Corrosion of Austenitic Stainless Steel in Mixed Acids (open access)

Corrosion of Austenitic Stainless Steel in Mixed Acids

Introduction:"A corrosion test program in support of the Redox Project was carried out during the second quarter of 1950 to determine the corrosion rates of several austenitic stainless steels in simulated 202-B Waste Storage solution containing HF, HN03, and H2SO4 acids. The results of this program are contained herein and all original data are recorded in laboratory notebook HW-3282-T."
Date: June 5, 1950
Creator: Koenig, W. W.
System: The UNT Digital Library
The Absorption and Translocation of Several Fission Elements by Russian Thistle (open access)

The Absorption and Translocation of Several Fission Elements by Russian Thistle

Abstract: An investigation was conducted to determine the absorption and translocation of fission products by Russian thistle from a localized spot of contaminated soil. The amount and identity of the radioactive elements absorbed and translocated by the Russian thistle is given along with the location of these elements in the plants. Beta radioactivity to the amounts of 10 microcuries per gram caused no visible effects on the growth habits of sectioned material are included.
Date: June 8, 1950
Creator: Selders, A. A.
System: The UNT Digital Library
Determination of Radiocesium with Chloroplatinic Acid (open access)

Determination of Radiocesium with Chloroplatinic Acid

The following report examines a rapid method used to eliminate the possibility of explosive perchlorate-organic mixtures in a control laboratory in order to determine radiocesium. These methods include the usage of chloroplatinic acid as a precipitate of radocesium.
Date: June 22, 1950
Creator: Erwing, R. E.
System: The UNT Digital Library
The Solubility of Plutonium (IV) Monobutyl Phosphate (open access)

The Solubility of Plutonium (IV) Monobutyl Phosphate

Report discussing a study regarding the identification and property analysis of plutonium (IV) monobutyl phosphate, which formed as a white precipitate in another study of the effects of monobutyl phosphate on plutonium(IV) in tributyl phosphate extractions.
Date: June 28, 1950
Creator: Moore, Robert Lee
System: The UNT Digital Library
Infrared Measurements on the System Hexone-Water-Uranyl Nitrate (open access)

Infrared Measurements on the System Hexone-Water-Uranyl Nitrate

The following report observes infrared measurements in the region of OH bands, the C2O band vicinity, the low frequency end of the spectrum, and the region of the UO2 band on the system hexone - water - uranyl nitrate.
Date: July 15, 1950
Creator: Burger, L. L. & Moore, R. H.
System: The UNT Digital Library
Fission Product Analysis of Urine (open access)

Fission Product Analysis of Urine

The following report describes a chemical procedure to analyze fission products and long-lived rare earths in both untreated urine samples and the supernates from the precipitation steps in the TTA procedure for plutonium.
Date: May 31, 1950
Creator: Thorburn, R. C.
System: The UNT Digital Library
Properties of Neutralized and Concentrated Aqueous Waste - Low Acid Flowsheets TBP-HW-No. 4 and No. 5 (open access)

Properties of Neutralized and Concentrated Aqueous Waste - Low Acid Flowsheets TBP-HW-No. 4 and No. 5

This report discusses properties and data regarding the neutralized and concentrated aqueous waste produced during studies of the tributyl phosphate (TBP) solvent extraction process.
Date: July 18, 1950
Creator: Curtis, M. H.; Harmon, M. K. & Cooper, V. R.
System: The UNT Digital Library
Preparation and Properties of RAF Solutions : Low Acid TBP Flowsheets HW Number 4 and HW Number 5 (open access)

Preparation and Properties of RAF Solutions : Low Acid TBP Flowsheets HW Number 4 and HW Number 5

This report follows work with the purposes of determining the minimum amount of nitric acid required to dissolve slurries of stored metal waste, determining the stability of such metastable solutions as a function of their chemical compositions - primarily acidity - versus time and temperature, and to define a feed suitable for a low-acid TBP process flowsheet, and to indicate the range of variations in composition which can be tolerated for plant operation.
Date: July 25, 1950
Creator: Maness, R. F. & Harmon, M. K.
System: The UNT Digital Library
Apparent viscosity of neutralized and concentrated raw slurry : TBP HW-no. 4 and HW flowsheet (open access)

