Enhanced durability and reactivity for zinc ferrite desulfurization sorbent (open access)

Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.
Date: August 28, 1987
Creator: Jha, Mahesh C.; Baltich, Linda K. & Berggren, Mark H.
Object Type: Report
System: The UNT Digital Library
The EPRI Laboratory experiments at ANL. [Vaporization of core-concrete mixtures] (open access)

The EPRI Laboratory experiments at ANL. [Vaporization of core-concrete mixtures]

The vaporization of core-concrete mixtures is being measured using a transpiration method. Mixtures of stainless steel, concrete (limestone or basaltic) and urania (doped with La/sub 2/O/sub 3/, SrO, BaO, and ZrO/sub 2/) are vaporized at 2150 - 2400 K from a zirconia crucible into flowing He - 6% H/sub 2/ gas. Up to 600 ppM H/sub 2/O is added to the gas to fix the partial molar free energy of oxygen in the range -420 kJ to -550 kJ. The fraction of the sample that is vaporized is determined by weight change and by chemical analyses on the condensates that are collected in an Mo condenser tube. The results are being used to test the thermodynemic data base and the underlying assumptions of computer codes used for prediction of release during the severe accident. 13 refs., 2 tabs.
Date: October 28, 1987
Creator: Roche, M. F.; Settle, J. L.; Leibowitz, L.; Johnson, C. E. & Ritzman, R. L.
Object Type: Article
System: The UNT Digital Library
Using the Nova target chamber for high-yield targets (open access)

Using the Nova target chamber for high-yield targets

The existing 2.2-m-radius Nova aluminum target chamber, coated and lined with boron-seeded carbon shields, is proposed for use with 1000-MJ-yield targets in the next laser facility. The laser beam and diagnostic holes in the target chamber are left open and the desired 10/sup -2/ Torr vacuum is maintained both inside and outside the target chamber; a larger target chamber room is the vacuum barrier to the atmosphere. The hole area available is three times that necessary to maintain a maximum fluence below 12 J/cm/sup 2/ on optics placed at a radius of 10 m. Maximum stress in the target chamber wall is 73 MPa, which complies with the intent of the ASME Pressure Vessel Code. However, shock waves passing through the inner carbon shield could cause it to comminute. We propose tests and analyses to ensure that the inner carbon shield survives the environment. 13 refs.
Date: September 28, 1987
Creator: Pitts, J.H.
Object Type: Article
System: The UNT Digital Library
Thermal stress in the edge cladding of Nova glass laser disks (open access)

Thermal stress in the edge cladding of Nova glass laser disks

We calculated thermal stresses in Nova glass laser disks having light-absorbing edge cladding glass attached to the periphery with an epoxy adhesive. Our closed-form solutions indicated that, because the epoxy adhesive is only 25 ..mu..m across, it does not significantly affect the thermal stress in the disk or cladding glass. Our numerical results showed a peak tensile stress in the cladding glass of 24 MPa when the cladding glass had a uniform absorption coefficient of 7.5 cm/sup -1/. This peak value is reduced to 19 MPa if surface parasitic oscillation heating is eliminated by tilting the disk edges. The peak tensile stresses exceed the typical 7 to 14-MPa working stress for glass; however, we have not observed any disk or cladding glass failures at peak Nova fluences of 20 J/cm/sup 2/. We have observed delamination of the epoxy adhesive bond at fluences several times that which would occur on Nova. Replacement laser disks will incorporate cladding with a reduced absorption coefficient of 4.5 cm/sup -1/. Recent experiments show that this reduced absorption coefficient is satisfactory.
Date: September 28, 1987
Creator: Pitts, J. H.; Kong, M. K. & Gerhard, M. A.
Object Type: Article
System: The UNT Digital Library
Characterization of organics in the feed streams for the H/F Effluent Treatment Facility (open access)

Characterization of organics in the feed streams for the H/F Effluent Treatment Facility

Analysis of weekly samples from the F- and H-area treblers indicates that tri-n-butylphosphate (TBP) is the major organic species in the feed to the F/H Effluent Treatment Facility (ETF). Concentrations up to 100 mg/L were observed, with an average of 50 mg/L from F-area and 3 mg/L from H-area. Normal paraffinic hydrocarbons (NPH) are present in lesser amounts, ranging up to 4 mg/L. These two species, both foulants of the reverse osmosis (RO) membranes, account for almost all of the dissolved organic carbon present in the samples. Samples from the sources which feed the treblers (and will feed the ETF) indicate that all eight canyon evaporators contribute TBP. None of the four tank farm evaporators contribute TBP. If TBP is to be removed at the sources, either the overhead streams from a number of evaporators will have to be piped to one or two central locations for treatment, or up to eight individual treatment points would have to be maintained. 6 refs., 5 tabs.
Date: September 28, 1987
Creator: Oblath, S. B.
Object Type: Report
System: The UNT Digital Library
Tumulus Disposal Demonstration Facility for the Oak Ridge Reservation (open access)

