Acceptance criteria for uranium check standards used to verify fluorimeter calibration have been developed. This work was done in response to Tiger Team finding QA/BMP-5, item 4. Data used as input to these calculations is retained in the Tiger Team closeout file, located in the Technical Service Division managers office. 3 refs., 4 tabs.

A Pulsed Lepton Source is being considered at the LAMPF facility at Los Alamos National Laboratory. The source plan is described together with a description of the components and performance as they exist at present. 9 figs.

Despite the rise in petroleum products prices, a colder-than-normal winter in the latter part of 1989 spurred an increase in demand for distillate fuel oils. The shipping and electric utilities industries contributed to a significant rise in demand for both distillate and residual fuels oils in 1989. A total of 72.9 billion gallons of fuel oil and kerosene were sold to consumers in 1989, an increase of 3.0 percent over 1988 sales volumes. Of all fuel oil sold during 1989, distillate fuel oil accounted for 68.3 percent, which was an increase over 1988 when distillate fuel oil accounted for 67.2 percent of all fuel oil products sold in the United States. Residual fuel oil's share of total fuel oil sold fell slightly to 29.9 percent from 30.7 percent in 1988. Kerosene followed with a 1.8 percent share, also falling from the previous year when it accounted for a 2.1 percent share of total fuel oil sold. 3 figs., 24 tabs.

Radian Corporation was contracted to investigate duct injection and electrostatic precipitator phenomena in a 1.7-MW pilot plant constructed for this test program. This study was an attempt to resolve previous problems and to answer remaining questions with the technology using an approach which concentrated on the fundamental mechanisms of the process. The goal of the study was to obtain a better understanding of the basic physical and chemical phenomena that control: (1) the desulfurization of flue gas by calcium-based reagent, and (2) the coupling of the duct injection process to an existing ESP particulate collection device. (VC)

A design study for a Pion Linac (PILAC) at LAMPF is under way at Los Alamos. We present here a reference design for a system of pion source, linac, and high-resolution beam line and spectrometer that will provide 10{sup 9} pions per second on target and 200-keV resolution for the ({pi}{sup +}, K{sup +}) reaction at 0.92 GeV. A general-purpose beam line that delivers both positive and negative pions in the energy range 0.4-1.1 GeV is included, thus opening up the possibility of a broad experimental program as is discussed in this report. A kicker-based beam sharing system allows delivery of beam to both beam lines simultaneously with independent sign and energy control. Because the pion linac acts like an rf particle separator, all beams produced by PILAC will be free of electron (or positron) and proton contamination. 4 refs., 6 figs.

Plastic crystal behavior is observed in semiconducting CsPb and NaSn at high temperature (600 and 500 C, respectively). This behavior is associated with M{sub 4}{sup 4{minus}} or A{sub 4}M{sub 4} structural units orientationally disordering about 50 C below the melting point where translational disorder sets in. This orientational disorder is different in the two phases, exhibiting jump reorientations in CsPb and a more isotropic behavior in NaSn. In other Zintl compounds such as KPb, there is a single melting point where orientational and translational disorder sets in simultaneously; the classification of the different Zintl compounds into these two different kinds of behavior will require calorimetry or neutron diffraction below the melting point. (DLC)

The NATO-ASI on Diamond and Diamond-Like Films and Coatings'' was an opportunity for us to learn the latest research results from ongoing programs in the leading laboratories of the world and relate them to our work. Specific examples are given in the comprehensive report which follows. The meeting format provided an ideal environment to meet and interact with our international counterparts. It is clear that our studies are well regarded, and that we have established an excellent reputation in a short time. New opportunities for collaboration were identified. A panel discussion at the end of the meeting addressed the needs and opportunities in the synthesis of CVD diamond. The key scientific needs are those related to modeling the nucleation and growth processes and to elucidation of the critical roles of atomic hydrogen and the mechanisms of carbon addition to the growing surfaces. The development and more extensive use of in situ diagnostics for both surface and gas phases are important to solving these issues. The more immediate practical questions concern the identification of the growth-rate-limiting steps, the relation of growth parameters to the resulting film structure, and the dependence of properties on structure.

