Advective-diffusive/dispersive transport of chemically reacting species in hydrothermal systems. Final report, FY83-85 (open access)

Advective-diffusive/dispersive transport of chemically reacting species in hydrothermal systems. Final report, FY83-85

A general formulation of multi-phase fluid flow coupled to chemical reactions was developed based on a continuum description of porous media. A preliminary version of the computer code MCCTM was constructed which implemented the general equations for a single phase fluid. The computer code MCCTM incorporates mass transport by advection-diffusion/dispersion in a one-dimensional porous medium coupled to reversible and irreversible, homogeneous and heterogeneous chemical reactions. These reactions include aqueous complexing, oxidation/reduction reactions, ion exchange, and hydrolysis reactions of stoichiometric minerals. The code MCCTM uses a fully implicit finite difference algorithm. The code was tested against analytical calculations. Applications of the code included investigation of the propagation of sharp chemical reaction fronts, metasomatic alteration of microcline at elevated temperatures and pressures, and ion-exchange in a porous column. Finally numerical calculations describing fluid flow in crystalline rock in the presence of a temperature gradient were compared with experimental results for quartzite.
Date: June 20, 1986
Creator: Lichtner, P. C. & Helgeson, H. C.
Object Type: Report
System: The UNT Digital Library
Strontium, Strontium-90, and Calcium Analyses of Clinch and Tennessee River Clams (open access)

Strontium, Strontium-90, and Calcium Analyses of Clinch and Tennessee River Clams

Analyses of clam shells for Sr, Sr/sup 90/, and Ca are reported. The data include 208 Sr, 80 Sr/sup 90/, and 35 Ca analyses. Information on age of the clam and shell weight are also included because the Sr concentration in some shells is affected by age and growth rate. A detailed description of sample treatment and preparation is also included. (auth)
Date: June 20, 1962
Creator: Nelson, D. J.
Object Type: Report
System: The UNT Digital Library
Why search for double beta decay (open access)

Why search for double beta decay

Searching for neutrinoless double beta decay is the only known practical method for trying to determine whether neutrinos are their own antiparticles. The theoretical motivation for supposing that they may indeed be their own antiparticles is described. The reason that it is so difficult to ascertain experimentally whether they are or are not is explained, as is the special sensitivity of neutrinoless double beta decay. The potential implications of the observation of this reaction for neutrino mass and for the physics of neutrinos is discussed.
Date: April 20, 1988
Creator: Kayser, B.
Object Type: Article
System: The UNT Digital Library
Automatic beam centering at the SSC interaction regions (open access)

Automatic beam centering at the SSC interaction regions

In the SSC interaction regions, the two colliding beams, each only a few microns in size, will have to be centered and maintained in good alignment over many hours, in order to provide the maximum possible luminosity and to minimize off-center beam-beam focussing effects. It is unlikely that sufficiently good alignment can be achieved without some kind of active feedback system, based on the beam-beam interaction rate. This memo describes such a system. In the proposed scheme, one of the beams is moved continuously and in a circular fashion about its mean transverse position. The radius of this motion is approximately 0.01 of the rms beam size at the interaction point. The motion is achieved with two sets of crossed high frequency dipole magnets, one on each side of the interaction region, suitably phased. As a consequence of this motion, the beam-beam interaction rate is modulated in synchronism with the beam motion when the beams are not centered on one another. The amplitude and phase of this modulation yields information on the magnitude and direction of the misalignment between the beams, allowing continuous display and automatic correction of any misalignment.
Date: March 20, 1984
Creator: Joestlein, H.
Object Type: Report
System: The UNT Digital Library
BX in situ oil shale project. Quarterly technical progress report, September 1-November 30, 1981 (open access)

BX in situ oil shale project. Quarterly technical progress report, September 1-November 30, 1981

