Impermeable Thin Al2O3 Overlay for TBC Protection From Sulfate and Vanadate Attack in Gas Turbines Quarterly Report (open access)

Impermeable Thin Al2O3 Overlay for TBC Protection From Sulfate and Vanadate Attack in Gas Turbines Quarterly Report

To improve the hot corrosion resistance of YSZ thermal barrier coatings, a 25 {micro}m thick Al{sub 2}O{sub 3} overlay were deposited by HVOF thermal spray, respectively, onto to the surface of YSZ coating. In the next reporting period, we will measure or calculate the residue stress within Al{sub 2}O{sub 3} overlay and YSZ coating to study the mechanism of effect of Al{sub 2}O{sub 3} overlay on spalling of YSZ coating. However, due to the thermal expansion mismatch between YSZ coating and Al{sub 2}O{sub 3} overlay, such surface modification using Al{sub 2}O{sub 3} overlay might deteriorate strain tolerance of the TBC. In the present work, in order to investigate the effect of Al{sub 2}O{sub 3} overlay on residual stress developed in the samples during cooling after hot corrosion at high temperature, Finite Element method (FEM) was employed to determine the detailed stress states in the test specimens after cooling. The results showed that there is no high stress concentration at the interface between the YSZ and the bond coat for TBCs system without Al{sub 2}O{sub 3} overlay. On the other hand, the maximum compressive stress with a value of approximately, -330 MPa occurred within the Al{sub 2}O{sub 3} overlay. The maximum …
Date: March 31, 2004
Creator: Mao, Scott X.
System: The UNT Digital Library
Impermeable Thin Al2O3 Overlay for TBC Protection From Sulfate and Vanadate Attack in Gas Turbines Quarterly Report (open access)

Impermeable Thin Al2O3 Overlay for TBC Protection From Sulfate and Vanadate Attack in Gas Turbines Quarterly Report

To improve the hot corrosion resistance of YSZ thermal barrier coatings, a 25 {micro}m and a 2 {micro}m thick Al{sub 2}O{sub 3} overlay were deposited by HVOF thermal spray onto to the surface of YSZ coating. Oxidation at high temperature and hot corrosion tests showed that Al{sub 2}O{sub 3} overlay deposited on the YSZ TBCs surface can not only reduce the hot corrosion rate, but also significantly prevents the bond coat from oxidation.
Date: August 31, 2004
Creator: Mao, Scott X.
System: The UNT Digital Library