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Flavorful supersymmetry (open access)

Flavorful supersymmetry

Weak scale supersymmetry provides elegant solutions to many of the problems of the standard model, but it also generically gives rise to excessive flavor and CP violation. We show that, if the mechanism that suppresses the Yukawa couplings also suppresses flavor changing interactions in the supersymmetry breaking parameters, essentially all the low energy flavor and CP constraints can be satisfied. The standard assumption of flavor universality in the supersymmetry breaking sector is not necessary. We study signatures of this framework at the LHC. The mass splitting among different generations of squarks and sleptons can be much larger than in conventional scenarios, and even the mass ordering can be changed. We find that there is a plausible scenario in which the next-to-lightest superparticle is a long-lived right-handed selectron or smuon which decays into the lightest superparticle, a gravitino. This leads to the spectacularsignature of monochromatic electrons or muons in a stopper detector, providing strong evidence for the framework.
Date: December 13, 2007
Creator: Nomura, Yasunori; Nomura, Yasunori; Papucci, Michele & Stolarski, Daniel
System: The UNT Digital Library
Monte Carlo without chains (open access)

Monte Carlo without chains

A sampling method for spin systems is presented. The spin lattice is written as the union of a nested sequence of sublattices, all but the last with conditionally independent spins, which are sampled in succession using their marginals. The marginals are computed concurrently by a fast algorithm; errors in the evaluation of the marginals are offset by weights. There are no Markov chains and each sample is independent of the previous ones; the cost of a sample is proportional to the number of spins (but the number of samples needed for good statistics may grow with array size). The examples include the Edwards-Anderson spin glass in three dimensions.
Date: December 12, 2007
Creator: Chorin, Alexandre J.
System: The UNT Digital Library
The Product Consistency Test How and Why It Was Developed (open access)

The Product Consistency Test How and Why It Was Developed

The Product Consistency Test (PCT), American Society for Testing Materials (ASTM) Standard C1285, is currently used world wide for testing glass and glass-ceramic waste forms for high level waste (HLW), low level waste (LLW), and hazardous wastes. Development of the PCT was initiated in 1986 because HLW glass waste forms required extensive characterization before actual production began and required continued characterization during production ({ge}25 years). Non-radioactive startup was in 1994 and radioactive startup was in 1996. The PCT underwent extensive development from 1986-1994 and became an ASTM consensus standard in 1994. During the extensive laboratory testing and inter- and intra-laboratory round robins using non-radioactive and radioactive glasses, the PCT was shown to be very reproducible, to yield reliable results rapidly, to distinguish between glasses of different durability and homogeneity, and to easily be performed in shielded cell facilities with radioactive samples. In 1997, the scope was broadened to include hazardous and mixed (radioactive and hazardous) waste glasses. In 2002, the scope was broadened to include glass-ceramic waste forms which are currently being recommended for second generation nuclear wastes yet to be generated in the nuclear renaissance. Since the PCT has proven useful for glass-ceramics with up to 75% ceramic component …
Date: December 15, 2008
Creator: Jantzen, Carol M. & Bibler, Ned E.
System: The UNT Digital Library
U-Sr isotopic speedometer: Fluid flow and chemical weatheringrates inaquifers (open access)

