Abstract: "In a study of the preparation and properties of delta-phase zirconium hydride it was found that large, sound bodies of the hydride can be prepared by direct combination of the elements if the rate of the reaction is retarded by limiting the supply of available hydrogen. Specimens up to 1-in. diameter were prepared using this technique. Because delta phase zirconium hydride does not readily form eutectics with iron-and nickel-base alloys below 1800 F these materials may be utilized for clodding the hydride. Delta-phase zirconium hydride is unaffected by exposure to liquid NaK or to nitrogen gas at temperatures below 1000 F. The hot hardness of delta-phase zirconium hydrid is about 130 kg per mm-2 at room temperature and 40 kg per mm-2 at 1500 F. The mean coefficient of thermal expansion (68 to 1337 F) is 6.5 x 10^-6 per deg F. The thermal conductivity varies from 5.7 Btu/(ft)(hr)(F) at 300 F to 5.1 Btu/(ft)(hr)(F) at 1300 F."

Abstract: A study has been made of the cladding of solid and powdered delta-phase zirconium hydride is both red and flat shapes with stainless steel. The program included investigations of metallurgical bonding, both with and without the sore of metallic barrier materials. Types 304 and 347 stainless steel were used for cladding material. The intermediate barrier-layer materials used were niobium, molybdenum, a combination of copper and molybdenum, and a combination of copper and niobium. The pressure-bonding techniques, involving the use of gas pressure at elevated temperatures, was employed in this study. Variable times and temperatures with a constant pressure of 10,000 poi were utilized by produce bonding. In this study, the best results were archived is cladding delta-phase zirconium hydride directly with Types 304 or 347 stainless steel. Good bonds were obtained by pressure bonding at 1600 F for 3 or 4 hr subsequent to pressure bonding at 1900 F for 1 to 2 hr at a pressure of 10,000 poi. Partial bonding was achieved between niobium and zirconium hydride and molybdeum and girconium hydride.