The ICPP processed Al fuel, prtncipally of the MTR-ETR type, durtng this quarter. Newly designed and installed processing equipment exhibited excellent operating performance. This included direct-air-pulsed extraction, stripping and scrub columns, and a cascade-controlled continuous evaporator in first cycle product concentration service. Aqueous zirconium fuel processing studies continued with the objective of adapting the hydrofluoric acid process to continuous dissolution-complexing to increase the capacity of the LCPP process while using as much existing equipment as possible to minimize costs. Six variations of hydrofluoric acid flowsheets were tested in a smallscale continuous dissolvers. Dissolution rates were found to be high in all cases and dissolution was easily initiated at temperatures as low as 36 deg C. Monel and Carpenter 2O(Nb) were found to be satisfactory construction materials, from the standpoint of corroston, if oxidizing conditions were carefully controlled. Additional studies are reported on the stability of blended Zr and Al process raffinates and on the nature of the solids which result from the sodium formate headend precipitation process. Electrolytic dissolution studies, dtrected at fundamentals of current utiltzation in a series''-type dissolver, demonstrated that high current utilization is obtained when the polarization resistance is small compared with the solution resistance. Factors affecting …

Technical report outlining the nature and effects of energy loss and radiation in biological materials during radiobiological processes.

Technical report outlining the effects of chromosomal abnormalities in tetraploid Argentine flint maize pollination, and subsequent generations.

The enrichment inventory required in the Hanford reactors is greatly dependent on the location of the radial enrichment ring. Present and past philosophy has dictated that the radial enrichment be located as close to the periphery of the reactors as possible, consistent with total control criteria, to obtain maximum flattening efficiency. As long as individual tube power limits dictate total pile power this philosophy of maximum flattening is consistent with a goal of maximum production. For the past year the total pile power at the K reactors has been restricted by bulk outlet water temperature limit or administrative total power level limits. During this time fuel ruptures have been negligible due to improved metal quality and axial flux shaping. If present operating conditions continue the relocation of the enrichment ring could be desirable to decrease the enrichment inventory. Moving the radial enrichment toward the center of the reactor to decrease the inventory would result in lower flattening efficiency and require higher tube power limits for the same total pile power level.

Declassified 27 Nov 1973.<><DSN>29:020169<ABS>Declassified 27 Nov 1973.

Lactates of all the rare earths except lanthanum, cerium, and praseodymium were prepared and studied. In the case of lanthanum, cerium, and praseodymium the laciates are apparently so soluble that they cannot be crystallized directly from aqueous solution. Products obtained by addition of anhydrous ethanol to sirupy solutions of the iight-rare-earth lactates were not well characterized and were deliquescent. Neodymium lactate trinydrate was prepared only by the addition of alcohol to a sirupy solution. Since it was not as deliquescent as the lactates of lanthanum, cerium, and praseodymium, some of its properties could be studied. The lactates of all the other rare earths, samarium through lutetium, as well as the lactate of yttrium, separated readily from aqueous media as trinydrates---the solubility of the hydrated lactate decreasing as the atomic number of the rare earth increased. Thermal decomposition of the crystalline lactates, except those of neodymium and samarium, proceeded through dihydrated and anhydrous states to a composition corresponding roughly to LnlacCOa at a temperature of about 290 to 300 deg C. Ln/ sub 2/(CO/sub 3/)/sub 3/ or Ln/sub 2/O(CO/sub 3/)/sub 2/ was obse rved. In order to make a comparison, thermal decomposition of the rareearth glycolates was studied also. Solubilities in …

From abstract: "Lactates of all the rare earths except lanthanum, cerium, and praseodymium were prepared and studied. In the case of lanthanum, cerium, and praseodymium the lactates are apparently so soluble that they cannot be crystallized directly from aqueous solution. Products obtained by addition of anhydrous ethanol to sirupy solutions of the light-rare-earth lactates were not well characterized and were deliquescent. Neodymium lactate trihydrate was prepared only by the addition of alcohol to a sirupy solution. Since it was not as deliquescent as the lactates of lanthanum, cerium, and praseodymium, some of its properties could be studied. The lactates of all the other rare earths, samarium through lutetium, as well as the lactate of yttrium, separated readily from aqueous media as trihydrates--the solubility of the hydrated lactate decreasing as the atomic number of the rare earth increased. Thermal decomposition of the crystalline lactates, except those of neodymium and samarium, proceeded through dihydrated and anhydrous states to a composition corresponding roughly to LnlacCO3 at a temperature of about 290-300°C. Ln2(CO3)3 or Ln2O(Co3)2 were observed. In order to make a comparison, thermal decomposition of the rare-earth glycolates was studied also. Solubilities in water at both 20 and 60°C have been tabulated."