Isolated ion pairs of a conventional ionic liquid, 1-Ethyl-3-Methyl-Imidazolium Bis(trifluoromethylsulfonyl)imide ([Emim+][Tf2N?]), and a reactive hypergolic ionic liquid, 1-Butyl-3-Methyl-Imidazolium Dicyanamide ([Bmim+][Dca?]), are generated by vaporizing ionic liquid submicron aerosol particles for the first time; the vaporized species are investigated by dissociative ionization with tunable vacuum ultraviolet (VUV) light, exhibiting clear intact cations, Emim+ and Bmim+, presumably originating from intact ion pairs. Mass spectra of ion pair vapor from an effusive source of the hypergolic ionic liquid show substantial reactive decomposition due to the internal energy of the molecules emanating from the source. Photoionization efficiency curves in the near threshold ionization region of isolated ion pairs of [Emim+][Tf2N?]ionic liquid vapor are compared for an aerosol source and an effusive source, revealing changes in the appearance energy due to the amount of internal energy in the ion pairs. The aerosol source has a shift to higher threshold energy (~;;0.3 eV), attributed to reduced internal energy of the isolated ion pairs. The method of ionic liquid submicron aerosol particle vaporization, for reactive ionic liquids such as hypergolic species, is a convenient, thermally ?cooler? source of isolated intact ion pairs in the gas phase compared to effusive sources.

New coating technology enables the fabrication of low cost structural health monitoring (SHM) and tamper indication devices that can be employed to strengthen national and international safeguards objectives. In particular, such innovations could serve the safeguards community by improving both the timeliness of detection and confidence in verification and monitoring. This work investigates the synthesis of functional surface coatings using chemical solutions deposition methods. Chemical solution deposition has recently received attention in the materials research community due to its unique advantages such as low temperature processing, high homogeneity of final products and the ability to fabricate materials with controlled surface properties and pore structures. The synthesis of functional coatings aimed at modifying the materials conductivity and optical properties was investigated by the incorporation of transition element (e.g. Cr{sup +3}) and rare earth (e.g. Er{sup +3}) serving as dopants in a polymer or gel matrix. The structural and morphological investigation of the as-deposited films was carried out using UV/Vis and photoluminescence (PL) spectroscopy. The as deposited coating was further investigated by scanning electron microscopy and energy dispersive x-ray microscopy.

Decoupling injection from acceleration is a key challenge to achieve compact, reliable, tunable laser-plasma accelerators (LPA). In colliding pulse injection the beat between multiple laser pulses can be used to control energy, energy spread, and emittance of the electron beam by injecting electrons in momentum and phase into the accelerating phase of the wake trailing the driver laser pulse. At LBNL, using automated control of spatiotemporal overlap of laser pulses, two-pulse experiments showed stable operation and reproducibility over hours of operation. Arrival time of the colliding beam was scanned, and the measured timing window and density of optimal operation agree with simulations. The accelerator length was mapped by scanning the collision point.

This paper addresses thermal drift in sodium thiosulfate liquid resistors and their replacement with linear disk resistors from HVR Advanced Power Components. Sodium thiosulfate resistors in the FXR induction linear accelerator application have a temperature coefficient of {approx}1.8%/C. The FXR Marx banks send an 8kJ pulse through eight 524 cm{sup 3} liquid resistors at a repetition rate of up to 1 every 45 seconds. Every pulse increases the temperature of the solution by {approx}0.4 C which produces a 0.7% change in resistance. The typical cooling rate is {approx}0.4 C per minute which results in {approx}0.1% energy drop per pulse during continuous pulsed operations. A radiographic accelerator is extraordinarily sensitive to energy variations. Changes in beam energy produce movement in beam transport, changes in spot size, and large dose variations. If self-heating were the only problem, we could predict the increase in input voltage required to compensate for the energy loss. However, there are other variables that influence the temperature of the resistors such as focus magnet heating, changes in room temperature, changes in cooling water, where the cell is located, etc. Additionally not all of the resistors have equivalent cooling rates and as many as 32 resistors are driven from …

Single-shot x-ray spectra from electron bunches produced by a laser-plasma wakefield accelerator (LPA) were measured using a photon-counting single-shot pixelated Silicon-based detector [3], providing for the first time direct spectra without assumptions required by filter based techniques. In addition, the electron bunch source size was measured by imaging a wire target, demonstrating few micron source size and stability. X-rays are generated when trapped electrons oscillate in the focusing field of the wake trailing the driver laser pulse. In addition to improving understanding of bunch emittance and wake structure, this provides a broadband, synchronized femtosecond source of keV x-rays. Electron bunch spectra and divergence were measured simultaneously and preliminary analysis shows correlation between x-ray andelectron spectra. Bremsstrahlung background was managed using shielding and magnetic diversion.

Automated alignment for the National Ignition Facility (NIF) is accomplished using a large-scale parallel control system that directs 192 laser beams along the 300-m optical path. The beams are then focused down to a 50-micron spot in the middle of the target chamber. The entire process is completed in less than 50 minutes. The alignment system commands 9,000 stepping motors for highly accurate adjustment of mirrors and other optics. 41 control loops per beamline perform parallel processing services running on a LINUX cluster to analyze high-resolution images of the beams and their references. This paper describes the status the NIF automatic alignment system and the challenges encountered as NIF development has transitioned from building the laser, to becoming a research project supporting a 24 hour, 7 day laser facility. NIF is now a continuously operated system where performance monitoring is increasingly more critical for operation, maintenance, and commissioning tasks. Equipment wear and the effects of high energy neutrons from fusion experiments are issues which alter alignment efficiency and accuracy. New sensors needing automatic alignment assistance are common. System modifications to improve efficiency and accuracy are prevalent. Handling these evolving alignment and maintenance needs while minimizing the impact on NIF experiment …

Cross-calibrations of charge diagnostics are conducted to verify their validity for measuring electron beams produced by laser plasma accelerators (LPAs). Employed diagnostics are a scintillating screen, activation based measurement, and integrating current transformer. The diagnostics agreed within {+-}8 %, showing that they can provide accurate charge measurements for LPAs provided they are used properly.

This article discusses a masked two-coordinate cobalt(I) complex that activates C-F bonds.

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Article discussing the breakdown of the Onsager principle as a sign of aging.

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