Possible explosive compounds in the Savannah River Site waste tank farm facilities (open access)

Possible explosive compounds in the Savannah River Site waste tank farm facilities

Based on a comparison of the known constituents in high-level nuclear waste stored at the Savannah River Site (SRS) and explosive compounds reported in the literature, only two classes of explosive compounds (metal NO{sub x} compounds and organic compounds) were identified as requiring further work to determine if they exist in the waste, and if so, in what quantities. Of the fourteen classes of explosive compounds identified as conceivably being present in tank farm operations, nine classes (metal fulminates, metal azides, halogen compounds, metal-amine complexes, nitrate/oxalate mixtures, metal oxalates, metal oxohalogenates, metal cyanides/cyanates, and peroxides) are not a hazard because these classes of compounds cannot be formed or accumulated in sufficient quantity, or they are not reactive at the conditions which exist in the tank farm facilities. Three of the classes (flammable gases, metal nitrides, and ammonia compounds and derivatives) are known to have the potential to build up to concentrations at which an observable reaction might occur. Controls have been in place for some time to limit the formation or control the concentration of these classes of compounds. A comprehensive list of conceivable explosive compounds is provided in Appendix 3.
Date: March 15, 1992
Creator: Hobbs, D. T.
System: The UNT Digital Library
Possible explosive compounds in the Savannah River Site waste tank farm facilities (open access)

Possible explosive compounds in the Savannah River Site waste tank farm facilities

Based on a comparison of the known constituents in high-level nuclear waste stored at the Savannah River Site (SRS) and explosive compounds reported in the literature, only two classes of explosive compounds (metal NO{sub x} compounds and organic compounds) were identified as requiring further work to determine if they exist in the waste, and if so, in what quantities. Of the fourteen classes of explosive compounds identified as conceivably being present in tank farm operations, nine classes (metal fulminates, metal azides, halogen compounds, metal-amine complexes, nitrate/oxalate mixtures, metal oxalates, metal oxohalogenates, metal cyanides/cyanates, and peroxides) are not a hazard because these classes of compounds cannot be formed or accumulated in sufficient quantity, or they are not reactive at the conditions which exist in the tank farm facilities. Three of the classes (flammable gases, metal nitrides, and ammonia compounds and derivatives) are known to have the potential to build up to concentrations at which an observable reaction might occur. Controls have been in place for some time to limit the formation or control the concentration of these classes of compounds. A comprehensive list of conceivable explosive compounds is provided in Appendix 3.
Date: March 15, 1992
Creator: Hobbs, D. T.
System: The UNT Digital Library
Resource Conservation and Recovery Act. Environmental guidance program reference book: Revision 11 (open access)

Resource Conservation and Recovery Act. Environmental guidance program reference book: Revision 11

This document describes the Resource Conservation and Recovery Act and implementing regulations.
Date: March 15, 1992
Creator: unknown
System: The UNT Digital Library