A Ca-Al-Si/FeS2 cell has been developed and has exhibited reasonably stable capacity through 3200 h of operation. This system is expected to be capable of meeting the ultimate performance goals (i.e., 160 W.h/kg) of this development program. Further tests of this cell system in the coming year will better define its ultimate performance capabilities.

"In recent years, the increasing sophistication of transmission electron microscope (TEM) studies of materials has necessitated more exacting methods of specimen preparation. The present report describes improved equipment and techniques for electropolishing and chemically polishing a wide variety of specimens. Many of the specimens used in developing or improving the techniques to be described were irradiated with heavy ions such as nickel or vanadium to study radiation damage. The high cost of these specimens increased the need for reproducible methods of initial preparation postirradiation processing, and final thinning for TEM examination. A technique was also developed to salvage specimens that had previously been thinned but were unusable for various reasons. Jet polishing is, in general, the method of choice for surface polishing, sectioning, and thinning. The older beaker electropolishing method is included in this report because it is inexpensive and simple, and gives some insight into how the more recent methods were developed"--NTIS abstract.

Although the Dirac theory of the hydrogen atom was proposed more than half a century ago, extension of the theory and its practical applications to complex atomic spectra took decades to mature. Development of quantum electrodynamics (QED) in its modern form, advances in high precision experimental techniques, and invention of high-speed computers have made atomic spectroscopy one of the most accurate branches of physics today, both in theory and experiment. In addition to a long-standing need to identify line-spectra coming from far and near parts of the universe, necessities such as to test QED further and to provide reliable data for ions in tokamak plasmas require an understanding of the theory of relativistic atomic structure beyond the framework of the original Dirac theory. Twenty articles from the proceedings of the workshop are presented. Contributed papers are grouped into theoretical and experimental subjects and presented after the papers for the second (atomic structure calculations) and third (experiment) sessions of the Workshop. Alphabetical listing of the authors is presented in Appendix 1, program of the Workshop in Appendix 2, and the list of the participants in Appendix 3.

Quarterly report discussing fuel cell research and development work at Argonne National Laboratory (ANL). This report describes work aimed at understanding and improving the performance of fuel cells having molten alkali-carbonate mixtures as electrolytes; the fuel cells operate at temperatures near 925 K.

This report consists of highlights for 1977 of Argonne National Laboratory's program on the development of lithium/metal sulfide batteries.

Quarterly progress report discussing projects by Argonne National Laboratories and subcontractors related to high-temperature batteries.

Quarterly progress report summarizing work done in Argonne National Laboratory's Applied Physics Division and Components Technology Division. The work in the Applied Physics Division includes reports on reactor safety program by members of the Reactor Safety Appraisals Group, Monte Carlo analysis of safety-related critical assembly experiments by members of the Theoretical Fast Reactor Physics Group, and Planning of Safety-Related (ZPR) Planning and Experiments Group. Work on reactor core thermal-hydraulic code development performed in the Components Technology Division is also included in this report.

A combination of backscattered electron imaging and analytical electron microscopy (AEM) with electron diffraction have been used to determine the physical and chemical properties of uranium contamination in soils from the Fernald Environmental Management Project in Ohio. The information gained from these studies has been used in the development and testing of remediation technologies.

OTTER (Organized Techniques for Theorem-proving and Effective Research) is a resolution-style theorem-proving program for first-order logic with equality. OTTER includes the inference rules binary resolution, hyperresolution, URresolution, and binary paramodulation. Some of its other abilities are conversion from first-order formulas to clauses, forward and back subsumption, factoring, weighting, answer literals, term ordering, forward and back demodulation, evaluable functions and predicates, and Knuth-Bendix completion. OTTER is coded in C, it is free, and it is portable to many different kinds of computers.

Highlights of the Chemical Technology (CMT) Division's activities during 1989 are presented. In this period, CMT conducted research and development in the following areas: (1) electrochemical technology, including high-performance batteries (mainly lithium/iron sulfide and sodium/metal chloride), aqueous batteries (lead-acid and nickel/iron), and advanced fuel cells with molten carbonate and solid oxide electrolytes; (2) coal utilization, including the heat and seed recovery technology for coal-fired magnetohydrodynamics plants and the technology for fluidized-bed combustion; (3) method, for recovery of energy from municipal waste and techniques for treatment of hazardous organic waste; (4) nuclear technology related to a process for separating and recovering transuranic elements from nuclear waste and for producing 99Mo from low-enriched uranium targets, the recovery processes for discharged fuel and the uranium blanket in a sodium-cooled fast reactor (the Integral Fast Reactor), and waste management; and (5) physical chemistry of selected materials in environments simulating those of fission and fusion energy systems.

This report introduces the following programs: kxp: a time-saving LaTeX preprocessor, kxpl: kxp plus latex, kxh: a help facility for kxp and LaTex, ptex: a program for printing a LaTeX document, and pptex: a program for printing parts of a LaTeX document. More detailed descriptions will be given in Part 2: A Reference Manual. The appendix gives instructions on how to use Argonne's Mathematics and Computer Science Division letterhead and intralaboratory memo L(sup A)T(sub E)X styles.

Quarterly progress report summarizing work performed by the Argonne National Laboratory Light-Water-Reactor Safety Research Program. It includes sections discussing research and development in: (1) loss of-coolant accident research: heat transfer and fluid dynamics; (2) transient fuel response and fission-product release program; (3) mechanical properties of zircaloy containing oxygen; and (4) steam-explosion studies.