Low-level, hazardous, and mixed waste disposal sites normally require some form of plant material to prevent erosion of the final closure cap. Waste disposal sites are closed and capped in a complex scientific manner to minimize water infiltration and percolation into and through the waste material. Turf type grasses are currently being used as an interim vegetative cover for most sites. This coverage allows for required monitoring of the closure cap for settlement and maintenance activities. The purpose of this five year study was to evaluate plant materials for use on wastes sites after the post-closure care period that are quickly and easily established and economically maintained, retard water infiltration, provide maximum year-round evapotranspiration, are ecologically acceptable and do not harm the closure cap. The results of the study suggest that two species of bamboo (Phyllostachys (P.) bissetii and P. rubromarginata) can be utilized to provide long lived, low maintenance, climax vegetation for the waste sites after surveillance and maintenance requirements have ceased.

Melter feed preparation processes, incorporating a final wash of the precipitate slurry feed to Defense Waste Processing Facility (DWPF) and a partial substitution of the SRAT formic acid requirement with nitric acid, should not produce peak hydrogen generation rates during Cold Chemical Runs (CCR's) and radioactive operation greater than their current, respective hydrogen design bases of 0.024 lb/hr and 1.5 lb/hr. A single SRAT bench-scale process simulation for CCR-s produced a DWPF equivalent peak hydrogen generation rate of 0.004 lb/hr. During radioactive operation, the peak hydrogen generation rate will be dependent on the extent DWPF deviates from the nominal precipitate hydrolysis and melter feed preparation process operating parameters. Two actual radioactive sludges were treated according to the new flowsheets. The peak hydrogen evolution rates were equivalent to 0.038 and 0.20 lb/hr (DWPF scale) respectively. Compared to the formic acid -- HAN hydrolysis flowsheets, these peak rates were reduced by a factor of 2.5 and 3.4 for Tank 15 and Tank 11 sludges, respectively.

In order to minimize solids deposition in the off-gas line between the primary film cooler and the quencher, Savannah River Laboratory (SRL) recommended earlier that a new DWPF melter off-gas jumper be built which would increase the off-gas velocity from less than 40 ft/s under the original design to at least 55 ft/s, excluding the melter air inleakage. Two design changes proposed for the new jumper were: (1) relocation of the entry point for the melter pressure control air from the current position near the quencher to near the film cooler exit, and (2) reduction of the inside diameter of the jumper from 8.33 to 7.156 inches. The objective of this study was to confirm the, optimum inside diameter (I.D.) proposed earlier and determine the upper and lower limits for the optimum, I.D. to initiate the actual design process. Based on more conservative bases for optimization used in this study, it was determined that the design limits for the new jumper I.D. is 7.15 [le] I.D. [le] 7.25 inches.

The overall project objective is to demonstrate the high efficiency of the Adams Counter-Current shale oil recovery process. The efficiency will first be demonstrated on a small scale, in the current phase, after which the demonstration will be extended to the operation of a small pilot plant. Thus the immediate project objective is to obtain data on oil shale retorting operations in a small batch rotary kiln that will be representative of operations in the proposed continuous process pilot plant. Although an oil shale batch sample is sealed in the batch kiln from the start until the end of the run, the process conditions for the batch are the same as the conditions that an element of oil shale would encounter in a continuous process kiln. Similar chemical and physical conditions (heating, mixing, pyrolysis, oxidation) exist in both systems.The two most important data objectives in this phase of the project are to demonstrate (1) that the heat recovery projected for this project is reasonable and (2) that an oil shale kiln will run well and not plug up due to sticking and agglomeration. The following was completed this quarter. (1) Twelve pyrolysis runs were made on five different oil shales. …

We present the results of a measurement to understand the effects of transverse misplacement of the [sup 137]Cs source tube inside the cast Pb plates of the SDC EMC calorimeter. The PMT current from a scintillator was measured as the [sup 137]Cs source was displaced by varying thicknesses of Pb, as well as varying thicknesses of air gap. At a nominal depth of 2 mm in Pb, we find a change in scintillator output of about 25%/mm, and about 10%/mm of air gap. The data are compared to a simple calculation. By taking the sum of the scintillators on top and below a source tube, we estimate a source tube displacement of [plus minus]450[mu] will cause an error in the PMT output by 1%.

