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High-Throughput Computational Search for Half-Metallic Oxides (open access)

High-Throughput Computational Search for Half-Metallic Oxides

The article describes a high-throughput computational search for half-metallic compounds. The analysis of calculated electronic properties of thousands of materials from the inorganic crystal structure database allowed the authors to identify potential half metals. They found over two-hundred strong half-metallic oxides; several of them have never been reported before.
Date: April 25, 2020
Creator: Liyanage, Laalitha S. I.; Slawińska, Jagoda; Gopal, Priya; Curtarolo, Stefano; Fornari, Marco & Buongiorno Nardelli, Marco
Object Type: Article
System: The UNT Digital Library
Surface-specific washing-free immunosensor for time-resolved cortisol monitoring (open access)

Surface-specific washing-free immunosensor for time-resolved cortisol monitoring

This article describes a method of measuring cortisol levels. It presents a metal-enhanced fluorescence assay based on a displacement of a dye labeled BSA-cortisol conjugate from the immune complex immobilized on the golden islands by free cortisol.
Date: December 29, 2020
Creator: Safarian, Sofia M.; Kusov, Pavel A.; Kosolobov, Sergey S.; Borzenkova, Oksana V.; Khakimov, Artem V.; Kotelevtsev, Yuri V. et al.
Object Type: Article
System: The UNT Digital Library
Analysis of the Fe 2p XPS for hematite 𝛂 Fe2O3: Consequences of covalent bonding and orbital splittings on multiplet splittings (open access)

Analysis of the Fe 2p XPS for hematite 𝛂 Fe2O3: Consequences of covalent bonding and orbital splittings on multiplet splittings

Article analyzes the origins of the complex Fe 2p X-Ray Photoelectron Spectra (XPS) of hematite (α-Fe₂O₃) and is related to the character of the bonding in this compound. This analysis provides a new and novel view of the reasons for XPS binding energies (BEs) and BE shifts, which deepens the current understanding and interpretation of the physical and chemical significance of the XPS. This article is part of the JCP Special Topic on Oxide Chemistry and Catalysis.
Date: January 2, 2020
Creator: Bagus, Paul S.; Nelin, Connie J.; Brundle, C. R.; Lahiri, N.; Ilton, Eugene S. & Rosso, Kevin M.
Object Type: Article
System: The UNT Digital Library
Magnetic confinement of effectively unmagnetized plasma particles (open access)

Magnetic confinement of effectively unmagnetized plasma particles

Article develops a planar model for an artificially structured boundary that may provide magnetic confinement of nonmagnetically trapped plasma particles.
Date: December 1, 2020
Creator: Ordonez, Carlos A.
Object Type: Article
System: The UNT Digital Library
Prescriptions for Correcting Ultraviolet-based Redshifts for Luminous Quasars at High Redshift (open access)

Prescriptions for Correcting Ultraviolet-based Redshifts for Luminous Quasars at High Redshift

This article presents near-infrared spectroscopy of 18 luminous quasars at 2.15 < z < 3.70 that allows the authors to obtain reliable systemic redshifts for these sources.
Date: April 8, 2020
Creator: Dix, Cooper; Shemmer, Ohad; Brotherton, Michael S.; Green, Richard F.; Mason, Michelle & Myers, Adam D.
Object Type: Article
System: The UNT Digital Library
An Extreme X-Ray Variability Event of a Weak-line Quasar (open access)

An Extreme X-Ray Variability Event of a Weak-line Quasar

Article reports the discovery of an extreme X-ray flux rise (by a factor of ≳20) of the weak-line quasar Sloan Digital Sky Survey (SDSS) J153913.47+395423.4 (hereafter SDSS J1539+3954) at z = 1.935. SDSS J1539+3954 is the most-luminous object among radio-quiet type 1 active galactic nuclei (AGNs) where such dramatic X-ray variability has been observed.
Date: February 3, 2020
Creator: Ni, Q.; Brandt, W. N.; Yi, W.; Luo, B.; Timlin, J. D., III; Hall, P. B. et al.
Object Type: Article
System: The UNT Digital Library
In silico guided structural and functional analysis of genes with potential involvement in resistance to coffee leaf rust: A functional marker based approach (open access)

In silico guided structural and functional analysis of genes with potential involvement in resistance to coffee leaf rust: A functional marker based approach

Article presents novel insights into the molecular nature of the SH genes, thereby opening new avenues for coffee rust resistance molecular breeding.
Date: July 8, 2020
Creator: Ferreira, Svio Siqueira; Barka, Geleta Dugassa; Caixeta, Eveline Teixeira & Zambolim, Larcio
Object Type: Article
System: The UNT Digital Library
Phononic crystal as a homogeneous viscous metamaterial (open access)

