A stress corrosion cracking (SCC) model has been adapted for performance prediction of high level radioactive-waste packages to be emplaced in the proposed Yucca Mountain repository. For waste packages of the proposed Yucca Mountain repository, the outer barrier material is the highly corrosion-resistant Alloy UNS-N06022 (Alloy 22), the environment is represented by aqueous brine films present on the surface of the waste package from dripping or deliquescence of soluble salts present in any surface deposits, and the tensile stress is principally from weld induced residual stress. SCC has historically been separated into ''initiation'' and ''propagation'' phases. Initiation of SCC will not occur on a smooth surface if the surface stress is below a threshold value defined as the threshold stress. Cracks can also initiate at and propagate from flaws (or defects) resulting from manufacturing processes (such as welding); or that develop from corrosion processes such as pitting or dissolution of inclusions. To account for crack propagation, the slip dissolution/film rupture (SDFR) model is adopted to provide mathematical formulae for prediction of the crack growth rate. Once the crack growth rate at an initiated SCC is determined, it can be used by the performance assessment to determine the time to through-wall …

The issue of women’s rights in Iraq has taken on new relevance, following the U.S.-led invasion of Iraq in 2003, efforts to reconstruct Iraq, and recent elections for a Transitional National Assembly (TNA). Over the past three years, the Bush Administration has reiterated its interest in ensuring that Iraqi women participate in politics and ongoing reconstruction efforts in Iraq. There has also been a widening debate regarding the extent to which the U.S.-led reconstruction efforts have been able to enhance women’s rights in Iraq and encourage their participation in Iraq’s governing institutions.

An option to dispose of the High Activity Waste (HAW) stream from the processing of unirradiated materials directly to Saltstone is being evaluated to conserve High Level Waste (HLW) tank farm space and to reduce the future production of HLW glass logs. To meet the Saltstone Waste Acceptance Criteria (WAC), decanting the supernate from precipitated solids was proposed to reduce mercury and radionuclide levels in the waste. Only the caustic supernate will then be sent to Saltstone. Verification that the Saltstone WAC will be met has involved a series of laboratory studies using surrogate and actual HAW solutions from H-Canyon. The initial experiment involved addition of sodium hydroxide (NaOH) to a surrogate HAW test solution and subsequent decanting of the supernate away from the precipitated solids. The chemical composition of the surrogate solution was based on a composition defined from analyses of actual HAW solutions generated during dissolution of unirradiated nuclear materials in H-Canyon [1]. Results from testing the surrogate HAW solution were reported in Reference [2]. Information obtained from the surrogate test solution study was used to define additional experiments on actual HAW solutions obtained from H-Canyon. These experiments were conducted with samples from three different batches of HAW …

This document reports on risk reduction activities performed at the VNL during CY2003 as a part of the Lith-343 actinic inspection project funded by International SEMATECH. The risk reduction activities described in this document comprise deliverable items 3.1.3, 3.1.4, 3.1.5 and 3.1.6 of Amendment 6 to the VNL EUV mask blank technology transfer contract.

This report provides background information on defense-related environmental programs, analyzes key implementations issues, and examines final versions of legislation to authorize and appropriate funding for these activities for FY2004.

This report briefly discusses procedures regarding conference reports in the House of Representatives.

This report discusses how the Program Assessment Rating Tool (PART) is structured, how it has been used, and how various commentators have assessed its design and implementation. The report concludes with a discussion of potential criteria for assessing the PART or other program evaluations, which Congress might consider during the budget process, in oversight of federal agencies and programs, and in consideration of legislation that relates to the PART or program evaluation generally.

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Nucleation-growth kinetic expressions are derived for thermal decomposition of HMX from a variety of types of data, including mass loss for isothermal and constant rate heating in an open pan, and heat flow for isothermal and constant rate heating in open and closed pans. Conditions are identified in which thermal runaway is small to nonexistent, which typically means temperatures less than 255 C and heating rates less than 1 C/min. Activation energies are typically in the 140 to 150 kJ/mol regime for open pan experiments and about 160 kJ/mol for sealed pan experiments. Our activation energies are about 10% lower than those derived from data supplied by the University of Utah, which we consider the best previous work. The reaction clearly displays more than one process, and most likely three processes, which are most clearly evident in open pan experiments. The reaction is accelerated for closed pan experiments, and one global reaction appears to fit the data well.

