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Determination of Oxygen in Uranium by Vacuum Fusion (open access)

Determination of Oxygen in Uranium by Vacuum Fusion

From abstract: "An apparatus for analysis of metal samples for oxygen content is described. Vasuum [sic] fusion in a graphite crucible which is insulated by porous carbon in an all pyrex glass apparatus is used to remove the oxygen as carbon monoxide. Temperatures over 2000°C. are attainable with a 6 K.V.A. Ajax converter for induction heating. Successful operation depended upon a preliminary vacuum heating of the carbon parts at 2100°C. to remove hydrocarbon tars so that cracking of the pyrex glass will not occur due to deposit of tar. An operating temperature of 1750°C. - 1800°C. has been found satisfactory for uranium when using a platinum bath. The platinum bath is the most suitable bath because of its low volatility, its satisfactory carbon solubility, and because of the decrease of 'getting errors' due to volatility of reactive metals. Most metals form stable compounds with platinum and are therefore strongly held by the platinum bath and can not vaporize and thus react with the excaping [sic] CO gas..."
Date: 1946
Creator: Brewer, Leo, 1919-2005
System: The UNT Digital Library
Early Fluorocarbon Studies at Columbia University (open access)

Early Fluorocarbon Studies at Columbia University

Development of certain liquid and solid fluorocarbon compounds with special properties.
Date: 1946
Creator: Cady, George H.; Burger, Leland L. & Barber, E. J.
System: The UNT Digital Library
Fluorescence Analysis for Uranium (open access)

Fluorescence Analysis for Uranium

From abstract: "An adaptation of a colorimeter for the rapid estimation of small amounts of uranium to ± 5% by fluorescence of a sodium fluoride bead or fluoride-carbonate melt is described. Solutions containing from 0.1 to 1000 micrograms per milliliter may be tested directly. The limit of visual detection on a 20 mg. bead is about 0.0003 microgram of uranium. A periodic chart of interferences is presented. The strangest interferences center around the latter parts of each transition series of elements."
Date: 1946
Creator: Zebroski, E. L.; Newton, T. W. (Thomas William), 1923- & Ripple, F. T.
System: The UNT Digital Library
Geochemistry of Germanium (open access)

Geochemistry of Germanium

From abstract: "This is a review, with annotated bibliography, of the mode of occurrence of the element germanium. It is not a list of specific ore deposits, but a summary of the types of minerals and rocks in which germanium has been reported to occur. Best sources for germanium are indicated, based on the data in the literature and on the unpublished spectrographic studies of the Geological Survey on mill and smelter products. Suggestions are made for further investigations."
Date: 1946
Creator: Fleischer, Michael, 1908-1998 & Harder, James O.
System: The UNT Digital Library
Hydrodynamic Theory of the Reaction Zone in High Explosives (open access)

Hydrodynamic Theory of the Reaction Zone in High Explosives

From introduction: "The first part deals with stationary detonation waves...the second part is concerned with the structure of detonation waves of finite age...the third part deals with the steady state motion attained by a detonation wave in certain cases of two-dimensional flow."
Date: 1946
Creator: Skyrme, Tony Hilton Royle, 1922-1987
System: The UNT Digital Library
Infrared Spectrum of Benzene (open access)

Infrared Spectrum of Benzene

From abstract: "Benzene shows weak absorption bands in the 3 aliphatic C-Z region of the spectrum. The peaks of these bands are at 3.439, 3.459, 3.504, and 3.545."
Date: 1946
Creator: Flanagan, John; Gardner, R.; McKee, Frances & Schlegel, Richard, 1913-
System: The UNT Digital Library
Minimum Hydrogen Peroxide Concentration Required for Precipitate Formation From 50 Per Cent Uranyl Salt Solutions (open access)

Minimum Hydrogen Peroxide Concentration Required for Precipitate Formation From 50 Per Cent Uranyl Salt Solutions

This two page report discusses the processes followed and findings of an effort to estimate the minimum amount of hydrogen peroxide concentrations required for the formation of a precipitate in 50 percent solutions of uranyl nitrate and uranyl sulfate containing various concentrations of excess anion as acid. The report contains a table detailing the results.
Date: 1946
Creator: Livingston, Ralph
System: The UNT Digital Library
Pile Theory Notes for M.I.T. Seminar (open access)

