The production of jets in association with a Z/{gamma}* boson is an example of an important class of processes at hadron colliders, namely vector boson + jet (V + jet) production. Comparisons of measurements of this class of processes with theory predictions constitute an important, fundamental test of the Standard Model of particle physics, and of the theory of QCD in particular. While having a smaller cross section than other V +jet processes, Z/{gamma}*({yields} e{sup +}e{sup -}) + jets production, with Z/{gamma}* {yields} e{sup +}e{sup -}/{mu}{sup +}{mu}{sup -}, has a distinct experimental signature allowing for measurements characterized by low backgrounds and a direct, precise measurement of the properties of the decay products of the Z/{gamma}* boson. In this thesis, several new measurements of the properties of jets produced in association with a Z/{gamma}* boson in p{bar p} collisions at {radical}s = 1.96 TeV are presented. The cross section for Z/{gamma}*({yields} e{sup +}e{sup -}) + N jet production (N {le} 3) is measured, differential in the transverse momentum of the Nth jet in the event, normalized to the inclusive Z/{gamma}* cross section. Also, the cross section for Z/{gamma}*({yields} e{sup +}e{sup -}) + N jets (N {ge} 1) is measured, differential in …

I describe a search for anomalous production of Z pairs through a new massive resonance X in 2.5-2.9 fb{sup -1} of p{bar p} collisions at {radical}s = 1.96 TeV using the CDFII Detector at the Fermilab Tevatron. I reconstruct Z pairs through their decays to electrons, muons, and quarks. To achieve perhaps the most efficient lepton reconstruction ever used at CDF, I apply a thorough understanding of the detector and new reconstruction software heavily revised for this purpose. In particular, I have designed and employ new general-purpose algorithms for tracking at large {eta} in order to increase muon acceptance. Upon analyzing the unblinded signal samples, I observe no X {yields} ZZ candidates and set upper limits on the production cross section using a Kaluza-Klein graviton-like acceptance.

The present work in this dissertation mainly focuses on the clean fivefold surfaces of i-Al-Pd-Mn quasicrystals as well as the nucleation and growth of Ag films on these surfaces. In addition, Ag film growth on NiAl(110) has been explored in the frame of this dissertation. First, we have investigated the equilibration of a fivefold surface of icosahedral Al-Pd-Mn quasicrystal at 900-915 K and 925-950 K, using Omicron variable temperature scanning tunneling microscope (STM). Annealing at low temperatures resulted in many voids on some terraces while the others were almost void-free. After annealing at 925-950K, void-rich terraces became much rarer. Our STM images suggest that through growth and coalescence of the voids, a different termination becomes exposed on host terraces. All of these observations in our study indicate that even after the quasicrystalline terrace-step structure appears, it evolves with time and temperature. More specifically, based on the STM observations, we conclude that during the annealing a wide range of energetically similar layers nucleate as surface terminations, however, with increasing temperature (and time) this distribution gets narrower via elimination of the metastable void-rich terraces. Next, we have examined the bulk structural models of icosahedral Al-Pd-Mn quasicrystal in terms of the densities, compositions …

The top quark is by far the heaviest known fundamental particle with a mass nearing that of a gold atom. Because of this strikingly high mass, the top quark has several unique properties and might play an important role in electroweak symmetry breaking - the mechanism that gives all elementary particles mass. Creating top quarks requires access to very high energy collisions, and at present only the Tevatron collider at Fermilab is capable of reaching these energies. Until now, top quarks have only been observed produced in pairs via the strong interaction. At hadron colliders, it should also be possible to produce single top quarks via the electroweak interaction. Studies of single top quark production provide opportunities to measure the top quark spin, how top quarks mix with other quarks, and to look for new physics beyond the standard model. Because of these interesting properties, scientists have been looking for single top quarks for more than 15 years. This thesis presents the first discovery of single top quark production. An analysis is performed using 2.3 fb{sup -1} of data recorded by the D0 detector at the Fermilab Tevatron Collider at centre-of-mass energy {radical}s = 1.96 TeV. Boosted decision trees are …