Frequency domain substructure synthesis is a modeling technique that enables the prediction of a combined response of individual structures using experimentally measured or numerically predicted frequency response functions (FRFs). The traditional synthesis algorithm [1,2] operates on component impedances and thus generally requires several matrix inversions. An improved algorithm, developed by Jetmundsen et al. [3], requires a single matrix inversion with a completely arbitrary interface definition that can easily incorporate connection impedances. The main limitations of the method are the large data requirements and sensitivity to data truncation. The utility of this technique is demonstrated through a comparison of synthesized and measured admittances of an edge-stiffened plate with attached equipment. The plate mobilities are obtained from a numerical analysis because of the ability to accurately model this structure using a finite element representation. The attachments are characterized experimentally because of their complexity. The sections describe the synthesis technique and show numerical and experimental results for the plate and equipment.

Precipitation scavenging can effectively remove particulates from the atmosphere. Therefore, this process is of importance in the real-time modeling of atmospheric transport for hazardous materials. To account for the rainfall effect in LLNL operational dispersion model, a modified version of a standard below-cloud aerosol scavenging model has been developed to handle the emergency response in this scenario (Loosmore and Cerdewall, 2003, hereafter referred to as LC). Two types of rain data can be used to incorporate precipitation scavenging in the dispersion model; realtime measurements (rain gauge and radar), and model prediction. The former approach has been adopted in LC's study for the below-cloud scavenging problem based on the surface rain measurements. However, the in-cloud scavenging effect remains unresolved as a restriction of available real-time measurements in providing the vertical structure of precipitation systems. The objective of this study is to explore the possibility to incorporate three-dimensional precipitation structure of forecast data into the dispersion model. Therefore, both in-cloud and below-cloud scavenging effects can be included in LLNL aerosol scavenging model. To this end, a mesoscale model (Naval Research Laboratory 3-D weather forecast model, COAMPS) is used to demonstrate this application using a mid-west severe storm case occurring on July 18, …

This report is a guide to one of the 13 regular appropriations bills that Congress considers each year.

This project consists of two activities. Task A, Simulations and Measurements, combines all the material model development and associated numerical work with the materials-oriented experimental activities. The goal of this effort is to provide an improved understanding of dynamic material properties and to provide accurate numerical representations of those properties for use in analysis codes. Task B, ALE3D Development, involves general development activities in the ALE3D code with the focus of improving simulation capabilities for problems of mutual interest to DoD and DOE. Emphasis is on problems involving multi-phase flow, blast loading of structures and system safety/vulnerability studies.

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There is considerable impetus for identification of aqueous OM catalysts as water is the ultimate ''green'' solvent. In collaboration with researchers at Ames Lab, we investigated effective fragment and Monte Carlo techniques for aqueous-phase hydroformylation (HyF). The Rh of the HyF catalyst is weakly aquated, in contrast to the hydride of the Rh-H bond. As the insertion of the olefin C=C into Rh-H determines the linear-to-branched aldehyde ratio, it is reasonable to infer that solvent plays an important role in regiochemistry. Studies on aqueous-phase organometallic catalysis were complemented in studies of the gas-phase reaction. A Rh-carbonyl-phosphine catalyst was investigated. Two of the most important implications of this research include (a) pseudorotation among five-coordinate intermediates is significant in HyF, and (b) CO insertion is the rate-determining step. The latter is in contrast to experimental deductions, highlighting the need for more accurate modeling. To this end, we undertook studies of (a) experimentally relevant PR{sub 3} co-ligands (PMe{sub 3}, PPh{sub 3}, P(p-PhSO{sub 3{sup -}}){sub 3}, etc.), and (b) HyF of propene. For the propylene research, simulations indicated that the linear: branched aldehyde ratio (linear is more desirable) is determined by thermodynamic discrimination of two distinct pathways. Other projects include a theory-experiment study of …

The analysis of surrogate reactions, an indirect technique for determining cross sections on unstable nuclei, relies heavily on compound-nuclear reaction models. The purpose of this tutorial is to provide an introduction to the principal models, based on the Hauser-Feshbach and Weisskopf-Ewing formalisms, and to show how they are applied to surrogate reactions.

