extension of previous experimental work with Alfven waves. We consider hydromagnetic waves propagating in a cylindrical plasma in a uniform axial magnetic field. The copper tube is filled with highly ionized plasma by an electrically driven switch-on ionizing wave. After the tube is filled with plasma, a hydromagnetic wave is induced by a radial current flow from the small molybdenum electrode to the copper tube. The force produced by this radial current together with the static axial magnetic field displaces the plasma in the azimuthal direction, and a transverse wave is propagated in the axial direction, along magnetic field lines. The transient magnetic field associated with the wave is also in the azimuthal direction.

A research and development program aimed at devising processes for the economical recovery of the potentially valuable long-lived fission products from Purex waste has been under wat at Hanford for several years. When this work has begun, the concentrated waste was primarily a nitric acid solution (6 to 10 M HNO3) containing the fission products and relatively small concentrations of iron, sulfate, and other corrosion products. Flowsheets based on classical separation schemes and rather similar to processes used by the Isotopes Division at the AEC's Oak Ridge operation served to separate the desired fission products from one another and from the corrosion products (1,2,3).These separation schemes employed careful step-wise pH adjustment to precipitate first the iron and then to separate the desired fission products from one another. The flowsheets were demonstrated on a pilot-plant scale with full-level plant waste. However, since the earlier work was complete, plant operations have been modified....

Writing the VARI-II Program was motivated by the need for a method of analyzing the results for the Absorber Burn-Up Experiment in progress at the Vallecitos Atomic Laboratory.

This program was established to develop new information concerning the mechanism of diffusion of fission gases (krypton and xenon) through UO2 and UC. The work was to concentrated on measurements of diffusion rates in unirradiated materials in the temperature range of 1000°C to above 2000°C, these determinations being important to the projected use of refractory fuel materials in high-temperature, high-burnup reactors.

A nonnuclear explosion involving an evaporator occurred in a shielded cell in the Radiochemical Processing Pilot plant at Oak Ridge National Laboratory. Plutonium released from the processing cell contaminated areas in the pilot plant building and nearby streets and building surfaces. The explosion is considered the result of rapid reaction of nitrated organic compounds formed by the inadvertent nitration of about 14 liters of a proprietary decontaminating reagent.

The computer program which performs spatial reconstruction of events photographed in a bubble chamber is required to eliminate human and digitizer errors. It recognizes and corrects for single nuclear scatterings in the presence of multiple Coulomb scatterings. Momentum components are determined and kinematic constraints are applied. Measured parameters are performed into special reference frames and quantities of physical interest are calculated. Results are stored in a tape file containing all events of one reaction type.

Simon (1960) has given a general steady state theory of plasma accumulation (without energy losses) in an OGRA device. Such a device is fed by injection of energetic molecular ions which dissociate to produce trapped protons. Initial trapping is achieved by dissociation in the background gas. Such a device is usually characterized by a critical input current of critical plasma density (a function of input current) above which plasma density builds up to a value limited by Coulomb-scattering losses. For a regime of operation of current interest at Oak Ridge National Laboratory (600-kev hydrogen molecular ion injection and dissociation, highly efficient ion-pumping action of the trapped plasma), extremely simple approximate formulas have been derived which describe with a fair degree of accuracy the critical current of density for plasma build-up.

The theory of mass transfer into a flowing fluid is utilizes to estimate the effect of gas film resistance on overall rates of transfer through a porous septum. The expressions developed for the mass transfer ratio...

Abstract. Fourteen commercial enamel frits from five different manufacturers were tested to determine their abilities to protect Nb-1% Zr during the forging cycle in the temperature range of 1800 to 2300 deg F. One frit was found to afford good coverage and protection at 2200 deg F at times up to 5 hours of exposure. Adherence was excellent during upset forging of a coated Nb--1% Zr sample heated 45 minutes at 2200 deg F. Another frit afforded good protection and coverage at 1700 deg F. (auth)