Pile Theory Notes for M.I.T. Seminar

This report discusses topics relating to pile theory, focusing specifically on describing a nuclear chain reacting system. Topics covered include the time dependence of neutron density, controlling chain reacting boxes, and the behavior of neutrons in a pile.
Date: 1946
Creator: Feld, T. T. & Friedman, Francis L. (Francis Lee), 1918-
System: The UNT Digital Library
Preparation of N-Polychloropolyfluoroheptane (open access)

Preparation of N-Polychloropolyfluoroheptane

From introduction: "Discussion of alternate processes for manufacture of perfluoroxylene as insurance against any eventuality, e.g. disaster, poor quality, required amount of elemental fluorine not obtainable, necessity for further expansion at some future date, or decreasing cost."
Date: 1946
Creator: Babcock, J. H.; Beanblossom, W. S. & Wojcik, B. H.
System: The UNT Digital Library
Theory of Pile Control Rods (open access)

Theory of Pile Control Rods

From abstract: "A control rod absorbs neutrons and increases the leakage of neutrons from the pile through the depression of the neutron density in its vicinity. To determine the effect of controls on critical conditions for a pile the absorber may be considered, as in the electrical analogue, to produce a singularity in neutron density at its position. The strength of such a singularity is determined by the boundary conditions which must be satisfied at the surface of the black or non-black absorber and the order of the singularity is determined by the geometry of the problem. The general solution of the pile equations can then be expressed by a sum of a regular solution plus the solution containing the proper singularities and this total solution can be adjusted to satisfy the boundary conditions. By this means the effect of control rods of various sizes and positions on pile reactivity and neutron distribution and the effects of mutual control rod shading have been investigated both by a thermal and by a two group theory."
Date: 1946
Creator: Scalettar, R. & Nordheim, L. W.
System: The UNT Digital Library
The Effect of Clay on the Intestinal Absorption of Strontium (open access)

The Effect of Clay on the Intestinal Absorption of Strontium

From abstract: "Rats have been fed active strontium which was adsorbed on clay, while their controls were fed the same amount of active strontium in aqueous solution. There was no significant difference in the amount deposited in the skeleton between the two groups, and it is concluded that if ions are adsorbed on inert material, they will be eluted during their passage through the gastrointestinal tract."
Date: January 21, 1946
Creator: Curtis, Howard J. (Howard James), 1906-
System: The UNT Digital Library
Comparative Effectiveness and Additivity of Fission Neutrons Gamma Rays and Beta Rays of Drosphila Eggs (open access)

Comparative Effectiveness and Additivity of Fission Neutrons Gamma Rays and Beta Rays of Drosphila Eggs

From abstract: "Some investigations have been made to ascertain the similarity of the mechanism of action of radiation which are different in their specific ionization. A suggested approach was to determine if the energies absorbed from the different types of radiation are additive in their lethal effects on biological objects. In an attempt to determine the additivity of ionizing radiation various dose combinations of fast neutrons, gamma rays and beta rays were administered to Drosophila eggs. These test objects were chosen because their dimensions are such that they tend to absorb these three radiations uniformly throughout their volume. Although the three radiations were found to vary in their biological effectiveness, per unit energy absorbed, all three were shown to be completely additive in their lethal effect on these organisms."
Date: February 1946
Creator: Stapleton, G. E. & Zirkle, Raymond E. (Raymond Elliot), 1902-1988
System: The UNT Digital Library
Analysis of X-ray Powder Diffraction Data on Crystalline Uranium Hexafluoride. (open access)

Analysis of X-ray Powder Diffraction Data on Crystalline Uranium Hexafluoride.

