Some Observations on the Reactivity of Plutonium Dioxide (open access)

Some Observations on the Reactivity of Plutonium Dioxide

The index of refraction of PuO2 made by thermal decomposition of PU(C2O2, 6H2O gradually increases from a value < 1.9 to 2.40 as the decomposition temperature is increased from 150 degree to l000 degree C. This change in refractive index parallels a gradual change in the x-ray diffraction pattern from weak, diffuse lines for PuO2 ignited at 150° to sharp, well resolved lines for PuO2 ignited at 1000°C. Similar results are observed for PuO2 made by thermal decomposition of Pu2(C2O4)3*11H2O. The refractive index of PuO2 made from Pu metal at 170°C is 2.40 and is not affected by further ignition at higher temperatures, although crystal growth does occur. The rate of solution of PuO2 in an HCl-KI solution is greatest for samples prepared at low temperatures and decreases markedly for oxides ignited at higher temperatures. These observations hive been interpreted to mean that ignition at higher temperatures causes a gradual perfection of the originally highly distorted and impurity-containing PuO2 lattice obtained by low temperature decomposition of the oxalates and promotes the slow growth of crystallites. Both factors decrease the reactivity of the PuO2.
Date: September 1, 1954
Creator: Bjorklund, C.W. & Staritzky, Eugene
System: The UNT Digital Library
Determination of Thorium in Plutonium-Thorium Alloys (open access)

Determination of Thorium in Plutonium-Thorium Alloys

A spectrophotometric method used in the determination of thorium was modified for the purpose of analyzing plutonium alloys which contained 0.01 to 0.8 percent thorium. Absorbance values were measured at 545 millimicrons for solutions containing thorium and thorin, the organic reagent added to form a colored complex with thorium in the presence of plutonium (III) . With plutonium-thorium 0.8 percent thorium, the average recovery of thorium was 99.6 +- 1.5 percent. For similar samples containing 0.01 to 0.2 percent thorium, the average recovery 101.0 +- 3.4 percent, after the thorium was separated from plutonium by precipitation of thorium fluoride with the aid of lanthanum fluoride as a carrier.
Date: September 1954
Creator: Bergstresser, K. S. (Karl Samuel), 1909-2004 & Smith, Maynard E. (Maynard Elliott)
System: The UNT Digital Library
On the Conductivity of ionized Gas (open access)

On the Conductivity of ionized Gas

The conductivity of ionized gases is treated by a method similar to that used by Alfven in his book "Cosmical Electrodynamics". The results differ from those of Alfven. In particular, it is shown that Alfven's conclusion, that whenever the Hall current disappears the conductivity becomes independent of the magnetic field, is not true in general. Moreover, it is not true under just the conditions of interest for the "Pinch Effect". The main conclusions of the present paper are (1) of currents down a tube, the ion component is the small fraction of m/M of the electron current, regardless of the magnitude of the magnetic field; (2) the conduction along the tube depends on the transverse motion of neutral mass, i.e. on the radial velocity of u(r) of the gas in the tube.
Date: September 15, 1954
Creator: Konopinski, Emil Jan, 1911-
System: The UNT Digital Library
Infinite Conductivity Theory of the Pinch (open access)

Infinite Conductivity Theory of the Pinch

With the assumption of infinite conductivity a simple model may be constructed for the dynamic construction of a current carrying plasma, i.e., the pinch effect. The magneto-hydrodynamic equations of this model are discussed and solved. It is also shown that the infinite conductivity model can be derived from a picture of particles orbiting without collisions in the fields set up by their motions.
Date: September 14, 1954
Creator: Rosenbluth, M.; Garwin, R. & Rosenbluth, A.
System: The UNT Digital Library