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Prediction of Corrosion of Alloys in Mixed-Solvent Environments (open access)

Prediction of Corrosion of Alloys in Mixed-Solvent Environments

Corrosion is much less predictable in organic or mixed-solvent environments than in aqueous process environments. As a result, US chemical companies face greater uncertainty when selecting process equipment materials to manufacture chemical products using organic or mixed solvents than when the process environments are only aqueous. Chemical companies handle this uncertainty by overdesigning the equipment (wasting money and energy), rather than by accepting increased risks of corrosion failure (personnel hazards and environmental releases). Therefore, it is important to develop simulation tools that would help the chemical process industries to understand and predict corrosion and to develop mitigation measures. To create such tools, we have developed models that predict (1) the chemical composition, speciation, phase equilibria, component activities and transport properties of the bulk (aqueous, nonaqueous or mixed) phase that is in contact with the metal; (2) the phase equilibria and component activities of the alloy phase(s) that may be subject to corrosion and (3) the interfacial phenomena that are responsible for corrosion at the metal/solution or passive film/solution interface. During the course of this project, we have completed the following: (1) Development of thermodynamic modules for calculating the activities of alloy components; (2) Development of software that generates stability diagrams …
Date: June 5, 2003
Creator: A. Anderko, P. Wang, R. D. Young, D. P. Riemer, P. McKenzie and M. M. Lencka (OLI Systems Inc.) & Laboratory), S. S. Babu and P. Angelini (Oak Ridge National
Object Type: Report
System: The UNT Digital Library
Secret Sessions of Congress: A Brief Historical Overview (open access)

Secret Sessions of Congress: A Brief Historical Overview

None
Date: August 5, 2003
Creator: Amer, Mildred L.
Object Type: Report
System: The UNT Digital Library
Altus Times (Altus, Okla.), Vol. 105, No. 147, Ed. 1 Friday, September 5, 2003 (open access)

Altus Times (Altus, Okla.), Vol. 105, No. 147, Ed. 1 Friday, September 5, 2003

Daily newspaper from Altus, Oklahoma that includes local, state, and national news along with advertising.
Date: September 5, 2003
Creator: Andrews, Mike
Object Type: Newspaper
System: The Gateway to Oklahoma History
Altus Times (Altus, Okla.), Vol. 105, No. 172, Ed. 1 Sunday, October 5, 2003 (open access)

Altus Times (Altus, Okla.), Vol. 105, No. 172, Ed. 1 Sunday, October 5, 2003

Daily newspaper from Altus, Oklahoma that includes local, state, and national news along with advertising.
Date: October 5, 2003
Creator: Andrews, Mike
Object Type: Newspaper
System: The Gateway to Oklahoma History
Altus Times (Altus, Okla.), Vol. 105, No. 199, Ed. 1 Wednesday, November 5, 2003 (open access)

Altus Times (Altus, Okla.), Vol. 105, No. 199, Ed. 1 Wednesday, November 5, 2003

Daily newspaper from Altus, Oklahoma that includes local, state, and national news along with advertising.
Date: November 5, 2003
Creator: Andrews, Mike
Object Type: Newspaper
System: The Gateway to Oklahoma History
Altus Times (Altus, Okla.), Vol. 105, No. 225, Ed. 1 Friday, December 5, 2003 (open access)

Altus Times (Altus, Okla.), Vol. 105, No. 225, Ed. 1 Friday, December 5, 2003

Daily newspaper from Altus, Oklahoma that includes local, state, and national news along with advertising.
Date: December 5, 2003
Creator: Andrews, Mike
Object Type: Newspaper
System: The Gateway to Oklahoma History
Broadband Internet Access: Background and Issues (open access)

Broadband Internet Access: Background and Issues

This report is about the Broadband Internet Access, The Background and analysis of Broadband. It's importance, and about broadband technologies like Cable, Satellite and other technologies. The status of Broadband Deployment and Development Issues.
Date: December 5, 2003
Creator: Angele. A
Object Type: Report
System: The UNT Digital Library
Evolution of Defects in Pu during Isochronal Annealing and Self Irradiation (open access)