The purpose of this Model Report (REV02) is to document the unsaturated zone (UZ) models used to evaluate the potential effects of coupled thermal-hydrological-chemical (THC) processes on UZ flow and transport. This Model Report has been developed in accordance with the ''Technical Work Plan for: Performance Assessment Unsaturated Zone'' (Bechtel SAIC Company, LLC (BSC) 2002 [160819]). The technical work plan (TWP) describes planning information pertaining to the technical scope, content, and management of this Model Report in Section 1.12, Work Package AUZM08, ''Coupled Effects on Flow and Seepage''. The plan for validation of the models documented in this Model Report is given in Attachment I, Model Validation Plans, Section I-3-4, of the TWP. Except for variations in acceptance criteria (Section 4.2), there were no deviations from this TWP. This report was developed in accordance with AP-SIII.10Q, ''Models''. This Model Report documents the THC Seepage Model and the Drift Scale Test (DST) THC Model. The THC Seepage Model is a drift-scale process model for predicting the composition of gas and water that could enter waste emplacement drifts and the effects of mineral alteration on flow in rocks surrounding drifts. The DST THC model is a drift-scale process model relying on the …

Ultra-wideband (UWB) array signal processing has the distinct advantage in that it is possible to illuminate or focus on ''spots'' at distant points in space, as opposed to just illuminating or steering at certain directions for narrowband array processing. The term ''spotforming'' is used to emphasize the property that point-focusing techniques with UWB waveforms can be viewed as a generalization of the well-known narrowband beamforming techniques. Because methods in spotforming can lead to powerful applications for UWB systems, in this paper we derive, simulate and experimentally verify UWB spot size as a function of frequency, bandwidth and array aperture.

This report provides basic information on congressional salaries and allowances. First, the report briefly summarizes the current salary of Members of Congress, limits on their outside earned income and honoraria, and applicable health insurance and retirement benefits. Second, it provides information on allowances available to Representatives and Senators to support them in their official and representational duties as Members. Third, it provides the salaries and allowances available to the Speaker of the House and the Vice President, as President of the Senate, and lists the salaries of congressional officers and officials and committee staff.

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Many methods exist for identifying modal parameters from experimental transfer function measurements. For frequency domain calculations, rational fraction polynomials have become the method of choice, although it generally requires the user to identify frequency bands of interest along with the number of modes in each band. This process can be tedious, especially for systems with a large number of modes, and it assumes the user can accurately assess the number of modes present in each band from frequency response plots of the transfer functions. When the modal density is high, better results can be obtained by using the singular value decomposition to help separate the modes before the modal identification process begins. In a typical calculation, the transfer function data for a single frequency is arranged in matrix form with each column representing a different drive point. The matrix is input to the singular value decomposition algorithm and left- and right-singular vectors and a diagonal singular value matrix are computed. The calculation is repeated at each analysis frequency and the resulting data is used to identify the modal parameters. In the optimal situation, the singular value decomposition will completely separate the modes from each other, so that a single transfer …

The ''demo enclosure'' is a small box meant to simulate the basic characteristics of an equipment enclosure, but without the complexity of an actual enclosure. Extensive experimental measurements have been made on the enclosure and are summarized in a companion report entitled ''Experimental Measurements of the Demo Enclosure''. In this report, we will summarize the associated numerical modeling of the enclosure's structural vibration and radiated sound field using finite and boundary element techniques. One of the main goals of the report is to establish useful modeling guidelines for finite and boundary element analyses of enclosures. Producing accurate predictions is of primary importance, but ease of implementation is also important. We will try to demonstrate that it is not always beneficial to try to duplicate all the enclosure's structural complexity in the finite and boundary element models because errors inevitably occur and it is frequently difficult to adjust the models without considerable effort. For example, it is relatively simple to produce accurate models for shelves and enclosures separately, but their interconnections are much more difficult to represent. When the models are combined into much larger finite element models, it becomes difficult and time consuming to optimize the modeling of the interconnections. …