Phononic crystal as a homogeneous viscous metamaterial

Article develops a homogenization theory, representing the low-frequency limit for a phononic crystal of cylinders embedded in a viscous fluid.
Date: June 8, 2020
Creator: Krokhin, Arkadii A.; Zubov, Yu.; Ibarias, M. & Arriaga, J.
Object Type: Article
System: The UNT Digital Library
Lipophilic signals lead to organ-specific gene expression changes in Arabidopsis seedlings (open access)

Lipophilic signals lead to organ-specific gene expression changes in Arabidopsis seedlings

Article presents a study where whole transcriptome sequencing (RNA-seq) and differential expression analysis were used to identify early (1–3 hr) transcriptional changes induced by the exogenous treatment of NAE 18:2 and NAE 18:3 in cotyledons, roots, and seedlings.
Date: July 15, 2020
Creator: Cannon, Ashley E.; Yan, Chengshi; Burks, David J.; Rao, Xiaolan; Azad, Rajeev K. & Chapman, Kent Dean
Object Type: Article
System: The UNT Digital Library
Insertional mutagenesis of Brachypodium distachyon using the Tnt1 retrotransposable element (open access)

Insertional mutagenesis of Brachypodium distachyon using the Tnt1 retrotransposable element

Article is a study exploring the possibility of using the tobacco retrotransposon Tnt1 to create a transposon-based insertion mutant population in B. distachyon.
Date: May 15, 2020
Creator: Serrani-Yarce, Juan C.; Nandety, Raja Sekhar; Gill, Upinder S.; Oh, Sunhee; Lee, Hee-Kyung; Zhang, Xinji et al.
Object Type: Article
System: The UNT Digital Library
Sc3N@Ih-C80 based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation (open access)

Sc3N@Ih-C80 based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation

Article reports light induced charge separation in a newly synthesized triphenylamine–thiophene-Sc₃N@Iₕ-C₈₀ donor–acceptor conjugate and its C₆₀ analog, triphenylamine–thiophene-C₆₀ conjugate, and the significance of the thiophene spacer in promoting electron transfer events.
Date: May 27, 2020
Creator: Gobeze, Habtom B.; D'Souza, Francis; Caballero, Rubén; Servián, Luis David; Fernandez-Delgado, Olivia; Echegoyen, Luis et al.
Object Type: Article
System: The UNT Digital Library
A new synthetic route for the preparation of [Os3(CO)10(μ-OH)(μ-H)] and its reaction with bis(diphenylphosphino)methane (dppm): syntheses and X-ray structures of two isomers of [Os3(CO)8(μ-OH)(μ-H)(μ-dppm)] and [Os3(CO)7(μ3-CO)(μ3-O)(μ-dppm)] (open access)

A new synthetic route for the preparation of [Os3(CO)10(μ-OH)(μ-H)] and its reaction with bis(diphenylphosphino)methane (dppm): syntheses and X-ray structures of two isomers of [Os3(CO)8(μ-OH)(μ-H)(μ-dppm)] and [Os3(CO)7(μ3-CO)(μ3-O)(μ-dppm)]

Article describes a convenient synthetic method for the preparation of the hydroxy-bridged triosmium cluster [Os₃(CO)₁₀(μ-OH)(μ-H)] along with the re-evaluation of the reaction of this cluster with dppm that has led to the isolation of a new isomer for [Os₃(CO)₈(μ-OH)(μ-H)(μ-dppm)].
Date: December 17, 2020
Creator: Richmond, Michael G.; Joy, Tuhinur R.; Bhoumik, Nikhil C.; Ghosh, Shishir & Kabir, Shariff E.
Object Type: Article
System: The UNT Digital Library
Comparative Diet Analysis of Barn Owl (Tyto alba) and Long- Eared Owl (Asio otus) in a Habitat Island in North-Central Texas (open access)

Comparative Diet Analysis of Barn Owl (Tyto alba) and Long- Eared Owl (Asio otus) in a Habitat Island in North-Central Texas

Article filling the regional gap in knowledge of diet composition of the barn owl (Tyto alba) and the long-eared owl (Asio otus). The study was conducted at the Lewisville Lake Environmental Learning Area (LLELA) and examined the remains found in owl pellets collected September 2016 to March 2017.
Date: August 22, 2020
Creator: Jiménez, Jaime E.; Jones, Matthew K.; Stoddart, Kaitlyn; Dickson, Sentell; Chapman, Abigail; Baxter-Slye, Jaime L. et al.
Object Type: Article
System: The UNT Digital Library
Angiogenesis in the Avian Embryo Chorioallantoic Membrane: A Perspective on Research Trends and a Case Study on Toxicant Vascular Effects (open access)

Angiogenesis in the Avian Embryo Chorioallantoic Membrane: A Perspective on Research Trends and a Case Study on Toxicant Vascular Effects