Evolution of Defects in Pu during Isochronal Annealing and Self Irradiation

We report on the evolution of defects in Pu during isochronal annealing and self irradiation using positron annihilation spectroscopy. Positron annihilation spectroscopy is a sensitive probe (part per million level) for atomic-scale defects. The spectroscopic tools available at LLNL allow the determination of size, concentration, and chemical surroundings of defects in aged Pu samples. Positron lifetime analysis was performed on eight samples aged 7 months to 42 years. All samples except the 7-month old sample contained a high concentration of positron trapping centers. The dominant component yielded a lifetime value of {approx}182 ps. In aged samples, a second longer lifetime component was observed that appears to increase in strength with the age of the sample. The observed lifetime values and their relative strengths are shown in figure 1. The top panel corresponds to the lifetime values and the bottom panel corresponds to the intensity of the long lifetime component. Positron lifetime values are determined by the bubble size and He content. When He is added to a bubble, the positron lifetime is shortened due to the increased electron density. When the size of the bubble is known from an independent measurement, the observed positron lifetime values and the associated first …
Date: February 5, 2003
Creator: Asoka-Kumar, P; Glade, S; Sterne, P A & Howell, R
Object Type: Article
System: The UNT Digital Library
Mechanical Behavior and Fractography of 304 Stainless Steel with High Hydrogen Concentration (open access)

Mechanical Behavior and Fractography of 304 Stainless Steel with High Hydrogen Concentration

Hydrogen embrittlement of 304 stainless steel with different hydrogen concentrations has been investigated. An electrochemical technique was used to effectively charge the high level of hydrogen into 304 stainless steel in a short period of time. At 25 ppm of hydrogen, 304 stainless steel loses 10 percent of its original mechanical strength and 20 percent plasticity. Although the ductile feature dominates the fractography, the brittle crown area near the outer surface shows the intergranular rupture effected by hydrogen. At 60 ppm of hydrogen, 304 stainless steel loses 23 percent of its strength and 38 percent plasticity, where the brittle mode dominates the fracture of the materials. Experimental results show that hydrogen damage to the performance of 304 stainless steel is significant even at very low levels. The fractograph analysis indicates the high penetration ability of hydrogen in 304 stainless steel. This work also demonstrates the advantages of the electrochemical charging technique in the study of hydrogen embrittlement.
Date: February 5, 2003
Creator: Au, M.
Object Type: Article
System: The UNT Digital Library
Characterization and Operation of Liquid Crystal Adaptive Optics Phoropter (open access)

Characterization and Operation of Liquid Crystal Adaptive Optics Phoropter

Adaptive optics (AO), a mature technology developed for astronomy to compensate for the effects of atmospheric turbulence, can also be used to correct the aberrations of the eye. The classic phoropter is used by ophthalmologists and optometrists to estimate and correct the lower-order aberrations of the eye, defocus and astigmatism, in order to derive a vision correction prescription for their patients. An adaptive optics phoropter measures and corrects the aberrations in the human eye using adaptive optics techniques, which are capable of dealing with both the standard low-order aberrations and higher-order aberrations, including coma and spherical aberration. High-order aberrations have been shown to degrade visual performance for clinical subjects in initial investigations. An adaptive optics phoropter has been designed and constructed based on a Shack-Hartmann sensor to measure the aberrations of the eye, and a liquid crystal spatial light modulator to compensate for them. This system should produce near diffraction-limited optical image quality at the retina, which will enable investigation of the psychophysical limits of human vision. This paper describes the characterization and operation of the AO phoropter with results from human subject testing.
Date: February 5, 2003
Creator: Awwal, A.; Bauman, B.; Gavel, D.; Olivier, S.; Jones, S.; Hardy, J. L. et al.
Object Type: Article
System: The UNT Digital Library
A Model for the Behavior of Magnetic Tunnel Junctions (open access)