This report covers the research progress made during the calendar year 1992. The new results obtained during this period are described, keyed to the references listed on the last two pages of this report.

This document recommends an interim dilution strategy for the low nitrite precipitate hydrolysis process. A minimum carbon dioxide purge rate of 27 scan during feeding and for 15 minutes after feeding and a maximum precipitate slurry feed rate of 36 gpm are recommended. These recommendations provide an interim dilution strategy that will provide for the start of cold chemical runs and until additional offgas data is collected from the PHEF (Precipitate Hydrolysis Experimental Facility).

This document reviews results from a number of studies concerning underground migration of radionuclides from nuclear test cavities at the Nevada Test Site (NTS). Discussed are all cases known to the Department of Energy's Hydrology and Radionuclide Migration Program where radionuclides have been detected outside of the immediate vicinity of nuclear test cavities that are identifiable as the-source of the nuclides, as well as cases where radionuclides might have been expected and were intentionally sought but not fixed. There are nine locations where source-identifiable radionuclide migration has been detected, one where migration was purposely induced by pumping, and three where migration might be expected but was not found. In five of the nine cases of non-induced migration, the inferred migration mechanism is prompt fracture injection during detonation. In the other four cases, the inferred migration mechanism is water movement. In only a few of the reviewed cases can the actual migration mechanism be stated with confidence, and the attempt has been made to indicate the level of confidence for each case. References are cited where more information may be obtained. As an aid to future study, this document concludes with a brief discussion of the aspects of radionuclide migration that, …

Project Work Plan was developed with joint participation by all subsystem teams. Comprehensive overall project activity schedules were developed for all individual B W groups and subcontractors with participation in Phase I.

This document contains the first quarterly technical progress report for PTI's Bench-Scale Testing Project of a circuit integrating PTI's KEN-FLOTETM Column Flotation Technology and PTI's On-Line Quality Monitor Control System. The twelve-month project will involve installation of a 300 lb/hr. bench-scale testing circuit at PETC's Coal Preparation Process Research Facility (CPPRF) and testing of two bituminous coals (Upper Freeport and Pittsburgh No. 8 Seam Raw Coals). Figure 1 contains the project plan as well as the approach to completing the major tasks within the twelvemonth project. The project is broken down into three phases, which include: Phase I - Preparation: The preparation phase was performed principally at PTI's Calumet offices from October through December, 1992. It involved building of the equipment and circuitry, as well as some preliminary design and equipment testing. Phase II - ET Circuit Installation and Testing: This installation and testing phase of the project will be performed at PETC's CPPRF from January through May, 1993, and will be the major focus of the project. It will involve testing of the continuous 300 lb/hr. circuit. Phase II - Project Finalization: The project finalization phase will occur from June through September, 1993, at PTI's Calumet offices and will …

Twenty tests for normality were compared for the purpose of detecting mixtures of two normal components with unequal means but equal variance. The purpose of this study was to determine the power of tests specifically designed to detect mixtures, i.e., the likelihood ratio and Engelman-Hartigan tests, relative to other tests for normality. We considered the entire range of mixing proportions [pi], 0 < [pi] < 1. For mixtures that are nearly symmetric (0.35 < [pi] < 0.65) the Engelman-Hartigan test was the most powerful. When [pi] > 0.85 or [pi] < 0.15, [radical]b[sub 1] was among the best tests. For intermediate mixing proportions, the likelihood ratio test was best. For situations in which the preferred test had power 50% or more, the power of the likelihood ratio test was also above 50% and within 15 percentage points of the preferred test.