September 1, 1981-November 30, 1981, was the fourth consecutive quarter of superheated steam injection at the BX In Situ Oil Shale Project. During the quarter, 117,520 barrels of water as steam were injected into project injection wells at an average wellhead temperature of 715/sup 0/F and an average wellhead pressure of 1378 PSIG. During the same period, 148,516 barrels of fluid were produced from the project production wells for a produced-to-injected fluid ratio of 1.26 to 1.0. Net oil production for the quarter was 169 barrels.
Date: December 20, 1981
Creator: Dougan, P. M.
Object Type: Report
System: The UNT Digital Library
Laser produced plasma soft x-ray generation (open access)

Laser produced plasma soft x-ray generation

The efficiency of soft x-ray production from laser-irradiated plasmas is simulated for two different spectral regions. These two regions, 14{Angstrom} {plus minus} 15% and 130{Angstrom} {plus minus} 1%, were chosen for proximity mask or point-projection technological applications. Relatively large conversion efficiencies were obtained from irradiation of a stainless steel target using the conditions suggested by recent Hampshire Instruments' experiments for proximity masking. Pulse-width and laser frequency parameter studies were performed for point-projection applications which suggest that the conversion applications which suggest that the conversion efficiency is sensitive to pulse-width but not to laser frequency. One of the critical components of any x-ray lithographic scheme is of course the x-ray laser source. There are two primary contenders for a reliable, efficient source currently: synchrotron radiation and spectral emission from laser produced plasma. The dominant issue for laser-plasma emission is the conversion efficiency -- output in the intended operating spectral region relative the required incident laser energy. Simulations are described in the following for both high and low energy spectral regions which have been suggested by either the proximity masking or point-projection technology.
Date: May 20, 1991
Creator: Cerjan, C. & Rosen, M.D.
Object Type: Article
System: The UNT Digital Library
Applications of Micellar Enzymology to Clean Coal Technology (open access)

Applications of Micellar Enzymology to Clean Coal Technology

This project is designed to develop methods for pre-combustion coal remediation by implementing recent advances in enzyme biochemistry. The novel approach of this study is incorporation of hydrophilic oxidative enzymes in reverse micelles in an organic solvent. Enzymes from commercial sources or microbial extracts are being investigated for their capacity to remove organic sulfur from coal by oxidation of the sulfur groups, splitting of C-S bonds and loss of sulfur as sulfuric acid Dibenzothiophene (DBT) and ehtylphenylsulfide (EPS)are serving as serving as models of organic sulfur-containing components of coal in initial studies.
Date: January 20, 1990
Creator: Walsh, C. T.
Object Type: Report
System: The UNT Digital Library
Directions for possible upgrades of the Mirror Fusion Test Facility (MFTF) (open access)

Directions for possible upgrades of the Mirror Fusion Test Facility (MFTF)

The Mirror Fusion Test Facility (MFTF) may be upgraded by extending the time of plasma sustenance in an approach to steady-state operation and/or by increasing the neutral-beam injection energy. Some parameter bounds for these upgrades are discussed as they relate to a definition of the required neutral-beam development.
Date: December 20, 1977
Creator: Damm, C. C.; Coensgen, F. H.; Devoto, R. S.; Molvik, A. W.; Porter, G. D.; Shearer, J. W. et al.
Object Type: Article
System: The UNT Digital Library
Elementary reaction rate measurements at high temperatures by tunable-laser flash-absorption (open access)

Elementary reaction rate measurements at high temperatures by tunable-laser flash-absorption

The major objective of this program is to measure thermal rate coefficients and branching ratios of elementary reactions. To perform these measurements, we have constructed an ultrahigh-purity shock tube to generate temperatures between 1000 and 5500 K. The tunable-laser flash-absorption technique is used to measure the rate of change of the concentration of species which absorb below 50,000 cm{sup {minus}1} e.g.: OH, CH, and CH{sub 3}. This technique is being extended into the vacuum-ultraviolet spectral region where we can measure atomic species e.g.: H, D, C, O, and N; and diatomic species e.g.: O{sub 2}, CO, and OH.
Date: March 20, 1992
Creator: Hessler, J.P.
Object Type: Article
System: The UNT Digital Library
Plutonium Residue Recovery (PuRR) project quarterly progress report, April--June 1989 (open access)