From introduction: "The concluding remarks of the report on the electron diffraction study of UF6 suggest two alternate explanations for the apparent discrepancy between the structure proposed for this compound as deduced from X-ray diffraction work on single crystals and from the electron diffraction investigation of the vapor. The second explanation is based on the premise that the difference may be due to essentially unlike methods of treating the diffraction data. In this report we shall analyze X-ray powder photographs following a scheme parallel to that used in the analysis of the electron diffraction data, to check whether this particular explanation is tenable."
Date: March 5, 1946
Creator: Bauer, S. H. (Simon Harvey), 1911- & Palter, H.
System: The UNT Digital Library
The Effect of Age on the Radiosensitivity of Mice (open access)

The Effect of Age on the Radiosensitivity of Mice

Abstract: Mice of different ages ranging from 1.5 to 12 months have been exposed to gamma rays in an effort to determine the change in radiosensitivity with age. The dose necessary to cause 50% killing was determined for each age group and sex. No change in sensitivity with age was observed with either sex, although the experimental error in the case of the males was quite large. The females were found to be more resistant than the males.
Date: April 8, 1946
Creator: Curtis, H. J.; Zirkle, Raymond E. (Raymond Elliot), 1902-1988; Anderson, Ernest C., 1920-2013 & Riley, E. F.
System: The UNT Digital Library
Sid Magnet Model Test Results (open access)

Sid Magnet Model Test Results

From introduction: "These data were taken on a 1/16th scale model of the magnet shown on sketch no. FS-2. The object of these measurements was to get information that would determine the final design of the full scale magnet. The one main point to be settled was whether a tapered or a cylindrical pole piece would give the largest value of Hρ for a given power input into the magnet (the cylindrical pole piece is shown in dotted lines in sketch FS-2)."
Date: April 19, 1946
Creator: Sewell, Duane C., 1918-2008
System: The UNT Digital Library
Autoxidation of Uranous Salts in Water Solution (open access)

Autoxidation of Uranous Salts in Water Solution

From introduction: "The fact that tetravalent uranium either in the form of solutions of its salts or, in some cases, in the dry state is readily oxidized by gaseous oxygen, has been observed by various investigators. A quantitative study of this reaction appeared to be desirable as a means of learning more about the nature of the ionic species present in uranous solutions. It was also of potential value in determining the importance of autoxidation as an undesirable side reaction involved in the handling of uranous solutions, and, if necessary, in developing procedures for minimizing the reaction."
Date: April 20, 1946
Creator: Nichols, Ambrose R., Jr.
System: The UNT Digital Library
The Beta-Gamma Hand and Foot Counters (open access)

The Beta-Gamma Hand and Foot Counters

Abstract: This is basically a counting rate meter, with an alarm circuit, operating from four GM tubes as the detecting elements. The Hand Counter comprises four logarithmic counting rate meters working from four GM tubes mounted individually, with associated electronic circuits, in suitable shields with a metal mesh type of window. Both sides of both hands are sampled simultaneously. In the Foot Counter, two GM tubes are separately and mounted in a suitable mesh window shielded with the electronic circuit; the foot counter uses only two counting rate meters, and both feet are sampled simultaneously. Each circuit is built in two parts; two tubes are in the shield and the balance of the circuit is in the electronic unit which is a standard 17" x 13" chassis. Circuit diagrams are included.
Date: May 1946
Creator: Bradley, W. H.
System: The UNT Digital Library
Electrolytic Reduction of Uranyl Ion (open access)

Electrolytic Reduction of Uranyl Ion

From introduction: "Due to the hydrogen overvoltage at the surface of a mercury cathode, uranium solutions is hydrochloric acid may be reduced not only to the tetravalent state, but until considerable trivalent uranium is formed. Other metallic ions act as oxidation-reduction catalysts as well as being reduced themselves. The following paper is a study of the various reactions taking place in solution and at the surface of the cathode."
Date: May 27, 1946
Creator: Nichols, Ambrose R., Jr.
System: The UNT Digital Library
The Geochemistry of Columbium and Tantalum (open access)

The Geochemistry of Columbium and Tantalum

From abstract: "This is a review, with annotated bibliography, of the mode of occurrence of the elements columbium and tantalum. It is not a list of specific ore deposits, but a summary of the types of minerals and rocks in which these elements have been reported to occur. In addition, the unpublished spectrographic studies of the Geological Survey are summarized, best sources for columbium and tantalum are indicated, and suggestions are made for further investigation."
Date: June 1946
Creator: Fleischer, Michael, 1908-1998 & Harder, James O.
System: The UNT Digital Library
The Geochemistry of Indium (open access)

