Chemistry of aliphatic sulfurpentafluoride derivatives (open access)

Chemistry of aliphatic sulfurpentafluoride derivatives

This report summarizes the literature through 1974 on aliphatic sulfurpentafluoride compounds. Methods of preparation and methods of transforming one pentafluorothio compound into another are briefly discussed. The physical properties of all known derivatives are tabulated. (auth)
Date: November 20, 1975
Creator: Bissell, E. R.
System: The UNT Digital Library
Internal friction in uranium (open access)

Internal friction in uranium

Results are presented of studies conducted to relate internal friction measurements in U to allotropic transformations. It was found that several internal friction peaks occur in $alpha$-uranium whose magnitude changed drastically after annealing in the $beta$ phase. All of the allotropic transformations in uranium are diffusional in nature under slow heating and cooling conditions. Creep at regions of high stress concentration appears to be responsible for high temperature internal friction in $alpha$-uranium. The activation energy for grain boundary relaxation in $alpha$-uranium was found to be 65.1 +- 4 kcal/mole. Impurity atoms interfere with the basic mechanism for grain boundary relaxation resulting in a distribution in activation energies. A considerable distribution in ln tau$sub 0$ was also found which is a measure of the distribution in local order and in the Debye frequency around a grain boundary. (auth)
Date: November 20, 1975
Creator: Selle, J. E.
System: The UNT Digital Library