Excited state charge transfer processes are studied using the fs/ps-CARS probe technique. This probe allows for multiplexed detection of Raman active vibrational modes. Systems studied include Michler's Ketone, Coumarin 120, 4-dimethylamino-4{prime}-nitrostilbene, and several others. The vibrational spectrum of the para di-substituted benzophenone Michler's Ketone in the first excited singlet state is studied for the first time. It is found that there are several vibrational modes indicative of structural changes of the excited molecule. A combined experimental and theoretical approach is used to study the simplest 7-amino-4-methylcoumarin, Coumarin 120. Vibrations observed in FTIR and spontaneous Raman spectra are assigned using density functional calculations and a continuum solvation model is used to predict how observed modes are affected upon inclusion of a solvent. The low frequency modes of the excited state charge transfer species 4-dimethylamino-4{prime}-nitrostilbene are studied in acetonitrile. Results are compared to previous work on this molecule in the fingerprint region. Finally, several partially completed projects and their implications are discussed. These include the two photon absorption of Coumarin 120, nanoconfinement in cyclodextrin cavities and sensitization of titania nanoparticles.

We have used the Collider Detector at Fermilab (CDF-II) to set upper limits on the branching ratio of the flavor-changing neutral-current (FCNC) top quark decay t {yields} Zc using a technique employing ratios of W and Z production, measured in 1.52 fb{sup -1} of p{bar p} data. The analysis uses a comparison of two decay chains, p{bar p} {yields} t{bar t} {yields} WbWb {yields} {ell}{nu}bjjb and p{bar p} {yields} t{bar t} ZcWb {yields} {ell}{sup +}{ell}{sup -} cjjb, to cancel systematic uncertainties in acceptance, efficiency, and luminosity. We validate the MC modeling of acceptance and efficiency for lepton identification over the multi-year dataset also using a ratio of W and Z production, in this case the observed ratio of inclusive production of W to Z-bosons, a technique that will be essential for precision comparisons with the standard model at the LHC. We introduce several methods of determining backgrounds to the W and Z samples. To improve the discrimination against SM backgrounds to top quark decays, we calculate the top mass for each event with two leptons and four jets assuming it is a t{bar t} event with one of the top quarks decaying to Zc. The upper limit on the Br(t …

The analysis presented in this thesis focuses on kinematic distributions in the t{bar t} system and studies in detail selected differential cross sections of top quarks as well as the reconstructed t{bar t} pair, namely the top quark transverse momentum and the t{bar t} system mass. The structure of the thesis is organized as follows: first the Standard Model of the particle physics is briefly introduced in Chapter 1, with relevant aspects of electroweak and strong interactions discussed. The physics of the top quark and its properties are then outlined in Chapter 2, together with the motivation for measuring the transverse top quark momentum and other kinematic-related variables of the t{bar t} system. The concepts of present-day high energy physics collider experiments and the explicit example of Fermilab Tevatron collider and the D0 detector in Chapters 3 and 4 are followed by the description of basic detector-level objects, i.e. tracks, leptons and jets, in Chapter 5; their identification and calibration following in next chapter with the emphasis on the jet energy scale in Chapter 6 and jet identification at the D0. The analysis itself is outlined in Chapter 7 and is structured so that first the data and simulation samples …

We perform cosmological N-body simulations of the Dvali-Gabadadze-Porrati braneworld model, by solving the full non-linear equations of motion for the scalar degree of freedom in this model, the brane bending mode. While coupling universally to matter, the brane-bending mode has self-interactions that become important as soon as the density field becomes non-linear. These self-interactions lead to a suppression of the field in high-density environments, and restore gravity to General Relativity. The code uses a multi-grid relaxation scheme to solve the non-linear field equation in the quasi-static approximation. We perform simulations of a flat self-accelerating DGP model without cosmological constant. However, the type of non-linear interactions of the brane-bending mode, which are the focus of this study, are generic to a wide class of braneworld cosmologies. The results of the DGP simulations are compared with standard gravity simulations assuming the same expansion history, and with DGP simulations using the linearized equation for the brane bending mode. This allows us to isolate the effects of the non-linear self-couplings of the field which are noticeable already on quasi-linear scales. We present results on the matter power spectrum and the halo mass function, and discuss the behavior of the brane bending mode within cosmological …