Plutonium Residue Recovery (PuRR) project quarterly progress report, April--June 1989

A material-balance flowsheet for ash-heel processing has been prepared. The major process features are (1) reduction of Pu into a calcium-zinc alloy and selective electrolytic recovery of the Pu from the alloy, (2) removal of americium as a waste, (3) concentration of nontransuranic tramp elements in a zinc waste, (4) removal of oxygen and recovery of calcium by electrolysis of CaO, and (5) zinc recycle by evaporation. Based on this idealized flowsheet, the mass of solid waste is only 62% of that of the original residue. This is accomplished by recycling virtually all the reagents and discarding the oxygen as CO and CO{sub 2}. The pyrochemical recovery of Pu from incinerator ash heel from the Rocky Flats Plant was investigated. During this period, zinc-calcium alloys were used to reduce the PuC{sub 2} in the ash. Reduction of ash heel has been attempted with zinc-calcium alloys containing 2, 6, and 10 wt% calcium after the reduction. These resulted in extractions of 95%, 97%, and 99.5%, respectively, of the Pu from the salt. Following exposure of the reduction alloy to a ZnCl{sub 2}-bearing salt, the Pu was removed effectively from the alloy; however, the Pu recovered in the salt did not complete …
Date: October 20, 1989
Creator: Gregg, D. W.; Hickman, R. G.; Landrum, J. H. (Lawrence Livermore National Lab., CA (USA)); Johnson, G. K.; Johnson, I.; Mulcahey, T. P. et al.
Object Type: Report
System: The UNT Digital Library
Ecological Sampling and Meteorological Calculation of Fallout on Forests Near Oak Ridge (open access)

Ecological Sampling and Meteorological Calculation of Fallout on Forests Near Oak Ridge

Spatial patterns of radioactive contuamination on forest foliage were measured by gamma spectrometry and are discussed with respect to local vs. world- wide origin of the fallout and implications for ecology, health physics, and management of nuclear facilities. In September 1959, I/sup 131/ on dogwood leaf samples varied from over 500 mu mu c/g dry wt near Oak Ridge National Laboratory stacks to 1 to 7 mu mu c/g near the margins of the Oak Ridge Reservation. Stack fallout tended to occur closer to the source than was calculated from hourly wind data by an IBM 610 computer program based on Culkowski' s adaptation of the SuttonChamberlain theory of atmospheric diffusion and deposition. Over most of the Reservation levels of Ru/sup 106/ Cs/sup 137/ Zr/sup 9/ >s/sup 5/Nb/sup 95/ and Ce/sup 144/ were similar to levels found elsewhere (2 to 9, 1 to 3, 2 to 9, and 10 to 20 mu mu c/g respectively) and were presumably controlled by weapons fallout. Higher levels were found in small areas and indicate the need for attention to localized contamination, even though indirect estilevels considered hazardous from the standpoint of health physics. (auth)
Date: September 20, 1961
Creator: Olson, J.S.
Object Type: Report
System: The UNT Digital Library
The Effect of Chemical Additives on the Synthesis of Ethanol (open access)