Tumulus Disposal Demonstration Facility for the Oak Ridge Reservation

This disposal concept is based on the Tumulus design developed by the French at the La Manche facility. Waste units are stacked above-grade on a concrete pad. The facility currently under development at the Oak Ridge National Laboratory (ORNL) involves sealing waste in concrete vaults, placing the vaults on a grade level concrete pad, and covering the pad and vaults with a soil cover after vault emplacement is complete. Emplacement is expected to continue until the facility exhausts its approximate 800 m/sup 3/ (28,000 ft/sup 3/) capacity. The facility incorporates engineered barriers to radionuclide migration; a monitoring system to ensure barrier performance; and a newly developed set of Demonstration Waste Acceptance Criteria to reduce the likelihood of groundwater contamination.
Date: June 28, 1987
Creator: Clapp, R.B. & van Hoesen, S.D.
Object Type: Article
System: The UNT Digital Library
ECH (electron cyclotron heating) in the Microwave Tokamak Experiment (open access)

ECH (electron cyclotron heating) in the Microwave Tokamak Experiment

The Microwave Tokamak Experiment (MTX) at LLNL will investigate electron heating in the MTX tokamak (formerly Alcator-C) at high density (up to 6 x 10/sup 20/ m/sup -3/) and high power by using a free electron laser (FEL). Parameters of the FEL are a peak power up to 8 GW and 50 ns duration, with average power 1 to 2 MW, at a frequency of 250 GHz. The planned input driver for the FEL is a gyrotron oscillator. The FEL output will be transported quasi-optically, inside a 50 cm evacuated pipe, to the input port of the tokamak by means of a four-mirror system. Launch polarization is the ordinary mode. This experiment will test the FEL technology at short wavelength and high peak and average power levels. Important physics issues to be explored are the effects of intense pulse heating (electric field up to 500 kV/cm) on nonlinear wave absorption and bulk heating, plasma confinement, plasma impurities, and parametric instabilities. Because the FEL technology is scalable to higher frequency and power, success of these experiments has importance for next-generation tokamaks.
Date: April 28, 1987
Creator: Stallard, B. W.; Smith, G. R.; James, R. A.; Thomassen, K. I.; Kritz, A. H.; Makowski, M. et al.
Object Type: Article
System: The UNT Digital Library
Texas Register, Volume 12, Number 65, Pages 2876-2979, August 28, 1987 (open access)

Texas Register, Volume 12, Number 65, Pages 2876-2979, August 28, 1987

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.
Date: August 28, 1987
Creator: Texas. Secretary of State.
Object Type: Journal/Magazine/Newsletter
System: The Portal to Texas History
Texas Register, Volume 12, Number 57, Pages 2453-2487, July 28, 1987 (open access)

Texas Register, Volume 12, Number 57, Pages 2453-2487, July 28, 1987

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.
Date: July 28, 1987
Creator: Texas. Secretary of State.
Object Type: Journal/Magazine/Newsletter
System: The Portal to Texas History
Texas Register, Volume 12, Number 32, Pages 1407-1427, April 28, 1987 (open access)

Texas Register, Volume 12, Number 32, Pages 1407-1427, April 28, 1987

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.
Date: April 28, 1987
Creator: Texas. Secretary of State.
Object Type: Journal/Magazine/Newsletter
System: The Portal to Texas History
Nuclear materials transportation workshops: USDOE outreach to local governments. Final report (open access)

Nuclear materials transportation workshops: USDOE outreach to local governments. Final report

To provide direct outreach to local governments, the Transportation Management Division of the United States Department of Energy asked the Urban Consortium and its Energy Task Force to assemble representatives for two workshops focusing on the transport of nuclear materials. The first session, for jurisdictions east of the Mississippi River, was held in New Orleans on May 5--6, 1988; the second was conducted on June 6--7, 1988 in Denver for jurisdictions to the west. Twenty local government professionals with management or operational responsibility for hazardous materials transportation within their jurisdictions were selected to attend each workshop. The discussions identified five major areas of concern to local government professionals; coordination; training; information resources; marking and placarding; and responder resources. Integrated federal, state, and local levels of government emerged as a priority coordination issue along with the need for expanded availability of training and training resources for first-reponders.
Date: September 28, 1987
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report No. 3, April--June 1987 (open access)

Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report No. 3, April--June 1987

AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.
Date: August 28, 1987
Creator: Jha, M. C.; Baltich, L. K. & Berggren, M. H.
Object Type: Report
System: The UNT Digital Library
Texas Attorney General Opinion: JM-628 (open access)

Texas Attorney General Opinion: JM-628

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Jim Mattox, regarding a legal question submitted for clarification; Applicability of the Professional Prosecutors Act to funding for the criminal district attorney of Tyler County
Date: January 28, 1987
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
Texas Attorney General Opinion: JM-711 (open access)