This article considers areas of cardiovascular research that have benefited from studies of the chorioallantoic membrane (CAM), including the themes of investigation of the CAM’s hemodynamic influence on heart and central vessel development, use of the CAM as a model vascular bed for studying angiogenesis, and the CAM as an assay tool.
Date: October 28, 2020
Creator: Burggren, Warren W. & Antich, Maria Rojas
Object Type: Article
System: The UNT Digital Library
Computational Study of Methane C–H Activation by Main Group and Mixed Main Group–Transition Metal Complexes (open access)

Computational Study of Methane C–H Activation by Main Group and Mixed Main Group–Transition Metal Complexes

This article presents density functional theory (DFT) research where nine different molecules, each with different combinations of A (triel) and E (divalent metal) elements, were reacted to effect methane C–H activation.
Date: May 26, 2020
Creator: Carter, Carly C. & Cundari, Thomas R., 1964-
Object Type: Article
System: The UNT Digital Library
Leaf Lipid Alterations in Response to Heat Stress of Arabidopsis thaliana (open access)

Leaf Lipid Alterations in Response to Heat Stress of Arabidopsis thaliana

Article measuring lipid levels with mass spectrometry to confirm the previously observed changes in Arabidopsis thaliana leaf lipids under three heat stress regimens. Additionally, in response to heat, increased oxidation of the fatty acyl chains of leaf galactolipids, sulfoquinovosyldiacylglycerols, and phosphatidylglycerols, and incorporation of oxidized acyl chains into acylated monogalactosyldiacylglycerols are shown. The authors also observed increased levels of digalactosylmonoacylglycerols and monogalactosylmonoacylglycerols. The hypothesis that a defect in sterol glycosylation would adversely affect regrowth of plants after a severe heat stress regimen was tested, but differences between wild-type and sterol glycosylation-defective plants were not detected.
Date: July 4, 2020
Creator: Shiva, Sunitha; Samarakoon, Thilani; Lowe, Kaleb A.; Roach, Charles; Vu, Hieu Sy; Colter, Madeline et al.
Object Type: Article
System: The UNT Digital Library
SEIPIN Isoforms Interact with the Membrane-Tethering Protein VAP27-1 for Lipid Droplet Formation (open access)

SEIPIN Isoforms Interact with the Membrane-Tethering Protein VAP27-1 for Lipid Droplet Formation

Article demonstrating that part of the function of two SEIPIN isoforms in Arabidopsis (Arabidopsis thaliana), AtSEIPIN2 and AtSEIPIN3, may depend on their interaction with the vesicle-associated membrane protein (VAMP)–associated protein (VAP) family member AtVAP27-1. The authors used a combination of biochemical, cell biology, and genetics approaches to show that AtVAP27-1 interacts with the N termini of AtSEIPIN2 and AtSEIPIN3 and likely supports the normal formation of LDs. This insight indicates that the ER membrane tethering machinery in plant cells could play a role with select SEIPIN isoforms in LD biogenesis at the ER, and additional experimental evidence in Saccharomyces cerevisiae supports the possibility that this interaction may be important in other eukaryotic systems.
Date: July 20, 2020
Creator: Greer, Michael Scott; Cai, Yingqi; Gidda, Satinder K.; Esnay, Nicolas; Kretzschmar, Franziska K.; Seay, Damien C. et al.
Object Type: Article
System: The UNT Digital Library
Multitask deep-learning-based design of chiral plasmonic metamaterials (open access)

Multitask deep-learning-based design of chiral plasmonic metamaterials

This article presents an end-to-end functional bidirectional deep-learning (DL) model for three-dimensional chiral metamaterial design and optimization. This ML model utilizes multitask joint learning features to recognize, generalize, and explore in detail the nontrivial relationship between the metamaterials’ geometry and their chiroptical response, eliminating the need for auxiliary networks or equivalent approaches to stabilize the physically relevant output. This model efficiently realizes both forward and inverse retrieval tasks with great precision, offering a promising tool for iterative computational design tasks in complex physical systems. Other potential applications include photodetectors, polarization-resolved imaging, and circular dichroism (CD) spectroscopy.
Date: July 1, 2020
Creator: Ashalley, Eric; Acheampong, Kingsley; Besteiro, Lucas V.; Yu, Peng; Neogi, Arup; Govorov, Alexander O. et al.
Object Type: Article
System: The UNT Digital Library
Sub-wavelength lateral detection of tissue-approximating masses using an ultrasonic metamaterial lens (open access)

Sub-wavelength lateral detection of tissue-approximating masses using an ultrasonic metamaterial lens