The Geochemistry of Indium

Abstract" This is a review, with annotated bibliography, of the mode of occurrence of the element indium. It is not a list of specific ore deposits, but a summary of the types of minerals and rocks in which indium has been reported to occur. In addition, the unpublished spectrographic studies of the Geological Survey on mill and smelter products are summarized, best sources of indium are indicated, and suggestions are made for further investigations. Indium has been found to occur most abundantly in sphalerites. The amount ranges from traces to maximum of 1.0 percent. Dark sphalerites are reported richer in indium than light-colored sphalerites. Up to 0.1 percent indium has been reported in chalcopyrite and bornite, but these minerals generally contain very little indium. There is an unverified report of a pegmatite in Utah containing 1.0 to 2.8 percent indium. Some residues in zinc smelting contain more than 1.0 percent indium and are the present source on indium. No better source can be suggested but steps should be taken to ascertain that this source is being fully exploited. Tin sulfide smelter products should be checked. An effort should be made to check the Utah pegmatite occurrence.
Date: June 1946
Creator: Fleischer, Michael, 1908-1998 & Harder, James Otto.
System: The UNT Digital Library
Some Studies of the Reactions of Uranium Oxides with Hydrogen, Oxygen and Water (open access)

Some Studies of the Reactions of Uranium Oxides with Hydrogen, Oxygen and Water

Abstract: The purpose of this research was to obtain data that would be useful in predicting changes that might be expected to occur in the oxidation state and degree of hydration of powdered uranium oxides maintained for long periods of time at temperatures between 30 and 300 degrees C. in the presence of excess water, hydrogen, oxygen and possibly hydrogen peroxide. The reaction of hydrogen and oxygen with water slurries of U3O8 were studied at 100-300 degree C.
Date: June 1946
Creator: Gillies, Daniel M.
System: The UNT Digital Library
The Chemical Effects of Nuclear Transformations (open access)

The Chemical Effects of Nuclear Transformations

This technical report is divided into two sections addressing two different chemical effects of nuclear transformations. The first section discusses the beta decay of lanthanum to cerium. The second section discusses the beta decay of selenium to bromine.
Date: June 6, 1946
Creator: Coryell, Charles D. (Charles Du Bois), 1912-1971; Gest, H.; Edwards, R. R. & Davies, T. H.
System: The UNT Digital Library
The Spatial Distribution of Neutrons Slowed Down by Elastic Collisions (open access)

The Spatial Distribution of Neutrons Slowed Down by Elastic Collisions

Technical report discussion of the complicated problem of the spatial distribution of slowed down neutrons. The introduction covers the current research on the topic. The following chapters cover the topics: (1) approximate treatment and its limitations, (2) age-velocity distribution, (3) general scheme of treatment based on transport equation, (4) Fermi's one-dimensional model, (5) moments, (6) remarks about the distribution function, and (7) point source.
Date: June 11, 1946
Creator: Placzek, G. (George), 1905-1955.
System: The UNT Digital Library
A Mass Spectrograph for the Analysis of Fission Product Mixtures (open access)

A Mass Spectrograph for the Analysis of Fission Product Mixtures

From introduction: "The analysis of mixtures of fission products with a mass spectrograph offers certain advantages. A chemical separation of the fission products found in the solution at Hanford is not necessary with the mass spectrograph technique. A sample of the mixtures can be placed on the sample holder and then the sample holder is mounted in the mass spectrograph. This reduces the amount of handling of the active solutions to one relatively simple and short operation. The health hazards involved in the analysis can be further reduced by increasing the efficiency of the spectrograph as much as possible, thus making possible an analysis of a sample of lower total activity. The mass spectrograph described here is an attempt to realize the advantages pointed out above. Particular attention has been given to increasing the increasing the efficiency of the instrument."
Date: June 12, 1946
Creator: Lewis, Lloyd G., 1917-
System: The UNT Digital Library