Apparent viscosity of neutralized and concentrated raw slurry : TBP HW-no. 4 and HW flowsheet

Report describing how the neutralized aqueous waste from the TBP Metal Recovery Process will be concentrated by evaporation to minimize the requirements for underground storage tank capacity.
Date: August 15, 1950
Creator: Allen, A. W. & Harmon, M. K.
System: The UNT Digital Library
Settling and Dissolution Characteristics and Composition of Hanford Waste Metal Sludge (open access)

Settling and Dissolution Characteristics and Composition of Hanford Waste Metal Sludge

Report reviewing a study regarding the chemical properties, appearance, texture, homogeneity and slurrying ability of waste metal sludge. The settling rates of sludge-supernatant slurries is also discussed.
Date: June 23, 1950
Creator: Brandt, H. L. & Burns, W. A.
System: The UNT Digital Library
Laboratory Survey of Deoxidants for Uranium Chips (open access)

Laboratory Survey of Deoxidants for Uranium Chips

Summary: "Six different types of solutions of various concentrations were used to deoxidize uranium chips on a laboratory scale. None of the solutions tested appears to be more desirable than 50% nitric acid for deoxidizing uranium chip on a production scale."
Date: August 3, 1950
Creator: Kattner, W. T.
System: The UNT Digital Library
The Nitrogen Mustards : A Review (open access)

The Nitrogen Mustards : A Review

The following report analyzes the nitrogen mustard found in mustard gas.
Date: 1950
Creator: DeLong, C. W.
System: The UNT Digital Library
Comparison of Diluents for Tributyl Phosphate (open access)

Comparison of Diluents for Tributyl Phosphate

From introduction: This report summarizes a study of the composution and physical properties of a number of hydrocarbon diluents together with some generalizations regarding relations between [vapor pressure, density and viscosity] properties.
Date: October 6, 1950
Creator: Burger, L. L.
System: The UNT Digital Library
Quarterly Progress Report: Research and Development Activities for January - March, 1951 (open access)

Quarterly Progress Report: Research and Development Activities for January - March, 1951

Report discussing progress in research and development by the Health Instrument Divisions, Hanford Works, for the term from January through March, 1951.
Date: April 18, 1951
Creator: Parker, H. M.
System: The UNT Digital Library
The Solubility of Tributyl Phosphate in Aqueous Solutions (open access)

The Solubility of Tributyl Phosphate in Aqueous Solutions

Report describing a study regarding the solubility and related properties of tributyl phosphate (TBP), which has lower solubility in water than most uranium solvents. Pure TBP and TBP in an inert diluent were tested for solubility in water, several nitric acid solutions of varying concentrations, and other solutions typical of process streams. For TBP-diluent-water system tests, equilibrium water content in organic phase was found.
Date: April 2, 1951
Creator: Burger, Leland L. & Forsman, R. C.
System: The UNT Digital Library
Retention of Iodine in Process Solutions by Mercuric Salts (open access)

Retention of Iodine in Process Solutions by Mercuric Salts

Report discussing a study of various types of mercuric salts in order to determine which salt prevents the evolution of iodine which results from sparging.
Date: June 15, 1951
Creator: Holm, C. H.
System: The UNT Digital Library
A Recomputation and Extension of Parameters Involved in Sutton's Diffusion Hypothesis (open access)

A Recomputation and Extension of Parameters Involved in Sutton's Diffusion Hypothesis

Report discussing changes in parameters regarding Sutton's diffusion hypothesis, which is used in calculations of plant stacks' atmospheric pollutant distribution. An explanation of the computation and results are given.
Date: June 19, 1951
Creator: Barad, M. L. & Hilst, G. R.
System: The UNT Digital Library
Coating Removal Waste Loss Reduction : Final Report, Production Test 221-B-8 (open access)