In this thesis, results of neutrino-nucleon neutral current (NC) elastic scattering analysis are presented. Neutrinos interact with other particles only with weak force. Measurement of cross-section for neutrino-nucleon reactions at various neutrino energy are important for the study of nucleon structure. It also provides data to be used for beam flux monitor in neutrino oscillation experiments. The cross-section for neutrino-nucleon NC elastic scattering contains the axial vector form factor G{sub A}(Q{sup 2}) as well as electromagnetic form factors unlike electromagnetic interaction. G{sub A} is propotional to strange part of nucleon spin ({Delta}s) in Q{sup 2} {yields} 0 limit. Measurement of NC elastic cross-section with smaller Q{sup 2} enables us to access {Delta}s. NC elastic cross-sections of neutrino-nucleon and antineutrino-nucleon were measured earlier by E734 experiment at Brookheaven National Laboratory (BNL) in 1987. In this experiment, cross-sections were measured in Q{sup 2} > 0.4 GeV{sup 2} region. Result from this experiment was the only published data for NC elastic scattering cross-section published before our experiment. SciBooNE is an experiment for the measurement of neutrino-nucleon scattering cross-secitons using Booster Neutrino Beam (BNB) at FNAL. BNB has energy peak at 0.7 GeV. In this energy region, NC elastic scattering, charged current elastic scattering, …

A strong case has been made by several experiments that neutrinos oscillate, although important questions remain as to the mechanisms and precise values of the parameters. In the standard picture, two parameters describe the nature of how the neutrinos oscillate: the mass-squared difference between states and the mixing angle. The purpose of this thesis is to use data from the MINOS experiment to precisely measure the parameters associated with oscillations first observed in studies of atmospheric neutrinos. MINOS utilizes two similar detectors to observe the oscillatory nature of neutrinos. The Near Detector, located 1 km from the source, observes the unoscillated energy spectrum while the Far Detector, located 735 km away, is positioned to see the oscillation signal. Using the data in the Near Detector, a prediction of the expected neutrino spectrum at the Far Detector assuming no oscillations is made. By comparing this prediction with the MINOS data, the atmospheric mixing parameters are measured to be {Delta}m{sub 32}{sup 2} = 2.45{sub +0.12}{sup -0.12} x 10{sub -3} eV{sup 2} and sin{sup 2}(2{theta}{sub 32}) = 1.00{sub -0.04}{sup +0.00} (> 0.90 at 90% confidence level).

Top quarks are predominantly produced in pairs via the strong interaction in {bar p}p collisions at {radical}s = 1.96 TeV . The top quark has a weak isospin 1/2, composing a weak isospin doublet with the bottom quark. This characteristic predicts not only top quark pair production via strong interaction but also single production together with a bottom quark via weak interaction. However, finding single top quark production is challenging since it is rarely produced ({sigma}{sub singletop} = 2.9 pb) against background processes with the same final state like W+jets and t{bar t}. A measurement of electroweak single top production probes the W-t-b vertex, which provides a direct determination of the Cabbibo-Kobayashi-Maskawa (CKM) matrix element |V{sub tb}|. The sample offers a source of almost 100% polarized top quarks. This thesis describes an optimized search for s-channel single top quark production and a measurement of the single top production cross section using 2.7 fb{sup -1} of data accumulated with the CDF detector. We are using events with one high-p{sub T} lepton, large missing E{sub T} and two identified b-quark jets where one jet is identified using a secondary vertex tagger, called SecVtx, and the other jet is identified using SecVtx or …