In this note we will present closed expressions for the beam-beam deflection angle for arbitrary elliptic beams including tilt. From these expressions signature curves, i.e., systematic deviations from the round beam deflection curve due to ellipticity or tilt are derived. In the course of the presentation we will prove that it is generally impossible to infer individual beam sizes from beam-beam deflection scans. 3 refs., 2 figs.

The traveler attended the 16th MPA Seminar on the Safety and Reliability of Plant Technology with Special Emphasis on Nuclear Technology. The objective of the trip was to gather information and data that could prove useful to the US Nuclear Regulatory Commission (USNRC) sponsored Heavy-Section Steel Irradiation (HSSI) and Heavy-Section Steel Technology (HSST) Programs and to present a paper entitled, Effects of Irradiation on Initiation and Crack-Arrest Toughness of Two High-Copper Welds and on Stainless Steel Cladding. This paper summarizes results from the 5th, 6th, and 7th Irradiation Series of experiments performed within the HSSI Program by the Metals and Ceramics Division at Oak Ridge National Laboratory (ORNL).

While developing dry sorbent duct injection flue gas desulfurization processes may offer significant improvement in capital cost and process simplicity compared to wet scrubbing systems, the economics of this technology can be improved significantly by an improvement in sorbent utilization. While a general understanding of the mechanism by which the sorbents operate is known, a much more detailed knowledge of reaction rate-controlling phenomena, the role of inherent reactivity, and mass transfer effects and their interaction in needed. Objectives of this project are threefold: 1. Mass transfer investigation--determine the controlling physical and chemical processes that limit sorbent utilization. In particular, determine whether mass transfer is a controlling factor in in-duct flue gas desulfurization and establish the relative contributions of gas- and liquid-phase mass transfer and inherent sorbent reactivity. 2. Field test support--evaluate various sorbents, operating conditions and process schemes to support large-scale field testings at Meredosia and Beverly. 3. Mass transfer enhancement--examine various techniques that will enable sorbent utilization rates of at least 75 percent to be achieved. Sorbents investigated were Ca(OH){sub 2}, Mississippi hydrate and Mississippi slaked lime. Epsom Salt was investigated as an additive. Agglomeration of Ca(OH){sub 2} solids was also investigated. 3 refs., 92 figs., 23 tabs.

This progress report will give a detailed breakdown of the work accomplished for ARIES-III during the contract period, November 1, 1990 to October 31, 1991. The areas of effort discussed are: Neutronics; First-Wall; Shield; Safety; Systems; Startup and Shutdown; Energy Conversion; Ripple Loss; and Fuel Resources.

A laser flash photolysis kinetic study of 2,2{prime}-bipyridine bidentate chelating ligands with one claw in the first coordination sphere of a molybdenum carbonyl complex has been completed at pressures up to 150 MPa. The reaction mechanism for thermal ring closure is found from activation volumes to change from associative interchange to dissociative interchange as substituents on the 2,2{prime}-bipyridine ligands become bulkier. In a similar study of more rigid, substituted phenanthroline bidentate ligands it was found that substituent bulkiness had little effect on the thermal ring closure mechanism. Stability constants for lithium ion complexes with crown ethers in a room temperature molten salt, fluorescence quantum yields for cresyl violet and several other dyes in solution, and the oxidation of alcohols by OsO{sub 4} have also been investigated.

Theoretical physics problems related to divertor design are presented, organized by the region in which they occur. Some of the open questions in edge physics are presented from a theoretician's point of view. After a cursory sketch of the fluid models of the edge plasma and their numerical realization, the following topics are taken up: time-dependent problems, non-axisymmetric effects, anomalous transport in the scrape-off layer, edge kinetic theory, sheath effects and boundary conditions in divertors, electric field effects, atomic and molecular data issues, impurity transport in the divertor region, poloidally localized power dissipation (MARFEs and dense gas targets), helium ash removal, and neutral transport. The report ends with a summary of selected problems of particular significance and a brief bibliography of survey articles and related conference proceedings.