Coating Removal Waste Loss Reduction : Final Report, Production Test 221-B-8

The following report covers a test with the objective to demonstrate that the plutonium and uranium losses associated with the aluminum jacket dissolution could be reduced by substituting a water wash for the 5 per cent nitric acid wash following the coating removal and that this change would not adversely effect the product yield of decontamination in subsequent process steps.
Date: June 25, 1951
Creator: Kirkendall, B. E.
System: The UNT Digital Library
Corrosion of Stainless Steels by Concentrated UNH Solutions (open access)

Corrosion of Stainless Steels by Concentrated UNH Solutions

The following report contains data from all corrosion tests initiated to determine the amount of iron, chromium, and nickel contamination expected in the Metal Recovery Process product.
Date: 1951
Creator: Sanborn, K. L.
System: The UNT Digital Library
Graphite Sample Boring from Process Channels : Final Report, Production Test 105-389-P (open access)

Graphite Sample Boring from Process Channels : Final Report, Production Test 105-389-P

The following report records a total of forty-nine graphite core samples that have been bored from process tube blocks in the Hanford piles with the intention to provide results to indicate that core boring is an entirely practical operation over bore scraping in obtaining powder samples.
Date: July 10, 1951
Creator: Cole, J. B.
System: The UNT Digital Library
Emission Spectroscopic Analysis of Hydrogen - Deuterium Mixtures (open access)

Emission Spectroscopic Analysis of Hydrogen - Deuterium Mixtures

The following report discusses a method developed by Broida and Moyer, the method describes an emission spectrometer procedure for the determination of the ratio 100 D/(H4D).
Date: July 30, 1951
Creator: Parodi, J. A.; Burch, W. G.; Kendall, L. F. & Leboeuf, M. B.
System: The UNT Digital Library
Laboratory Demonstration of Redox Feed Head-End Treatment ; Ruthenium Volatilization and Manganese Dioxide Scavenging (open access)

Laboratory Demonstration of Redox Feed Head-End Treatment ; Ruthenium Volatilization and Manganese Dioxide Scavenging

From introduction: "The prime motive behind the experiments described in this report and in those preceding it in this series is the desire to reduce the number of Redox cycles necessary for decontamination from fission products of the plutonium and uranium streams sufficient to allow final disposition of these two products...This report deals with the mechanics of manganese dioxide handing, laboratory development of manganese dioxide scavenging, and a series of experiments at multicurie level combining ruthenium volatilization and manganese dioxide scavenging in stainless steel equipment."
Date: July 15, 1951
Creator: Hicks, H. G.; McCormack, C. G. & Roake, W. E.
System: The UNT Digital Library
Experimental Rolling of Uranium : Lackawanna No. 3 (open access)

Experimental Rolling of Uranium : Lackawanna No. 3

The following report is one of a series of rolling tests to establish the rolling process for Feed Materials Production Center at Fernold, Ohio. The primary objective of this program is to find a mechanically feasible process for continuous rolling of uranium.
Date: December 13, 1951
Creator: Riches, J. W.
System: The UNT Digital Library
Accumulation of Radioactivity in Columbia River Fish in the Vicinity of the Hanford Works (open access)

Accumulation of Radioactivity in Columbia River Fish in the Vicinity of the Hanford Works

Abstract: The data obtained from the radioassay of fish collected in vicinity of the Hanford Works between April, 1948 and June, 1950 are presented. Most of the radioactivity in the fish resulted from the concentration of p32 in the scales, bone, and certain visceral organs. The level of activity density in the fish was influenced by size, feeding habits and metabolic rate in addition to the activity density of the water. Changes in operation of nuclear reactors have resulted in progressive increases in activity densities of fish from one year to the next. The levels of radioactivity are not sufficiently high to be hazardous to either the fish or persons eating them.
Date: July 1, 1952
Creator: Olson, P. A., Jr. & Foster, Richard F.
System: The UNT Digital Library