This report presents work done on a laboratory combustor in an attempt to identify mechanisms that govern the simultaneous capture of alkali and sulfur species using sorbent injection techniques. The mechanisms of capture fall into two broad categories i.e. Physical transport of alkali species (in vapor or condensed phase) to the sorbent surface and surface reaction between the alkali species and the sorbents. Water solubility, though not specific, has been used to get an indication of relative significance of these two broad mechanisms. It is assumed that the physically adsorbed alkali species on sorbents are predominantly water soluble while the chemically reacted alkali content is predominantly water insoluble. In order to infer possible dominant mechanisms, specific parameters has been varied during experimentation. Such parameters include, speciation, particle time-temperature history, and furnace burning conditions.

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Photograph of a newspaper clipping with a photograph taken by Carolyn Bauman from the Fort Worth Star Telegram April 23, 1992 of Moscow police officer Oleg Orjekhouski. The caption beneath the picture says "Moscow police officer Oleg Orjekhouski looks at one of the displays at the Arlington Police Museum." The display is of a mannequin wearing a motorcycle police uniform. A United States Flag is in the background. Officer Orjekhouski is wearing his uniform.

This report presents work done on a laboratory combustor in an attempt to identify mechanisms that govern the simultaneous capture of alkali and sulfur species using sorbent injection techniques. The mechanisms of capture fall into two broad categories i.e. Physical transport of alkali species (in vapor or condensed phase) to the sorbent surface and surface reaction between the alkali species and the sorbents. Water solubility, though not specific, has been used to get an indication of relative significance of these two broad mechanisms. It is assumed that the physically adsorbed alkali species on sorbents are predominantly water soluble while the chemically reacted alkali content is predominantly water insoluble. In order to infer possible dominant mechanisms, specific parameters has been varied during experimentation. Such parameters include, speciation, particle time-temperature history, and furnace burning conditions.

This project revolves around understanding the fundamental processes involved in the catalytic removal of harmful oxygenated organics present in coal liquids. We are modelling the complex type of sulfided Mo catalyst proposed for these reactions with simple single crystal surfaces. These display a controlled range and number of reaction sites and can be extensively characterized by surface science techniques. We then investigate the reaction pathways for representative simple oxygenates upon these surfaces. We have made considerable progress in characterizing the adsorption site of sulfur on the Mo(110) surface. The sulfur is probably located in the quasi-fourfold center hollow site on the surface at a vertical distance of about 1.5{Angstrom} above the topmost metal layer. At present the calculations assume no reconstruction of the metal layer and this tentative finding may change when we allow the metal to reconstruct. We have also progressed in our understanding of the reactions of furan on these surfaces. The data is therefore consistent with propane adsorption being hindered relative to either ethylene or furan, but the release of hydrogen from adsorbed furan is a higher energy process than the equivalent process for a simple hydrocarbon. The effect of preadsorbed S on furan and hydrocarbon adsorption …

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Contributions were made towards the ultimate goal of creating a complete theory of edge turbulence and transport in magnetic fusion devices. The main focus has been to utilize a resistive MHD model. This analysis includes: (1) rippling'' type models in which the current fluctuations are decoupled and the resistivity fluctuations are fundamental, and (2) drift'' type models in which the ambient current can be small (no resistivity fluctuations needed) and the current fluctuations are fundamental. In these turbulence frameworks, the important atomic physics based edge sources have been included (impurity radiation, ionization, and charge exchange effects).

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Contributions were made towards the ultimate goal of creating a complete theory of edge turbulence and transport in magnetic fusion devices. The main focus has been to utilize a resistive MHD model. This analysis includes: (1) ``rippling`` type models in which the current fluctuations are decoupled and the resistivity fluctuations are fundamental, and (2) ``drift`` type models in which the ambient current can be small (no resistivity fluctuations needed) and the current fluctuations are fundamental. In these turbulence frameworks, the important atomic physics based edge sources have been included (impurity radiation, ionization, and charge exchange effects).