The Effect of Chemical Additives on the Synthesis of Ethanol

The objective of this research is to elucidate the role of various chemical additives on ethanol synthesis over Rh- and Ni-based catalysts. Chemical additives used for this study will include S, P, Ag, Cu, Mn, and Na which have different electronegativities. The effect of additives on the surface state of the catalysts, heat of adsorption of reactant molecules, reaction intermediates, reaction pathways, reaction kinetics, and product distributions is/will be investigated by a series of experimental studies of NO adsorption, reaction probing, study state rate measurement, and transient kinetic study. A better understanding of the role of additives on the synthesis reaction may allow us to use chemical additives to manipulate the catalytic properties of Rh- and Ni-based catalysts for producing high yields of ethanol from snygas. 27 refs., 2 figs., 2 tabs.
Date: September 20, 1991
Creator: Chuang, S. C. & Balakos, M. W.
Object Type: Report
System: The UNT Digital Library
Current California legislative and regulatory activity impacting geothermal hydrothermal commercialization: monitoring report No. 2. Report No. 1020 (open access)

Current California legislative and regulatory activity impacting geothermal hydrothermal commercialization: monitoring report No. 2. Report No. 1020

The progress of four bills relating to geothermal energy is reported. The current regulatory activities of the California Energy Commission, the Lake County Planning Commission/Lake County Air Pollution Control District, the Governor's Office of Planning and Research, the State Lands' Commission, and the California Public Utilities Commission are reviewed. (MHR)
Date: April 20, 1980
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Anomalous isotopic composition of cosmic rays (open access)

Anomalous isotopic composition of cosmic rays

Recent measurements of nonsolar isotopic patterns for the elements neon and (perhaps) magnesium in cosmic rays are interpreted within current models of stellar nucleosynthesis. One possible explanation is that the stars currently responsible for cosmic-ray synthesis in the Galaxy are typically super-metal-rich by a factor of two to three. Other possibilities include the selective acceleration of certain zones or masses of supernovas or the enhancement of /sup 22/Ne in the interstellar medium by mass loss from red giant stars and planetary nebulas. Measurements of critical isotopic ratios are suggested to aid in distinguishing among the various possibilities. Some of these explanations place significant constraints on the fraction of cosmic ray nuclei that must be fresh supernova debris and the masses of the supernovas involved. 1 figure, 3 tables.
Date: June 20, 1980
Creator: Woosley, S. E. & Weaver, T. A.
Object Type: Article
System: The UNT Digital Library
Computor program for mathematical evaluation of the Rocky Flats nuclear accident dosimetry system (open access)

Computor program for mathematical evaluation of the Rocky Flats nuclear accident dosimetry system

A computer program has been developed to facilitate the evaluation of the Rocky Flats Emergency Dosimetry System. This program evaluates data to determine the neutron fluence associated with a criticality accident. It is necessary to obtain information about the critical system for personnel dose estimates. Information pertaining to the geometry and position of the critical material and orientation of personnel, with respect to the material, is essential to supplement the calculations contained in this program.
Date: December 20, 1977
Creator: Wood, C. B.
Object Type: Report
System: The UNT Digital Library
Investigation of methods to transfer heat from solar liquid-heating collectors to heat storage tanks. Final report (open access)

Investigation of methods to transfer heat from solar liquid-heating collectors to heat storage tanks. Final report

A study was made of the methods available to transfer heat from the collector to the water storage tank in water heating systems. In counterflow heat exchangers used in double loop water heating systems, it was found to be more important to use a high water flowrate than a high heat transfer fluid flowrate. It was earlier thought to be best to have matched WC/sub p/ (mass flowrate-specific heat) products in the loops. It was shown in this study that the water WC/sub p/ product should be about twice as large as that of the heat transfer fluid. It was found that neither the heat exchanger type nor the size was very critical, so that very simple criteria were adequate in determining optimum heat exchanger size. It was found that there is a definite system size below which one should use a traced tank or a coil in a tank. Equations and optimization criteria were developed for traced tanks or tanks with coils. At present, there is no quantitative understanding of liquid to liquid (direct contact) heat exchangers, though they are clearly quite effective. Draindown systems are discussed, and several appendices are included on heat transfer and other characteristics of …
Date: April 20, 1978
Creator: Horel, J. D. & de Winter, F.
Object Type: Report
System: The UNT Digital Library
Engineering design and analysis of advanced physical fine coal cleaning technologies (open access)