At particle accelerators the Standard Model has been tested and will be tested further to a great precision. The data analyzed in this thesis have been collected at the world's highest energetic-collider, the Tevatron, located at the Fermi National Accelerator Laboratory (FNAL) in the vicinity of Chicago, IL, USA. There, protons and antiprotons are collided at a center-of-mass energy of {radical}s = 1.96 TeV. The discovery of the top quark was one of the remarkable results not only for the CDF and D0 experiments at the Tevatron collider, but also for the Standard Model, which had predicted the existence of the top quark because of symmetry arguments long before already. Still, the Tevatron is the only facility able to produce top quarks. The predominant production mechanism of top quarks is the production of a top-antitop quark pair via the strong force. However, the Standard Model also allows the production of single top quarks via the electroweak interaction. This process features the unique opportunity to measure the |V{sub tb}| matrix element of the Cabbibo-Kobayashi-Maskawa (CKM) matrix directly, without assuming unitarity of the matrix or assuming that the number of quark generations is three. Hence, the measurement of the cross section of …

This thesis describes a search for standard model Higgs bosons decaying to W boson pairs in proton-anti-proton collisions at a center of mass energy of 1.96 TeV using the CDF II detector. The decay to W bosons is dominant for Higgs masses greater than about 135 GeV. The final state examined consists of two leptons and missing transverse energy from the leptonic decay of one or more W bosons. The signal production mechanisms included are gluon fusion, associated production with a W or Z boson, and vector boson fusion. Matrix element calculations and artificial neural networks are used to discriminate signal from background for Higgs masses in the range 110 {le} M{sub H} {le} 200 GeV. No significant excess of events is observed at any of the Higgs masses investigated. Upper limits on the standard model Higgs cross section are set at 95% confidence for each Higgs mass investigated, the most stringent limit being 1.63 times the predicted standard model cross section for a Higgs mass of 160 GeV.

Ozone, an ambient pollutant, is transformed into other airborne pollutants in the indoor environment. In this dissertation, the type and amount of byproducts that result from ozone reactions with common indoor surfaces, surface residues, and vapors were determined, pollutant concentrations were related to occupant exposure, and frameworks were developed to predict byproduct concentrations under various indoor conditions. In Chapter 2, an analysis is presented of secondary organic aerosol formation from the reaction of ozone with gas-phase, terpene-containing consumer products in small chamber experiments under conditions relevant for residential and commercial buildings. The full particle size distribution was continuously monitored, and ultrafine and fine particle concentrations were in the range of 10 to>300 mu g m-3. Particle nucleation and growth dynamics were characterized.Chapter 3 presents an investigation of ozone reactions with aircraft cabin surfaces including carpet, seat fabric, plastics, and laundered and worn clothing fabric. Small chamber experiments were used to determine ozone deposition velocities, ozone reaction probabilities, byproduct emission rates, and byproduct yields for each surface category. The most commonly detected byproducts included C1?C10 saturated aldehydes and skin oil oxidation products. For all materials, emission rates were higher with ozone than without. Experimental results were used to predict byproduct exposure …

This dissertation presents a new measurement of p{bar p} {yields} t{bar t}X production at {radical}s = 1.96 TeV using 974.2 pb{sup -1} of data collected with the D0 detector between 2002 and 2006. We focus on the final state where the W boson from one of the top quarks decays into a {tau} lepton and its associated neutrino, while the other W boson decays into a quark-antiquark pair. We aim to select those events in which the {tau} lepton subsequently decays hadronically, meaning to one or three charged hadrons, zero or more neutral hadrons and a tau neutrino (the charge conjugate processes are implied in all of the above). The observable signature thus consists of a narrow calorimeter shower with associated track(s) characteristic of a hadronic tau decay, four or more jets, of which two are initiated by b quarks accompanying the W's in the top quark decays, and a large net missing momentum in the transverse plane due to the energetic neutrino-antineutrino pair that leave no trace in the detector media. The preliminary result for the measured cross section is: {sigma}(t{bar t}) = 6.9{sub -1.2}{sup +1.2}(stat){sub -0.7}{sup +0.8}(syst) {+-} 0.4 (lumi) pb. This indicates that our finding is consistent …

