The Production of Beryllium by the Metallothermic Reduction of Beryllium Fluoride (open access)

The Production of Beryllium by the Metallothermic Reduction of Beryllium Fluoride

Report discussing "the production of beryllium by the metallothermic reduction of its fluoride...Charges of BaF2 and Mg reacted smoothly when heated by induction in graphite crucibles and on continued heating the metal and slag separated fairly well. It was found that an addition of CaCl2 to the top of the charge facilitated the separation a great deal. Very clean, massive metal has been produced by this procedure."
Date: September 30, 1945
Creator: Spedding, F. H.; Wilhelm, H. A.; Keller, W. H. & Noher, Charles
System: The UNT Digital Library
Pyrohydrolysis in the Analysis of Fluorides and Other Halides (open access)

Pyrohydrolysis in the Analysis of Fluorides and Other Halides

Abstract. Fluorides and other halides are hydrolyzed completely by passing a rapid stream of superheated steam over the sample near 1000 degrees C in a specially designed platinum reaction tube. The steam and hydrogen halide are condensed by cooling, and the resulting distillate titrated with standard sodium hydroxide solution. The fluorides and chlorides of the light metals, hitherto thought of as very difficult to hydrolyze, are mixed with U3O8, or other metallic oxides, which reacts with the products of hydrolysis, thus shifting the equilibrium so that the reaction is complete in a comparatively short time. A description of the apparatus, including photographs, the recommended method of procedure, hydrolysis rate graphs, and suggestions for further applications of the method are given.
Date: June 30, 1945
Creator: Cline, W. D.
System: The UNT Digital Library
Composition and Thermal Decomposition of Uranyl Peroxide (open access)

Composition and Thermal Decomposition of Uranyl Peroxide

Technical report on the studies that have been made on the composition and thermal decomposition of uranyl peroxide. The conditions of precipitation and drying have been found to have no appreciable effect on the composition of the compound, but do affect the physical appearance of the precipitate and the rate of thermal decomposition. The UO4 + 2H2O appears to be thermodynamically unstable with respect to UO3 at 25 degrees C and atmospheric pressure, although the rate of conversion is extremely slow. The UO4 + 2H2O is completely converted to UO3 on standing at 150 degrees C and atmospheric pressure for two weeks. Partially decomposed uranyl peroxide samples contain extra oxygen which is released on immersing the sample in water.
Date: June 30, 1945
Creator: Leininger, R. F.; Hunt, J. P. & Koshland, D. E., Jr.
System: The UNT Digital Library
Unwatering and sampling of the Kirk Mine, Gilpin County, Colorado (open access)

Unwatering and sampling of the Kirk Mine, Gilpin County, Colorado

Two parts of a report. Part I is regarding unwatering and sampling of the Kirk mine. Part II discusses the geology of kirk mine. Kirk mine is located in Gilpin County, Colorado.
Date: April 30, 1945
Creator: Hill, J. M.; Selfridge, G. C.; George, D. R. & Guillotte, G. B.
System: The UNT Digital Library