Texas Attorney General Opinion: JM-711

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Jim Mattox, regarding a legal question submitted for clarification; Constitutionality of procedures employed by state universities in offering religion and biblical studies courses
Date: May 28, 1987
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
Texas Attorney General Opinion: JM-712 (open access)

Texas Attorney General Opinion: JM-712

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Jim Mattox, regarding a legal question submitted for clarification; Applicability of the out-of-state bidder provisions of article 601g, V.T.C.S., to an Arkansas statute which gives preference to certain bidders on highway construction projects
Date: May 28, 1987
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
Texas Attorney General Opinion: JM-759 (open access)

Texas Attorney General Opinion: JM-759

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Jim Mattox, regarding a legal question submitted for clarification; Whether the Texas Department of Corrections granting of good time to prisoners for time incarcerated in a county jail violates section 3(c) of article 6181-1, V.T.C.S.
Date: July 28, 1987
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
Texas Attorney General Opinion: JM-777 (open access)

Texas Attorney General Opinion: JM-777

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Jim Mattox, regarding a legal question submitted for clarification; Whether a loss of "physical or mental faculties" under article 67011-1, V.T.C.S., represents more than one distinct offense for purpose of a criminal complaint
Date: August 28, 1987
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
Texas Attorney General Opinion: JM-778 (open access)

Texas Attorney General Opinion: JM-778

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Jim Mattox, regarding a legal question submitted for clarification; Jurisdiction of a county court at law over suits for the collection of delinquent taxes
Date: August 28, 1987
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
Texas Attorney General Opinion: JM-798 (open access)

Texas Attorney General Opinion: JM-798

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Jim Mattox, regarding a legal question submitted for clarification; Whether a defendant is eligible for misdemeanor probation while he is serving a probated felony sentence
Date: September 28, 1987
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
Texas Attorney General Opinion: JM-799 (open access)

Texas Attorney General Opinion: JM-799

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Jim Mattox, regarding a legal question submitted for clarification; Whether the Cameron County Bail Bond Board is authorized to set a limit on the value amount of bonds which a corporate surety may provide
Date: September 28, 1987
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
Texas Attorney General Opinion: JM-817 (open access)

Texas Attorney General Opinion: JM-817

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Jim Mattox, regarding a legal question submitted for clarification; Whether a state university may contract with a corporation in which the spouse of a regent owns a substantial interest
Date: October 28, 1987
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
Texas Attorney General Opinion: JM-837 (open access)

Texas Attorney General Opinion: JM-837

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Jim Mattox, regarding a legal question submitted for clarification; Whether artificial or tube feeding constitutes a life-sustaining procedure for purposes of article 4590h, V.T.C.S. (RQ-1036)
Date: December 28, 1987
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
I.F.H. Quarter Module Lifting Fixture (open access)

I.F.H. Quarter Module Lifting Fixture

The main purpose of this report is to explain the procedure for lifting the I.F.H. quarter module from a 'prone' position to a 'standing' position and then into the liquid nitrogen test vessel. The main objective for the design of the lifting fixtures was simplicity. The fixtures are to be made of .75 inch thick stainless steel plates which is a stock item for the steel companies. The fixtures are stainless steel so they will be able to keep their structural integrity when immersed in the liquid nitrogen.
Date: April 28, 1987
Creator: May, M.P.
Object Type: Report
System: The UNT Digital Library
Direct Catalytic Conversion of Methane and Light Hydrocarbon Gases Quarterly Report: Number 3 (open access)

Direct Catalytic Conversion of Methane and Light Hydrocarbon Gases Quarterly Report: Number 3

The goal of this research is to develop catalysts that directly convert methane and light hydrocarbons to intermediates that can, as economics dictate, be subsequently converted either to liquid fuels or value-added chemicals. In this program we are exploring two approaches to developing such catalysts. The first approach consists of developing advanced catalysts for reforming methane. We will prepare the catalysts by reacting organometallic complexes of transition metals (Fe, Ru, Rh, and Re) with zeolitic and rare-earth-exchanged zeolitic supports to produce surface-confined metal complexes in the zeolite pores. Our second approach entails synthesizing the porphyrin and phthalocyanine complexes of Cr, Mn, Ru, Fe, and/or Co within the pores of zeolitic supports for use as selective oxidation catalysts for methane and light hydrocarbons. During this reporting period, we concentrated on synthesizing and testing methane oxidation catalysts using the automated GC sampling system. We modified our preparation method of zeolite-encapsulated phthalocyanines (PC). The catalysts have higher complex loading, and the uncomplexed metal ions were back-exchanged by sodium ions (to remove any uncomplexed metal ions). Four metal ions were used: cobalt, iron, ruthenium, and manganese. We also synthesized four zeolite-encapsulated tetraphenylporphyrin (TPP) complexes using the same metals. These catalysts were tested for methane …
Date: August 28, 1987
Creator: Wilson, Robert B., Jr. & Chan, Yee Wai
Object Type: Report
System: The UNT Digital Library