Article demonstrating a phononic metamaterial lens (ML) for detection of laterally subwavelength object features in tissue-like phantoms beyond the phononic crystal evanescent zone and Fresnel zone of the emitter.
Date: November 24, 2020
Creator: Walker, Ezekiel; Jin, Yuqi; Reyes, Delfino & Neogi, Arup
Object Type: Article
System: The UNT Digital Library
Anisotropic optical properties of single Si2Te3 nanoplates (open access)

Anisotropic optical properties of single Si2Te3 nanoplates

Article reporting a combined experimental and computational study of the optical properties of individual silicon telluride (Si2Te3) nanoplates.
Date: November 5, 2020
Creator: Chen, Jiyang; Bhattarai, Romakanta; Cui, Jingbiao; Shen, Xiao & Hoang, Thang
Object Type: Article
System: The UNT Digital Library
Electrochemical sensor for selective tyramine determination, amplified by a molecularly imprinted polymer film (open access)

Electrochemical sensor for selective tyramine determination, amplified by a molecularly imprinted polymer film

This article devised, fabricated, and tested a molecularly imprinted polymer (MIP) film based electrochemical sensor for selective determination of tyramine.
Date: November 17, 2020
Creator: Ayerdurai, Viknasvarri; Cieplak, Maciej; Noworyta, Krzysztof R.; Gajda, Marianna; Ziminska, Agnieszka; Sosnowska, Marta et al.
Object Type: Article
System: The UNT Digital Library
Substrate Specificity of LACCASE8 Facilitates Polymerization of Caffeyl Alcohol for C-Lignin Biosynthesis in the Seed Coat of Cleome hassleriana (open access)

Substrate Specificity of LACCASE8 Facilitates Polymerization of Caffeyl Alcohol for C-Lignin Biosynthesis in the Seed Coat of Cleome hassleriana

This article finds that the transcript profile of the laccase gene ChLAC8 parallels the accumulation of C-lignin during seed coat development. Recombinant ChLAC8 oxidizes caffeyl and sinapyl alcohols, generating their corresponding dimers or trimers in vitro, but cannot oxidize coniferyl alcohol. The authors propose a basis for this substrate preference based on molecular modeling/docking experiments. Suppression of ChLAC8 expression led to significantly reduced C-lignin content in the seed coats of transgenic Cleome plants. Feeding of 13C-caffeyl alcohol to the Arabidopsis (Arabidopsis thaliana) caffeic acid o-methyltransferase mutant resulted in no incorporation of 13C into C-lignin, but expressing ChLAC8 in this genetic background led to appearance of C-lignin with >40% label incorporation. These results indicate that ChLAC8 is required for C-lignin polymerization and determines lignin composition when caffeyl alcohol is available.
Date: October 9, 2020
Creator: Wang, Xin; Zhuo, Chunliu; Xiao, Xirong; Wang, Xiaoqiang; Docampo-Palacios, Maite; Chen, Fang et al.
Object Type: Article
System: The UNT Digital Library
Cellular Plasticity in Response to Suppression of Storage Proteins in the Brassica napus Embryo (open access)

Cellular Plasticity in Response to Suppression of Storage Proteins in the Brassica napus Embryo

Article testing the tradeoff between protein and oil storage in oilseed crops by analyzing the effect of suppressing key genes encoding protein storage products (napin and cruciferin). This study provides mechanistic insights into the intriguing link between lipid and protein storage, which have implications for biotechnological strategies directed at improving oilseed crops.
Date: April 30, 2020
Creator: Rolletschek, Hardy; Schwender, Jorg; König, Christina; Chapman, Kent Dean; Romsdahl, Trevor; Lorenz, Christin et al.
Object Type: Article
System: The UNT Digital Library
Seedling Chloroplast Responses Induced by N-Linolenoylethanolamine Require Intact G-Protein Complexes (open access)

Seedling Chloroplast Responses Induced by N-Linolenoylethanolamine Require Intact G-Protein Complexes

This article shows that the activity of N-linolenoylethanolamine (NAE 18:3) requires an intact G-protein complex. Specifically, genetic ablation of the Gβγ dimer or loss of the full set of atypical Gα subunits strongly attenuates an NAE-18:3–induced degreening of cotyledons in Arabidopsis (Arabidopsis thaliana) seedlings. This effect involves, at least in part, transcriptional regulation of chlorophyll biosynthesis and catabolism genes. In addition, there is feedforward transcriptional control of G-protein signaling components and G-protein interactors. These results are consistent with NAE 18:3 being a lipid signaling molecule in plants with a requirement for G-proteins to mediate signal transduction, a situation similar, but not identical, to the action of NAE endocannabinoids in animal systems.
Date: July 14, 2020
Creator: Yan, Chengshi; Cannon, Ashley E.; Watkins, Justin; Keereetaweep, Jantana; Khan, Bibi Rafeiza; Jones, Alan M. et al.
Object Type: Article
System: The UNT Digital Library