Annual report of the environmental monitoring program at Argonne National Laboratory, discussing activities and findings of the group.

Report on development of high-performance batteries including design study for stationary energy storage and electric-vehicle propulsion, and materials development studies on electrical feedthroughs and new types of separators.

This is a sequel to the paper ''A comparison of two ODE codes: GEAR and EPISODE,'' and is concerned with the testing of two superficially similar ODE packages, GEAR and EPISODE. Fourteen basic test problems, some with several cases, are the basis for the testing. These problems represent several types-nonlinear systems with real and complex eigenvalues, linear systems with varied diagonal dominance, linear scalar problems, stiff and non-stiff problems, chemical kinetics with and without diurnal effect, and systems arising from the use of the numerical method of lines. Some problems are included in order to examine the options and error returns. The test results are presented in two forms: raw output and a comparative display of operation counts and of timings for the best method in the GEAR package and the best method in the EPISODE package. This approach allows a comparison of the consequences of the fixed-step interpolate strategy (GEAR) for changing step size against the truly variable step size strategy (EPISODE). It is concluded that EPISODE is generally faster than GEAR for problems involving wave fronts or transients on the interior of the interval of integration. For linear or simply decaying problems, these roles are usually reversed.

Quarterly progress report summarizing work done in Argonne National Laboratory's Applied Physics Division including: reactor safety research and technical coordination of the Reactor Safety Research safety analysis program.

This document provides a complete specification of the input language for the environmental theorem prover. This language is essentially the same input language used by any of the programs designated by AURA, an automated reasoning program developed at Argonne National Laboratory. The intended audience is the user who is already familiar with the concepts and terms associated with resolution-based theorem provers.

This report presents the results of a survey undertaken to identify and characterize current practices for detecting and locating leaks in district heating systems, particular steam systems. Currently used technology and practices are reviewed. In addition, the survey was used to gather information that may be important for the application of acoustic leak detection. A few examples of attempts to locate leaks in steam and hot water pipes by correlation of acoustic signals generated by the leaks are also discussed.

The Generic TRUEX Model (GTM) was used to design a flowsheet for the TRUEX solvent extraction process that would be used to determine its instrumentation and control requirements. Sensitivity analyses of the key process variables, namely, the aqueous and organic flow rates, feed compositions, and the number of contactor stages, were carried out to assess their impact on the operation of the TRUEX process. Results of these analyses provide a basis for the selection of an instrument and control system and the eventual implementation of a control algorithm. Volume Two of this report is an evaluation of the instruments available for measuring many of the physical parameters. Equations that model the dynamic behavior of the TRUEX process have been generated. These equations can be used to describe the transient or dynamic behavior of the process for a given flowsheet in accordance with the TRUEX model. Further work will be done with the dynamic model to determine how and how quickly the system responds to various perturbations. The use of perturbation analysis early in the design stage will lead to a robust flowsheet, namely, one that will meet all process goals and allow for wide control bounds. The process time delay, …

Dynamic interactions between the vehicle and guideway in a high-speed ground transportation system based on magnetically levitated (maglev) vehicles were studied, with an emphasis on the effects of vehicle and guideway parameters. Two dynamic models for the vehicle are presented. In one model, the vehicle is considered to be a moving force traveling at various speeds on a simply supported single- or two-span beam. In the second model, the vehicle is considered to be one-dimensional and has two degrees of freedom; this model consists of the primary and secondary suspensions of the vehicle, with lumped masses, linear springs, and dampings. The Bernoulli-Euler beam equation is used to model the characteristics of a flexible guideway, and the guideway synthesis is based on modal analysis. Analyses were performed to gain an understanding of response characteristics under various loading conditions and to provide benchmark data for verification of existing comprehensive computer programs and some basic design guidelines for maglev systems. Finally, the German Transrapid maglev system was evaluated.

This report reviews and summarizes the present state of knowledge regarding the effects of the glass surface area/solution volume (SA/V) ratio on the corrosion behavior of borosilicate waste glasses.

A program has been established for DOE Environmental Restoration and Waste Management (EM) to evaluate factors that are likely to affect waste glass reaction during repository disposal, with emphasis on an unsaturated environment typical of what may be expected for the proposed Yucca Mountain repository site.

The radiolytic yields of hydrogen nitrogen, oxygen, nitrous oxide, and carbon monoxide from two batches of WHC-supplied samples of grouted simulated waste have been (gamma) irradiated at several dose rates (0.025, 0.63 and 130 krad/h for hydrogen and 130 krad/h for all other gases). In one batch, the liquid waste simulant that was added to the grout included the original components that were added to Tank 102-AP (labeled "virgin" waste.) The second batch included a similar liquid waste simulant that was preirradiated to 35 Mrad prior to incorporation into the grout. It is believed that the preirradiated samples more closely represent radioactive waste that was stored in the tank for several years. The lowest dose rate corresponds approximately to that expected in the grout; with the high dose rate, doses equivalent to about 85 years storage in grout vaults were achieved. Most of the results on the batch of virgin samples have been reported recently (Report ANL 93/42). Here we report the results from the batch of preirradiated grout samples and compare the results from the two batches. The radiolytic yields of hydrogen and nitrogen are lower in the preirradiated than in the virgin grout. On the other hand G(oxygen) …

BlockSolve is a software library for solving large, sparse systems of linear equations on massively parallel computers. The matrices must be symmetric, but may have an arbitrary sparsity structure. BlockSolve is a portable package that is compatible with several different message-passing pardigms. This report gives detailed instructions on the use of BlockSolve in applications programs.