Many factors are responsible for the rapid growth of analytical chemistry during the past ten to fifteen years. One of the most important of these factors is the greatly increased significance to present day chemistry of many elements that in the recent past were principally chemical curiosities. Since the Atomic Energy program is concerned with many such elements, it is of interest to discuss the cause for this concern and the resulting effect on the field of analytical chemistry. A number of pertinent analytical research problems at Hanford will be cited as examples.

The processing of irradiated fuels from power and propulsion reactors is planned by Hanford Atomic Products Operation as part of the Atomic Energy Commission's interim reprocessing scheme. The several chemical processes proposed for the reprocessing of these fuels may be divided into two categories: first, total dissolution processes which dissolve both fuel element cladding and core material and, second, selective dissolution processes which dissolve either cladding or core material. The Niflex process uses a nitric and hydrofluoric acid solution for the total dissolution of stainless steel clad uranium fuel elements.