U-Sr isotopic speedometer: Fluid flow and chemical weatheringrates inaquifers

Both chemical weathering rates and fluid flow are difficultto measure in natural systems. However, these parameters are critical forunderstanding the hydrochemical evolution of aquifers, predicting thefate and transport of contaminants, and for water resources/water qualityconsiderations. 87Sr/86Sr and (234U/238U) activity ratios are sensitiveindicators of water-rock interaction, and thus provide a means ofquantifying both flow and reactivity. The 87Sr/86Sr values in groundwaters are controlled by the ratio of the dissolution rate to the flowrate. Similarly, the (234U/238U) ratio of natural ground waters is abalance between the flow rate and the dissolution of solids, andalpha-recoil loss of 234U from the solids. By coupling these two isotopesystems it is possible to constrain both the long-term (ca. 100's to1000's of years) flow rate and bulk dissolution rate along the flow path.Previous estimates of the ratio of the dissolution rate to theinfiltration flux from Sr isotopes (87Sr/86Sr) are combined with a modelfor (234U/238U) to constrain the infiltration flux and dissolution ratefor a 70-m deep vadose zone core from Hanford, Washington. The coupledmodel for both (234U/238U) ratios and the 87Sr/86Sr data suggests aninfiltration flux of 5+-2 mm/yr, and bulk silicate dissolution ratesbetween 10-15.7 and 10-16.5 mol/m2/s. The process of alpha-recoilenrichment, while primarily responsible for the observed variation …
Date: December 27, 2005
Creator: Maher, Kate; DePaolo, Donald J. & Christensen, John N.
System: The UNT Digital Library
A Chemical Approach to 3-D Lithographic Patterning of Si and GeNanocrystals (open access)

A Chemical Approach to 3-D Lithographic Patterning of Si and GeNanocrystals

Ion implantation into silica followed by thermal annealingis an established growth method for Si and Ge nanocrystals. Wedemonstrate that growth of Group IV semiconductor nanocrystals can besuppressed by co-implantation of oxygen prior to annealing. For Sinanocrystals, at low Si/O dose ratios, oxygen co-implantation leads to areduction of the average nanocrystal size and a blue-shift of thephotoluminescence emission energy. For both Si and Ge nanocrystals, atlarger Si/O or Ge/O dose ratios, the implanted specie is oxidized andnanocrystals do not form. This chemical deactivation was utilized toachieve patterned growth of Si and Ge nanocrystals. Si was implanted intoa thin SiO2 film on a Si substrate followed by oxygen implantationthrough an electron beam lithographically defined stencil mask. Thermalannealing of the co-implanted structure yields two-dimensionallypatterned growth of Si nanocrystals under the masked regions. We applieda previously developed process to obtain exposed nanocrystals byselective HF etching of the silica matrix to these patterned structures.Atomic force microscopy (AFM) of etched structures revealed that exposednanocrystals are not laterally displaced from their original positionsduring the etching process. Therefore, this process provides a means ofachieving patterned structures of exposed nanocrystals. The possibilitiesfor scaling this chemical-based lithography process to smaller featuresand for extending it to 3-D patterning is discussed.
Date: December 12, 2005
Creator: Sharp, I. D.; Xu, Q.; Yi, D. O.; Liao, C. Y.; Ager, J. W., III; Beeman, J. W. et al.
System: The UNT Digital Library
AN INNOVATIVE APPROACH FOR CONSTRUCTING AN IN-SITU BARRIER FOR STRONTIUM-90 AT THE HANFORD SITE WASHINGTON (open access)

AN INNOVATIVE APPROACH FOR CONSTRUCTING AN IN-SITU BARRIER FOR STRONTIUM-90 AT THE HANFORD SITE WASHINGTON

Efforts to reduce the flux of Sr-90 to the Columbia River from Hanford Site 100-N Area past-practice liquid waste disposal sites have been underway since the early 1990s. Termination of all liquid discharges to the ground in 1993 was a major step toward meeting this goal. However, Sr-90 adsorbed on aquifer solids beneath liquid waste disposal sites and extending beneath the near-shore riverbed remains a continuing contaminant source to groundwater and the Columbia River. The initial pump-and-treat system proved to be ineffective as a long-term solution because of the geochemical characteristics of Sr-90. Following an evaluation of potential Sr-90 treatment technologies and their applicability under 100-NR-2 Operable Unit hydrogeologic conditions, the U.S. Department of Energy and the Washington State Department of Ecology agreed to evaluate apatite sequestration as the primary remedial technology, combined with a secondary polishing step utilizing phytoextraction if necessary. Aqueous injection was initiated in July 2005 to assess the efficacy of in-situ apatite along the 100 m of shoreline where Sr-90 concentrations are highest. The remedial technology is being developed by Pacific Northwest National Laboratory. CH2M Hill Plateau Remediation Company is implementing this technology in the field with support from PNNL.
Date: December 8, 2008
Creator: RJ, FABRE
System: The UNT Digital Library
Localized Pd Overgrowth on Cubic Pt Nanocrystals for Enhanced Electrocatalytic Oxidation of Formic Acid (open access)