A Model for the Behavior of Magnetic Tunnel Junctions

A magnetic tunnel junction is a device that changes its electrical resistance with a change in an applied magnetic field. A typical junction consists of two magnetic electrodes separated by a nonmagnetic insulating layer. The magnetizations of the two electrodes can have two possible extreme configurations, parallel and antiparallel. The antiparallel configuration is observed to have the higher measured resistance and the parallel configuration has the lower resistance. To switch between these two configurations a magnetic field is applied to the device which is primarily used to change the orientation of the magnetization of one electrode usually called the free layer, although with sufficient high magnetic field the orientation of the magnetizations of both of the electrodes can be changed. The most commonly used models for describing and explaining the electronic behavior of tunnel junctions are the Simmons model and the Brinkman model. However, both of these models were designed for simple, spin independent tunneling. The Simmons model does not address the issue of applied magnetic fields nor does it address the form of the electronic band structure in the metallic electrodes, including the important factor of spin polarization. The Brinkman model is similar, the main difference between the two …
Date: August 5, 2003
Creator: Baker, Bryan John
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Assessment of Unabated Facility Emission Potentials for Evaluating Airborne Radionuclide Monitoring Requirements at Pacific Northwest National Laboratory - 2003 (open access)

Assessment of Unabated Facility Emission Potentials for Evaluating Airborne Radionuclide Monitoring Requirements at Pacific Northwest National Laboratory - 2003

Assessments were performed to evaluate compliance with the airborne radionuclide emission monitoring requirements in the National Emission Standards for Hazardous Air Pollutants (NESHAP - U.S. Code of Federal Regulations, Title 40, Part 61, Subpart H) and Washington Administrative Code (WAC) 246-247: Radiation Protection - Air Emissions. In these assessments, potential unabated offsite doses were evaluated for emission locations at facilities owned by the U.S. Department of Energy and operated by Pacific Northwest National Laboratory (PNNL) on the Hanford Site. This report describes the inventory-based methods and provides the results for the assessment performed in 2003.
Date: December 5, 2003
Creator: Ballinger, Marcel Y.; Sula, Monte J.; Gervais, Todd L. & Edwards, Daniel L.
Object Type: Report
System: The UNT Digital Library
Investigations of the Electronic Properties and Surface Structures of Aluminium-Rich Quasicrystalline Alloys (open access)

Investigations of the Electronic Properties and Surface Structures of Aluminium-Rich Quasicrystalline Alloys

The work presented in this dissertation has investigated three distinct areas of interest in the field of quasicrystals: bulk structure, transport properties, and electronic structure. First, they have described the results of a study which explored the fundamental interactions between the atomic species of the icosahedral Al-Pd-Mn quasicrystal. The goal of this work was to determine whether the pseudo-MacKay or Bergman type clusters have a special stability or are merely a geometric coincidence. This was carried out by using laser vaporization to produce gas-phase metal clusters, which were analyzed using time-of-flight mass spectrometry. Both the kinetic and thermodynamic stabilities of the clusters were probed. The data indicated no special stability for either pseudo-MacKay or Bergman type clusters as isolated units. This, however, is not proof that these clusters are simply a geometric coincidence. It is possible that such clusters only have stability in the framework of the bulk matrix and do not exist as isolated units. Next, they have reported their investigations of the bulk thermal transport properties of a decagonal Al-Ni-Co two dimensional quasicrystal in the temperature range 373K-873K. The properties of a sample oriented along the periodic axis and another oriented along the aperiodic axis were measured. A …
Date: August 5, 2003
Creator: Barrow, Jason A.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Actinic Mask Inspection at the ALS Initial Design Review (open access)