This thesis studies important dynamical observables of strong interactions such as form factors. It is known that Quantum Chromodynamics (QCD) is a theory which describes strong interactions. For large energies, one can apply perturbative techniques to solve some of the QCD problems. However, for low energies QCD enters into the nonperturbative regime, where different analytical or numerical tools have to be applied to solve problems of strong interactions. The holographic dual model of QCD is such an analytical tool that allows one to solve some nonperturbative QCD problems by translating them into a dual five-dimensional theory defined on some warped Anti de Sitter (AdS) background. Working within the framework of the holographic dual model of QCD, we develop a formalism to calculate form factors and wave functions of vector mesons and pions. As a result, we provide predictions of the electric radius, the magnetic and quadrupole moments which can be directly verified in lattice ca

Over the fifty-five year history of Nuclear Magnetic Resonance (NMR), considerable progress has been made in the development of techniques for studying the structure, function, and dynamics of biological molecules. The majority of this research has involved the development of multi-dimensional NMR experiments for studying molecules in solution, although in recent years a number of groups have begun to explore NMR methods for studying biological systems in the solid-state. Despite this new effort, a need still exists for the development of techniques that improve sensitivity, maximize information, and take advantage of all the NMR interactions available in biological molecules. In this dissertation, a variety of novel NMR techniques for studying biomolecules are discussed. A method for determining backbone ({phi}/{psi}) dihedral angles by comparing experimentally determined {sup 13}C{sub a}, chemical-shift anisotropies with theoretical calculations is presented, along with a brief description of the theory behind chemical-shift computation in proteins and peptides. The utility of the Spin-Polarization Induced Nuclear Overhauser Effect (SPINOE) to selectively enhance NMR signals in solution is examined in a variety of systems, as are methods for extracting structural information from cross-relaxation rates that can be measured in SPINOE experiments. Techniques for the production of supercritical and liquid laser-polarized …

This dissertation presents a search for {mu}{sub {nu}} and {bar {mu}{sub {nu}}} disappearance with the MiniBooNE experiment in the {Delta}m{sup 2} region of a few eV{sup 2}. Disappearance measurements in this oscillation region constrain sterile neutrino models and CPT violation in the lepton sector. Fits to the shape of the {mu}{sub {nu}} and {bar {mu}{sub {nu}}} energy spectra reveal no evidence for disappearance in either mode. This is the first test of {bar {mu}{sub {nu}}} disappearance between {Delta}m{sup 2} = 0:1 -- 10 eV2. In addition, prospects for performing a joint analysis using the SciBooNE detector in conjunction with MiniBooNE are discussed.

This research is divided into two related topics. In the first topic, the synthesis and characterization of novel composite materials reinforced with MWCNTs by ring-opening metathesis polymerization (ROMP) is reported for two ROMP based monomers: dicyclopentadiene (DCPD) and 5-ethylidene-2-norbornene (ENB). Homogeneous dispersion of MWCNTs in the polymer matrices is achieved by grafting norbornene moieties onto the nanotube surface. For the DCPD-based system, the investigation of mechanical properties of the composites shows a remarkable increase of tensile toughness with just 0.4 wt % of functionalized MWCNTs (f-MWCNTs). To our knowledge, this represents the highest toughness enhancement efficiency in thermosetting composites ever reported. DMA results show that there is a general increase of thermal stability (rg) with the addition of f-MWCNTs, which means that covalently bonded f-MWCNTs can reduce the local chain mobility of the matrix by interfacial interactions. The ENB system also shows significant enhancement of the toughness using just 0.8 wt % f-MWCNTs. These results indicate that the ROMP approach for polyENB is also very effective. The second topic is an investigation of the biorenewable rubbers synthesized by the tandem ROMP and cationic polymerization. The resin consists of a norbornenyl-modified linseed oil and a norbornene diester. Characterization of the bio-based …

We measure the production cross section of t{bar t} events in p{bar p} collisions at {radical}s = 1.96 TeV. The data was collected by the CDF experiment in Run 2 of the Tevatron accelerator at the Fermi National Accelerator Laboratory between 2002 and 2007. 1.7 fb{sup -1} of data was recorded during this time period. We reconstruct t{bar t} events in the lepton+jets channel, whereby one W boson - resulting from the decay of the top quark pairs - decays leptonically and the other hadronically. The dominant background to this process is the production of W bosons in association with multiple jets. To distinguish t{bar t} from background, we identify soft electrons from the semileptonic decay of heavy flavor jets produced in t{bar t} events. We measure a cross section of {sigma}{sub p{bar p}} = 7.8 {+-} 2.4(stat) {+-} 1.6(syst) {+-} 0.5(lumi).