Localized Pd Overgrowth on Cubic Pt Nanocrystals for Enhanced Electrocatalytic Oxidation of Formic Acid

Single crystalline surface such as (100), (111), (110) has been studied as an idealized platform for electrocatalytic reactions since the atomic arrangement affects a catalytic property. The secondary metal deposition on these surfaces also alters the catalytic property often showing improvement such as poisoning decrease. On the other hand, electrocatalysts used for practical purpose usually have a size on the order of nanometers. Therefore, linking the knowledge from single crystalline studies to nanoparticle catalysts is of enormous importance. Recently, the Pt nanoparticles which surface structure was preferentially oriented was synthesized and used as electrocatalysts. Here, we demonstrate a rational design of a binary metallic nanocatalyst based on the single crystalline study.
Date: December 14, 2007
Creator: Lee, Hyunjoo; Habas, Susan; Somorjai, Gabor & Yang, Peidong
System: The UNT Digital Library
Unexplained Excess of Electron-Like Events From a 1-GeV Neutrino Beam (open access)

Unexplained Excess of Electron-Like Events From a 1-GeV Neutrino Beam

The MiniBooNE Collaboration observes unexplained electron-like events in the reconstructed neutrino energy range from 200 to 475 MeV. With 6.46 x 10{sup 20} protons on target, 544 electron-like events are observed in this energy range, compared to an expectation of 415.2 {+-} 43.4 events, corresponding to an excess of 128.8 {+-} 20.4 {+-} 38.3 events. The shape of the excess in several kinematic variables is consistent with being due to either {nu}{sub e} and {bar {nu}}{sub e} charged-current scattering or to {nu}{sub {mu}} neutral-current scattering with a photon in the final state. No significant excess of events is observed in the reconstructed neutrino energy range from 475 to 1250 MeV, where 408 events are observed compared to an expectation of 385.9 {+-} 35.7 events.
Date: December 1, 2008
Creator: Aguilar-Arevalo, A. A.; Anderson, C. E.; Bazarko, A. O.; Brice, Stephen J.; Brown, B. C.; Bugel, L. et al.
System: The UNT Digital Library
Nuclear Resonance Fluorescence Excitations Near 2 MeV in 235U and 239Pu (open access)

Nuclear Resonance Fluorescence Excitations Near 2 MeV in 235U and 239Pu

A search for nuclear resonance fluorescence excitations in {sup 235}U and {sup 239}Pu within the energy range of 1.0- to 2.5-MeV was performed using a 4-MeV continuous bremsstrahlung source at the High Voltage Research Laboratory at the Massachusetts Institute of Technology. Measurements utilizing high purity Ge detectors at backward angles identified 9 photopeaks in {sup 235}U and 12 photopeaks in {sup 239}Pu in this energy range. These resonances provide unique signatures that allow the materials to be non-intrusively detected in a variety of environments including fuel cells, waste drums, vehicles and containers. The presence and properties of these states may prove useful in understanding the mechanisms for mixing low-lying collective dipole excitations with other states at low excitations in heavy nuclei.
Date: December 27, 2006
Creator: Bertozzi, W.; Caggiano, J. A.; Hensley, W. K.; Johnson, M. S.; Korbly, S. E.; Ledoux, R. J. et al.
System: The UNT Digital Library
Magnetic Measurements and Simulations for a 4-magnet Dipole Chicane for the International Linear Collider (open access)

Magnetic Measurements and Simulations for a 4-magnet Dipole Chicane for the International Linear Collider