Actinic Mask Inspection at the ALS Initial Design Review

This report is the first milestone report for the actinic mask blank inspection project conducted at the VNL, which forms sub-section 3 of the Q1 2003 mask blank technology transfer program at the VNL. Specifically this report addresses deliverable 3.1.1--design review and preliminary tool design. The goal of this project is to design an actinic mask inspection tool capable of operating in two modes: high-speed scanning for the detection of multilayer defects (inspection mode), and a high-resolution aerial image mode in which the image emulates the imaging illumination conditions of a stepper system (aerial image or AIM mode). The purpose and objective of these two modes is as follows: (1) Defect inspection mode--This imaging mode is designed to scan large areas of the mask for defects EUV multilayer coatings. The goal is to detect the presence of multilayer defects on a mask blank and to store the co-ordinates for subsequent review in AIM mode, thus it is not essential that the illumination and imaging conditions match that of a production stepper. Potential uses for this imaging mode include: (a) Correlating the results obtained using actinic inspection with results obtained using other non-EUV defect inspection systems to verify that the non-EUV …
Date: March 5, 2003
Creator: Barty, A.; Chapman, H.; Sweeney, D.; Levesque, R.; Bokor, J.; Gullikson, E. et al.
Object Type: Report
System: The UNT Digital Library
Application of Reservoir Characterization and Advanced Technology to Improve Recovery and Economics in a Lower Quality Shallow Shelf San Andres Reservoir. Annual Report: August 3, 2000--August 2, 2001 (open access)

Application of Reservoir Characterization and Advanced Technology to Improve Recovery and Economics in a Lower Quality Shallow Shelf San Andres Reservoir. Annual Report: August 3, 2000--August 2, 2001

The OXY-operated Class 2 Project at West Welch is designed to demonstrate how the use of advanced technology can improve the economics of miscible CO{sub 2} injection projects in lower quality Shallow Shelf Carbonate reservoirs. The research and design phase (Budget Period 1) primarily involved advanced reservoir characterization. The current demonstration phase (Budget Period 2) is the implementation of the reservoir management plan for an optimum miscible CO{sub 2} flood design based on the reservoir characterization. Although Budget Period 1 for the Project officially ended 12/31/96, reservoir characterization and simulation work continued during the Budget Period 2. During the seventh annual reporting period (8/3/00-8/2/01) covered by this report, work continued on interpretation of the interwell seismic data to create porosity and permeability profiles which were distributed into the reservoir geostatistically. The initial interwell seismic CO{sub 2} monitor survey was conducted and the acquired data processed and interpretation started. Only limited well work and facility construction were conducted in the project area. The CO{sub 2} injection initiated in October 1997 was continued, although the operator had to modify the operating plan in response to low injection rates, well performance and changes in CO{sub 2} supply. CO{sub 2} injection was focused in …
Date: May 5, 2003
Creator: Beebe, Tom
Object Type: Report
System: The UNT Digital Library
Supplemental Appropriations FY2003: Iraq Conflict, Afghanistan, Global War on Terrorism, and Homeland Security (open access)

Supplemental Appropriations FY2003: Iraq Conflict, Afghanistan, Global War on Terrorism, and Homeland Security

None
Date: May 5, 2003
Creator: Belasco, Amy & Nowels, Larry
Object Type: Report
System: The UNT Digital Library
The Rice Thresher, Vol. 91, No. 3, Ed. 1 Friday, September 5, 2003 (open access)

The Rice Thresher, Vol. 91, No. 3, Ed. 1 Friday, September 5, 2003

A weekly student newspaper from the Rice University in Houston, Texas that includes campus news and commentaries along with advertising.
Date: September 5, 2003
Creator: Berenson, Mark
Object Type: Newspaper
System: The Portal to Texas History
The Rice Thresher, Vol. 91, No. 14, Ed. 1 Friday, December 5, 2003 (open access)

The Rice Thresher, Vol. 91, No. 14, Ed. 1 Friday, December 5, 2003

A weekly student newspaper from the Rice University in Houston, Texas that includes campus news and commentaries along with advertising.
Date: December 5, 2003
Creator: Berenson, Mark
Object Type: Newspaper
System: The Portal to Texas History
Intelligence Issues for Congress (open access)

Intelligence Issues for Congress

This report discusses intelligence issues for Congress including terrorism, conflicts between Israel and Palestine, in Iraq, and among the former Yugoslav states, and North Korean missile capabilities. Updated August 5, 2003.
Date: August 5, 2003
Creator: Best, Richard A., Jr.
Object Type: Report
System: The UNT Digital Library
LARGE AREA FILTERED ARC DEPOSITION OF CARBON AND BORON BASED HARD COATINGS (open access)

