Extremely radioactive particles result from the abrasive wheel cutting of irradiated fuel elements in the cut-off cell located in the 327 Building. Due to the use of water during the cutting operation these particles are in suspension and must be removed before the liquid can be discharged to the liquid waste tanks in the 340 building. The filters presently employed in the cell total activity discharged to the 340 Building tanks is attributed to the particles which pass these filters. With the start-up of a new, larger cut-off cell the cutting is expected to increase considerably, thereby increasing the amount of radioactive cuttings requiring disposal. The installation of equipment which would more efficiently remove the suspended particles would (1) reduce the activity level of wastes disposed to ground, (2) reduce the radiation exposure level to drivers who truck the wastes to the 200 Area, and (3) prevent the forming of localized high radiation zones due to the deposition of particles in the waste line in the 327 Building.

Disposal of liquid radioactive wastes to ground requires knowledge of the area ground-water hydrology. Information is desired on direction and velocity of ground-water flow. Direction of flow can be determined from maps showing contours on the water table surface, such contours being derived from well water elevations. Ground-water velocity is more difficult to ascertain.

Through the years, considerable effort has been expended in studies of the explosive reactions sometimes observed in the dissolution of uranium-zirconium alloys in nitric acid. It has been shown (1) that such reactions result from the rapid oxidation of finely dived solids released by the preferential dissolution of the metallic matrix. The explosive portion of such solids has been identifies (1) as an intermetallic compound with the approximate composition UZr2. This compound, referred to as the epsilon phase in previous work, has more recently (2) been termed the delta phase. The latter designation will be employed here.

One of the UO2 fuel element designs proposed for use in the PTRT is the nested tubular concepts. This configuration compromises a central fuel todo surrounded by two concentric tubes of fuel (see sketch, appenx I.) . These UO2 shapes are to be jacketed in the Zircaloy and must be separated from each other and the procuresses tyvm vt annular spaces for the passage of coolant. The annuli are established and and maintained by the longitudinal ribs on the outer surface of all three jacketed fuel elements.

The attached survey information comprises a cross section of Air and Gas Cleaning Operations as used in the Chemical Processing Department at the Hanford Atomic Products Operation, Richland, Washington. Most of the information as requested by J. T. Fitsgerald, Harvard University, is included in these surveys, certain cost information was difficult to isolate in the manner requested and may, therefore, be only roughly approximate. The numerical significance of the data will indicate this in most instances.

Very little information and data are available on the various physical properties of Zircaloy tubing, especially the high temperature- high pressure failure aspects. As greater use is being made of the low cross-sectional properties of this material in the design and development of reactor components, it was considered desirable to determine the type of failure that would be experienced under conditions of a localized over-heating. This hot-spot could be caused by "cocked" or warped fuel elements coming in direct contact with the process tube, thereby preventing adequate cooling media at the particular location.

The Zircaloy-a clad, swaged UOa, 19-rod cluster fuel element for the PRTR was designed to use Zircaloy-a wire spirally wrapped around the fuel rods as spacing members. Such use of unbonded, Zircaloy-a spacers introduced the possibility of fretting corrosion. This paper reports preliminary irradiation tests conducted to determine whether or not such corrosions occurs in this fuel element design.

Sinterability studies on mixtures of UO2 and PuO2 powders have been continued. All of the censities from previous sintering experiments have been recalculated utilizing a somewhat different water immersion technique. Since densities of pellete obtained by physical dimensions are inaccurate due to chipping, and water immersion does not account for the open porosity, the pellets were coated with clear krylon before being immersed in water. This effectively sealed the open pores. Plots of density versus composition still indicate a drastic reduction in UO2 sinterability with even the slightest additions of PuO2 and a rapid increase with PuO2 contents greater than 20 weight percent. The following table compares densities of pure UO2 and PuO2 after an eight hour soak time:

Aluminum nitrate solutions are used as salting agents in the redox process and frequently in organic-aqueous extractions in the laboratory. Determination of specific gravity is a convenient means of estimating the concentration of such solutions. However, where an aluminum nitrate solution has been prepared by dissolving aluminum hydrate in nitric acid, the ratio of nitrate to aluminum may intentionally be other than stoichiometric, the solutions being described as acid, neutral, or acid deficient.