T-474 at SLAC is a prototype BPM-based energy spectrometer for the ILC. We describe magnetic measurements and simulations for the 4-magnet chicane used in T-474.
Date: December 17, 2007
Creator: Schreiber, H. J.; Viti, M.; /DESY; Duginov, V. N.; Kostromin, S. A.; Morozov, N. A. et al.
System: The UNT Digital Library
Dynamic Imaging of Surface Motion with a Stereo Borescope (open access)

Dynamic Imaging of Surface Motion with a Stereo Borescope

A new stereo borescope has been investigated that would provide a time-resolved calibrated method of recording the motion and deformation of a three-dimensional (3-D) surface during explosively driven dynamic shock experiments at the Nevada Test Site. In these experiments, geometries would likely prove to be incompatible with conventional direct optical systems. Single line-of-sight borescopes lack adequate depth-of-field for quantitative imaging of the 3-D surface. To improve depth-of-field and provide time resolution, a stereo borescope has been fabricated for use with a nine-frame framing camera. At one end, stereo optics couple light from the dynamic surface into a pair of flexible 1-mm-diameter correlated fiber-optic bundles. At the other end, small-format lenses (~3 mm) interface with the framing camera, which is set up to simultaneously record the separate-perspective views. All nine frames could be recorded in a period as short as 1.8 μs, and spatial resolution is optimized to 11 line-pairs per mm. To achieve pseudo 3-D depth perception, photogrammetric analysis has been demonstrated with commercial software from ADAM technology (Australia). This paper presents the results from time-resolved stereo images of dynamic surfaces collected in a series of high-explosives experiments at the National Security Technologies, LLC, “Boom Box” in Santa Barbara, CA. …
Date: December 11, 2008
Creator: Berninger, Michael & Baker, Stuart
System: The UNT Digital Library
A celestial gamma-ray foreground due to the albedo of small solar system bodies and a remote probe of the interstellar cosmic ray spectrum (open access)

A celestial gamma-ray foreground due to the albedo of small solar system bodies and a remote probe of the interstellar cosmic ray spectrum

We calculate the {gamma}-ray albedo flux from cosmic-ray (CR) interactions with the solid rock and ice in Main Belt asteroids and Kuiper Belt objects (KBOs) using the Moon as a template. We show that the {gamma}-ray albedo for the Main Belt and Kuiper Belt strongly depends on the small-body mass spectrum of each system and may be detectable by the forthcoming Gamma Ray Large Area Space Telescope (GLAST). The orbits of the Main Belt asteroids and KBOs are distributed near the ecliptic, which passes through the Galactic center and high Galactic latitudes. If detected, the {gamma}-ray emission by the Main Belt and Kuiper Belt has to be taken into account when analyzing weak {gamma}-ray sources close to the ecliptic, especially near the Galactic center and for signals at high Galactic latitudes, such as the extragalactic {gamma}-ray emission. Additionally, it can be used to probe the spectrum of CR nuclei at close-to-interstellar conditions, and the mass spectrum of small bodies in the Main Belt and Kuiper Belt. The asteroid albedo spectrum also exhibits a 511 keV line due to secondary positrons annihilating in the rock. This may be an important and previously unrecognized celestial foreground for the INTErnational Gamma-Ray Astrophysics Laboratory …
Date: December 17, 2007
Creator: Moskalenko, Igor V.; Porter, Troy A.; Digel, Seth W.; Michelson, Peter F. & Ormes, Jonathan F.
System: The UNT Digital Library
Evidence against correlations between nuclear decay rates and Earth-Sun distance (open access)

Evidence against correlations between nuclear decay rates and Earth-Sun distance

We have reexamined our previously published data to search for evidence of correlations between the rates for the alpha, beta-minus, beta-plus, and electron capture decays of 22Na, 44Ti, 108Agm, 121Snm, 133Ba, and 241Am and the Earth?Sun distance. We find no evidence for such correlations and set limits on the possible amplitudes of such correlations substantially smaller than those observed in previous experiments.
Date: December 8, 2008
Creator: Norman, Eric B.; Browne, Edgardo; Shugart, Howard A.; Joshi, Tenzing H. & Firestone, Richard B.
System: The UNT Digital Library
D and B meson spectroscopy, new states, baryons at the Tevatron (open access)