The existence of the Higgs boson is required by the Standard Model of particle physics, yet it has not been observed. The precise nature of the Higgs boson is unknown and the mechanism by which it interacts with known Standard Model particles is also not known. Long-lived, electrically neutral hadrons have recently been proposed in hidden-valley models and could constitute a pathway through which the Higgs boson communicates with the Standard Model. Such a scenario may provide a novel path to Higgs discovery at the Tevatron. This thesis describes a search for a neutral, long-lived particle produced in decays of Higgs bosons in p{bar p} collisions at a center-of-mass energy of {radical}s = 1.96 TeV, which decays to b-jets and lives long enough to travel at least 1.6 cm before decaying. This analysis uses 3.65 fb{sup -1} of data recorded with the Run II D0 detector at the Fermilab Tevatron collider from April 2002 to August of 2008. We perform a search for eight possible hidden-valley scenarios resulting from a Higgs decay. No significant excess over background is observed and cross-section limits are placed at 95% CL.

Three major high performance quantum chemistry computational packages, NWChem, GAMESS and MPQC have been developed by different research efforts following different design patterns. The goal is to achieve interoperability among these packages by overcoming the challenges caused by the different communication patterns and software design of each of these packages. A chemistry algorithm is hard to develop as well as being a time consuming process; integration of large quantum chemistry packages will allow resource sharing and thus avoid reinvention of the wheel. Creating connections between these incompatible packages is the major motivation of the proposed work. This interoperability is achieved by bringing the benefits of Component Based Software Engineering through a plug-and-play component framework called Common Component Architecture (CCA). In this thesis, I present a strategy and process used for interfacing two widely used and important computational chemistry methodologies: Quantum Mechanics and Molecular Mechanics. To show the feasibility of the proposed approach the Tuning and Analysis Utility (TAU) has been coupled with NWChem code and its CCA components. Results show that the overhead is negligible when compared to the ease and potential of organizing and coping with large-scale software applications.

The top quark is the heaviest known matter particle and plays an important role in the Standard Model of particle physics. At hadron colliders, it is possible to produce single top quarks via the weak interaction. This allows a direct measurement of the CKM matrix element V{sub tb} and serves as a window to new physics. The first direct measurement of single top quark production with a tau lepton in the final state (the tau+jets channel) is presented in this thesis. The measurement uses 4.8 fb{sup -1} of Tevatron Run II data in p{bar p} collisions at {radical}s = 1.96 TeV acquired by the D0 experiment. After selecting a data sample and building a background model, the data and background model are in good agreement. A multivariate technique, boosted decision trees, is employed in discriminating the small single top quark signal from a large background. The expected sensitivity of the tau+jets channel in the Standard Model is 1.8 standard deviations. Using a Bayesian statistical approach, an upper limit on the cross section of single top quark production in the tau+jets channel is measured as 7.3 pb at 95% confidence level, and the cross section is measured as 3.4{sub -1.8}{sup +2.0} …

This thesis presents the analysis of the double differential dijet mass cross section, measured at the D0 detector in Batavia, IL, using p{bar p} collisions at a center of mass energy of {radical}s = 1.96 TeV. The dijet mass was calculated using the two highest p{sub T} jets in the event, with approximately 0.7 fb{sup -1} of data collected between 2004 and 2005. The analysis was presented in bins of dijet mass (M{sub JJ}) and rapidity (y), and extends the measurement farther in M{sub JJ} and y than any previous measurement. Corrections due to detector effects were calculated using a Monte Carlo simulation and applied to data. The errors on the measurement consist of statistical and systematic errors, of which the Jet Energy Scale was the largest. The final result was compared to next-to-leading order theory and good agreement was found. These results may be used in the determination of the proton parton distribution functions and to set limits on new physics.