The basic process for fabricating a swaged fuel rod is simple, easy to control and inexpensive. A zircaloy tube is filled with uranium dioxide powder, the ends temporarily plugged and the loaded tube is swaged to compact the UO2 powder to the required density. The swaged rod is then cut to length and counterbored and then end cape are welded into each end. After several tests and inspections, nineteen rods which meet the quality standards are assembled into a single fuel element ready for irradiation.

In connection with the study of aqueous-tributyIphosphate (TBP) systems, the study of the interactions of various diluents with the TBP has been extended. The diluents used were mineral oil, Amsco 125-90W, dodecane, n-hexane, cyclohexane, benzene, n-octyl bromide, carbon tetrachloride, chloroform and pentachloroethane. The solubility of TBP in water from solutions of these diluents and the solubility of water in the organic phase was determined. For the paraffin hydrocarbons as diluents the solubility of TBP in water was found to increase with increasing molal volume of the diluent. No evidence for the formation of TBP-water complex of simple mole ration was found.

The preparation of radioactive metallurgical specimens for microscopic examination is one of the responsibilities of the Radiometallurgy Sub-Unit. An abrasive cut-off machine development program, based upon a previous experimental model, was undertaken to provide a method for sectioning of irradiated materials without undue personnel exposure or spread of contamination and finally to provide data for the design of an abrasive cutting unit for use in the work cells in the Radiometallurgy Building. A horizontal-feed type set-off machine, powered by a 7 1/2 hp motor with V-belt drive, has been developed for the submerged sectioning of irradiated uranium and is currently being used successfully to obtain samples for metallurgical, chemical and physical investigations without excessive personnel exposure or spread of radioactive contaminates.

A laboratory test was performed to determine if a 10% oxalic acid solution could be safely be employed as a substitute to 2% chromic acid plus 5% phosphoric acid for removal of corrosion products from aluminum corrosion samples or slugs.

Plankton collected from the Columbia River by the net method and by the centrifuge method were compared. The centrifuged plankton (nannoplankton) exceeded the net plankton in weight, in abundance of organisms and in radioactivity. Similar seasonal trends were present in both types of plankton.

An analytical method for Cu-64 in reactor effluent has been studied based upon electrodeposition of the active copper with inert copper carrier. A two hour plating time was employed at a current density of 10 ma/sq cm and four volts across the cell. A stainless steel cathode plate was used. Carrier yields of greater than 80% were obtained with a standard deviation of the yield-corrected counting rate as low as 0.24%. Very little, if any contamination by other radioactive elements present was shown by decay curve studies. Self-absorption and self-scatter factors to correct the counting rate were obtained.

This report refutes earlier calculations made in the flux level of exponential piles. The results of the earlier calculations made on subcritical assemblies using critical assembly equations are in error. The calculations used in this report were more successful.

An addendum to report HW-30390 a additional power generation calculation for P, the rate of energy release, in kilowatts, was derived.

Report describing tests "in which a double chambered irradiation capsule containing NaK (sodium-potassium alloy) in its inner chamber was deliberately perforated to allow NaK (the heat transfer medium) and water to react within the capsule chambers" (p. 2). The report includes descriptions of the materials used in the tests, test procedures, and results.

Methods of the Radiation Monitoring Operation of the Chemical Processing Department.

The purposes of this study are to review the available information affecting the disposal of Purex cooling water, powerhouse waste water, and B plant cooling water, to consider the feasibility of various disposal schemes, and to prepare recommendations to the Manufacturing Department for the most desirable courses of action.

The design notes contained herein may assist in preliminary studies concerning feasibility of any proposed gamma monitor system. The minimum and maximum solution concentrations for each type of system are listed. The data is based on 32 ml liquid sample.

This report describes a proposed modification to the ventilation system in the Redox Canyon Building. Detailed drawings and cost estimates are provided for three alternatives.

Relations governing the measurement of Stainless Steel corrosion rates by activation analysis are derived and discussed. The principal neutron induced radioactivities are calculated and graphed. Shielding requirements are considered and it is concluded that six inches of lead shielding should be sufficient for the proposed experiments if the samples are allowed to cool for one day in the reactor storage basin.

The object of this study was to determine whether agitation with ultrasonic energy would significantly increase the dissolution rate of nickel in nitric acid.