D and B meson spectroscopy, new states, baryons at the Tevatron

We review recent results in heavy quark hadron spectroscopy at the Tevatron. With increasing data samples, the Tevatron experiments start to uncover information on the spectroscopy of b-hadrons. Most important are the first observations of the narrow B**{sub s}{sup 0} as well as {Sigma}{sub b}{sup {+-}}, {Sigma}*{sub b}{sup {+-}} and {Xi}{sub b}{sup -} baryons. In addition we present updated results on the narrow B**{sup 0} and B{sub c} mesons.
Date: December 1, 2007
Creator: Kreps, Michal & U., /Karlsruhe
System: The UNT Digital Library
Semi-inclusive DIS: Factorization (open access)

Semi-inclusive DIS: Factorization

In this talk, we will present a QCD factorization theorem for the semi-inclusive deep-inelastic scattering with hadrons in the current fragmentation region detected at low transverse momentum. There has been considerable experimental and theoretical interest in semi-inclusive hadron production in deep inelastic scattering (SIDIS) processes. For example, by studying the polarized and unpolarized SIDIS, one will be able to identify the sea quark distribution and polarization in nucleon, and the experimental results from the HERMES collaboration have revealed nontrivial sea structure in nucleon [1]. More recently, SIDIS opened a new window to study the transverse momentum dependent (TMD) parton distributions and fragmentation functions from the low transverse momentum hadron production. The transverse momentum distribution of the final state hadron is directly related to the transverse momentum dependence of the parton distributions and fragmentation. These studies will provide new opportunities to explore the partonic structure of nucleon, especially the three-dimension distribution of partons inside nucleon. The DIS experiments, including HERMES, COMPAS, and JLab Hall B collaborations, have studied various azimuthal asymmetries in SIDIS. In particular, the HERMES collaboration found sizable single spin asymmetries in these processes involving nontrivial QCD effects and hadron structure.
Date: December 10, 2008
Creator: Yuan, Feng
System: The UNT Digital Library
B^0_s Oscillations (open access)

B^0_s Oscillations

For a long time the B{sub s}{sup 0}-{bar B}{sub s}{sup 0} system has eluded a complete investigation of its observables. Only recently the Tevatron experiments have accumulated sizable B{sub s}{sup 0} samples, which allow a direct and precise study of the system properties. This contribution reviews the most up-to-date measurements by the CDF and D0 Collaborations of the B{sub s}{sup 0}-{bar B}{sub s}{sup 0} system parameters: the mass and decay width differences, {Delta}m{sub s} and {Delta}{Lambda}{sub s}, between the heavy and light B{sub s}{sup 0} mass eigenstates, the average decay width {Lambda}{sub s}, and the CP-violating phase in the mixing {phi}{sub s}.
Date: December 1, 2007
Creator: Casarsa, Massimo
System: The UNT Digital Library
Beryllium Use in the Advanced Test Reactor (open access)

Beryllium Use in the Advanced Test Reactor

The Advanced Test Reactor (ATR) at the Idaho National Laboratory (INL) began operation in 1967. It makes use of a unique serpentine fuel core design and a beryllium reflector. Reactor control is achieved with rotating beryllium cylinders to which have been fastened plates of hafnium. Over time, the beryllium develops rather high helium content because of nuclear transmutations and begins to swell. The beryllium must be replaced at nominally 10-year intervals. Determination of when the replacement is made is by visual observation using a periscope to examine the beryllium surface for cracking and swelling. Disposition of the irradiated beryllium was once accomplished in the INL’s Radioactive Waste Management Complex, but that is no longer possible. Among contributing reasons are high levels of specific radioactive contaminants including transuranics. The INL is presently considering disposition pathways for this irradiated beryllium, but presently is storing it in the canal adjacent to the reactor. Numerous issues are associated with this situation including (1) Is there a need for ultra-low uranium material? (2) Is there a need to recover tritium from irradiated beryllium either because this is a strategic material resource or in preparation for disposal? (3) Is there a need to remove activation and …
Date: December 1, 2007
Creator: Longhurst, Glen R.
System: The UNT Digital Library
Terminator Detection by Support Vector Machine Utilizing aStochastic Context-Free Grammar (open access)