LARGE AREA FILTERED ARC DEPOSITION OF CARBON AND BORON BASED HARD COATINGS

This document is a final report covering work performed under Contract No. DE-FG02-99ER82911 from the Department of Energy under a SBIR Phase II Program. Wear resistant, hard coatings can play a vital role in many engineering applications. The primary goal of this project was to develop coatings containing boron and carbon with hardness greater than 30 GPa and evaluate these coatings for machining applications. UES has developed a number of carbon and boron containing coatings with hardness in the range of 34 to 65 GPa using a combination of filtered cathodic arc and magnetron sputtering. The boron containing coatings were based on TiB2, TiBN, and TiBCN, while the carbon containing coatings ere TiC+C and hydrogen free diamond-like-carbon. Machining tests were performed with single and multilayer coated tools. The turning and milling tests were run at TechSolve Inc., under a subcontract at Ohio State University. Significant increases in tool lives were realized in end milling of H-13 die steel (8X) and titanium alloy (80%) using the TiBN coating. A multilayer TiBN/TiN performed the best in end-milling of highly abrasive Al-Si alloys. A 40% increase in life over the TiAlN benchmark coating was found. Further evaluations of these coatings with commercialization partners …
Date: December 5, 2003
Creator: Bhattacharya, Rabi S.
Object Type: Report
System: The UNT Digital Library
Phenomenological aspects of heterotic orbifold models at one loop (open access)

Phenomenological aspects of heterotic orbifold models at one loop

We provide a detailed study of the phenomenology of orbifold compactifications of the heterotic string within the context of supergravity effective theories. Our investigation focuses on those models where the soft Lagrangian is dominated by loop contributions to the various soft supersymmetry breaking parameters. Such models typically predict non-universal soft masses and are thus significantly different from minimal supergravity and other universal models. We consider the pattern of masses that are governed by these soft terms and investigate the implications of certain indirect constraints on supersymmetric models, such as flavor-changing neutral currents, the anomalous magnetic moment of the muon and the density of thermal relic neutralinos. These string-motivated models show novel behavior that interpolates between the phenomenology of unified supergravity models and models dominated by the superconformal anomaly.
Date: August 5, 2003
Creator: Birkedal-Hansen, A.; Binetruy, P.; Mambrini, Y. & Nelson, B.
Object Type: Report
System: The UNT Digital Library
Recommendations for SZ/TSPA Model Uncertainty Analysis Concerning the Yucca Mountain Project (open access)

Recommendations for SZ/TSPA Model Uncertainty Analysis Concerning the Yucca Mountain Project

This report considers the problem of how best to evaluate the stability (i.e., sampling reliability) of Monte Carlo outputs obtained for two Yucca Mountain Project (YMP) modeling components, namely, outputs for the Saturated Zone (SZ) model, and for the Total System Performance Assessment (TSPA) model. One approach considered is the one that has been employed to date, namely, the application of Monte Carlo methods. Also considered in this context are potential improvements that might be obtained by the additional use of a Monte Carlo ''quitting rule'', such as that defined by Woo (1991), to select the number of Monte Carlo sample runs to perform. By the Monte Carlo approach, each output-value sample (realization) is calculated as a function of a sample-value vector of stochastic realizations, each of which in turn corresponds to a value of a corresponding distributed input variable. Abstractions from the SZ model and the Biosphere model are both used as input to the TSPA model. Sets of stochastic realizations required for SZ and TSPA abstractions ''expensive'' to generate, so the practical issue addressed by a ''quitting rule'' is how to determine what number of realizations is ''enough'' for the purpose of characterizing sampling error in the Monte …
Date: November 5, 2003
Creator: Bogen, K T
Object Type: Report
System: The UNT Digital Library
Joint Strike Fighter (JSF) Program: Background, Status, and Issues (open access)

Joint Strike Fighter (JSF) Program: Background, Status, and Issues

None
Date: February 5, 2003
Creator: Bolkcom, Christopher
Object Type: Report
System: The UNT Digital Library
Tactical Aircraft Modernization: Issues for Congress (open access)

Tactical Aircraft Modernization: Issues for Congress

None
Date: March 5, 2003
Creator: Bolkcom, Christopher
Object Type: Report
System: The UNT Digital Library