Terminator Detection by Support Vector Machine Utilizing aStochastic Context-Free Grammar

A 2-stage detector was designed to find rho-independent transcription terminators in the Escherichia coli genome. The detector includes a Stochastic Context Free Grammar (SCFG) component and a Support Vector Machine (SVM) component. To find terminators, the SCFG searches the intergenic regions of nucleotide sequence for local matches to a terminator grammar that was designed and trained utilizing examples of known terminators. The grammar selects sequences that are the best candidates for terminators and assigns them a prefix, stem-loop, suffix structure using the Cocke-Younger-Kasaami (CYK) algorithm, modified to incorporate energy affects of base pairing. The parameters from this inferred structure are passed to the SVM classifier, which distinguishes terminators from non-terminators that score high according to the terminator grammar. The SVM was trained with negative examples drawn from intergenic sequences that include both featureless and RNA gene regions (which were assigned prefix, stem-loop, suffix structure by the SCFG), so that it successfully distinguishes terminators from either of these. The classifier was found to be 96.4% successful during testing.
Date: December 30, 2006
Creator: Francis-Lyon, Patricia; Cristianini, Nello & Holbrook, Stephen
System: The UNT Digital Library
SAVANNAH RIVER SITE CAPABILITIES FOR CONDUCTING INGESTION PATHWAY CONSEQUENCE ASSESSMENTS FOR EMERGENCY RESPONSE (open access)

SAVANNAH RIVER SITE CAPABILITIES FOR CONDUCTING INGESTION PATHWAY CONSEQUENCE ASSESSMENTS FOR EMERGENCY RESPONSE

Potential airborne releases of radioactivity from facilities operated for the U. S. Department of Energy at the Savannah River Site could pose significant consequences to the public through the ingestion pathway. The Savannah River National Laboratory has developed a suite of technologies needed to conduct assessments of ingestion dose during emergency response, enabling emergency manager at SRS to develop initial protective action recommendation for state agencies early in the response and to make informed decisions on activation of additional Federal assets that would be needed to support long-term monitoring and assessment activities.
Date: December 11, 2007
Creator: Hunter, C
System: The UNT Digital Library
4-D XRD for strain in many grains using triangulation (open access)

4-D XRD for strain in many grains using triangulation

Determination of the strains in a polycrystalline materialusing 4-D XRD reveals sub-grain and grain-to-grain behavior as a functionof stress. Here 4-D XRD involves an experimental procedure usingpolychromatic micro-beam X-radiation (micro-Laue) to characterizepolycrystalline materials in spatial location as well as with increasingstress. The in-situ tensile loading experiment measured strain in a modelaluminum-sapphire metal matrix composite using the Advanced Light Source,Beam-line 7.3.3. Micro-Laue resolves individual grains in thepolycrystalline matrix. Results obtained from a list of grains sorted bycrystallographic orientation depict the strain states within and amongindividual grains. Locating the grain positions in the planeperpendicular to the incident beam is trivial. However, determining theexact location of grains within a 3-D space is challenging. Determiningthe depth of the grains within the matrix (along the beam direction)involved a triangulation method tracing individual rays that producespots on the CCD back to the point of origin. Triangulation wasexperimentally implemented by simulating a 3-D detector capturingmultiple diffraction images while increasing the camera to sampledistance. Hence by observing the intersection of rays from multiple spotsbelonging to the corresponding grain, depth is calculated. Depthresolution is a function of the number of images collected, grain to beamsize ratio, and the pixel resolution of the CCD. The 4DXRD methodprovides grain morphologies, strain …
Date: December 31, 2006
Creator: Bale, Hrishikesh A.; Hanan, Jay C. & Tamura, Nobumichi
System: The UNT Digital Library
Field driven ferromagnetic phase nucleation and propagation from the domain boundaries in antiferromagnetically coupled perpendicular anisotropy films (open access)

Field driven ferromagnetic phase nucleation and propagation from the domain boundaries in antiferromagnetically coupled perpendicular anisotropy films

We investigate the reversal process in antiferromagnetically coupled [Co/Pt]{sub X-1}/{l_brace}Co/Ru/[Co/Pt]{sub X-1}{r_brace}{sub 16} multilayer films by combining magnetometry and Magnetic soft X-ray Transmission Microscopy (MXTM). After out-of-plane demagnetization, a stable one dimensional ferromagnetic (FM) stripe domain phase (tiger-tail phase) for a thick stack sample (X=7 is obtained), while metastable sharp antiferromagnetic (AF) domain walls are observed in the remanent state for a thinner stack sample (X=6). When applying an external magnetic field the sharp domain walls of the thinner stack sample transform at a certain threshold field into the FM stripe domain wall phase. We present magnetic energy calculations that reveal the underlying energetics driving the overall reversal mechanisms.
Date: December 9, 2008
Creator: Hauet, Thomas; Gunther, Christian M.; Hovorka, Ondrej; Berger, Andreas; Im, Mi-Young; Fischer, Peter et al.
System: The UNT Digital Library
Research Experience with a Plug-In Hybrid Electric Vehicle: Preprint (open access)

Research Experience with a Plug-In Hybrid Electric Vehicle: Preprint

This technical document reports on the exploratory research conducted by NREL on PHEV technology using a Toyota Prius that has been converted to a plug-in hybrid electric vehicle. The data includes both controlled dynamometer and on-road test results, particularly for hilly driving. The results highlight the petroleum savings and benefits of PHEV technology.
Date: December 1, 2007
Creator: Markel, T.; Pesaran, A.; Kelly, K.; Thornton, M. & Nortman, P.
System: The UNT Digital Library
ALUMINUM HYDRIDE: A REVERSIBLE MATERIAL FOR HYDROGEN STORAGE (open access)

ALUMINUM HYDRIDE: A REVERSIBLE MATERIAL FOR HYDROGEN STORAGE

Hydrogen storage is one of the greatest challenges for implementing the ever sought hydrogen economy. Here we report a novel cycle to reversibly form high density hydrogen storage materials such as aluminium hydride. Aluminium hydride (AlH{sub 3}, alane) has a hydrogen storage capacity of 10.1 wt% H{sub 2}, 149 kg H{sub 2}/m{sup 3} volumetric density and can be discharged at low temperatures (< 100 C). However, alane has been precluded from use in hydrogen storage systems because of the lack of practical regeneration methods; the direct hydrogenation of aluminium to form AlH{sub 3} requires over 10{sup 5} bars of hydrogen pressure at room temperature and there are no cost effective synthetic means. Here we show an unprecedented reversible cycle to form alane electrochemically, using alkali alanates (e.g. NaAlH{sub 4}, LiAlH{sub 4}) in aprotic solvents. To complete the cycle, the starting alanates can be regenerated by direct hydrogenation of the dehydrided alane and the alkali hydride being the other compound formed in the electrochemical cell. The process of forming NaAlH{sub 4} from NaH and Al is well established in both solid state and solution reactions. The use of adducting Lewis bases is an essential part of this cycle, in the isolation …
Date: December 31, 2008
Creator: Fewox, C; Ragaiy Zidan, R & Brenda Garcia-Diaz, B
System: The UNT Digital Library
Erratum: High power impulse magnetron sputtering:Current-voltage-time characteristics indicate the onset of sustainedself-sputtering (open access)

Erratum: High power impulse magnetron sputtering:Current-voltage-time characteristics indicate the onset of sustainedself-sputtering

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Date: December 14, 2007
Creator: Anders, Andre; Andersson, Joakim & Ehiasarian, Arutiun
System: The UNT Digital Library