Engineering design and analysis of advanced physical fine coal cleaning technologies

This project is sponsored by the United States Department of Energy (DOE) for the Engineering Design and Analysis of Advanced Physical Fine Coal Cleaning Technologies. The major goal is to provide the simulation tools for modeling both conventional and advanced coal cleaning technologies. This DOE project is part of a major research initiative by the Pittsburgh Energy Technology Center (PETC) aimed at advancing three advanced coal cleaning technologies-heavy-liquid cylconing, selective agglomeration, and advanced froth flotation through the proof-of-concept (POC) level.
Date: January 20, 1992
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Report from the polarization group of the Fermilab injector workshop (open access)

Report from the polarization group of the Fermilab injector workshop

The group considered physics, accelerator, and polarized source issues. Most of the physics study was concerned with what significant and unique experiments could be done if polarized protons could be accelerated in the main injector and eventually in the Tevatron. 12 refs., 4 figs.
Date: July 20, 1989
Creator: Berger, E.; Glass, G.; Imai, K.; Jones, L.; Lin, A.M.T.; Mane, S.R. et al.
Object Type: Article
System: The UNT Digital Library
Hanford Site environmental report for calendar year 1990 (open access)

Hanford Site environmental report for calendar year 1990

The Hanford Site Environmental Report is prepared annually to summarize environmental data and information, describe environmental management performance, and demonstrate the status of compliance with environmental regulations. The report also highlights major environmental programs and efforts. The following sections: describe the Hanford Site and its new mission; summarize the status in 1990 of compliance with environmental regulations; describe the environmental programs at the Hanford Site; present information on environmental surveillance and the ground-water protection and monitoring program; and discuss activities to ensure quality.
Date: December 20, 1991
Creator: Woodruff, R.K.; Hanf, R.W.; Hefty, M.G. & Lundgren, R.E. (eds.)
Object Type: Report
System: The UNT Digital Library
Fusion breeder blanket nucleonics (open access)

Fusion breeder blanket nucleonics

Refined nuclear analysis, including the treatment of resonance and spatial self-shielding, coupled with an optimization procedure, has resulted in improved performance estimates for two conceptual fission-suppressed blankets. Net specific breeding in these two blankets maximized at 0.024 and 0.023 U-233 atoms/MeV, which is about an order of magnitude higher than in fission breeders.
Date: June 20, 1986
Creator: Lee, J. D.
Object Type: Article
System: The UNT Digital Library
Cover-gas seal program. Test report - sodium dip-seal wetting study. [at 450/sup 0/F] (open access)

Cover-gas seal program. Test report - sodium dip-seal wetting study. [at 450/sup 0/F]

This report documents the tests conducted to find a reliable surface preparation method of treating the CRBRP dip seal blade (SA508 Class 2 steel) to insure its sodium wettability at 450F or less. Two techniques were established which depressed the sodium wetting temperature of SA 508, Class 2 dip seal blade material to 375F. These techniques were depositing an approx. 60 x 10/sup -6/ inch layer of tin on the blade surface by a brush-on plating process, and, by cleaning the blade surface with ultrasonics while it is immersed in sodium. The tin plating technique is recommended as the initial and primary surface preparation method and ultrasonics as a rewetting and backup technique. This work was conducted in support of the Sodium Dip Seal Feature Test, DRS 32.05.
Date: October 20, 1977
Creator: Carnevali, R.
Object Type: Report
System: The UNT Digital Library
Image collapsing concentrators. Interim scientific report No. 2 (open access)

Image collapsing concentrators. Interim scientific report No. 2

A cylindrical Fresnel-type lens has been designed and ray traced that focuses approximately to lines over a 60/sup 0/ elevation angle interval. Forty stepped prism facets are configured on the inside surface of the lens, and the lens outer surface can be well approximated by a smooth circular arc. Especially contoured cylindrical subreflectors are described for concentrating the broad image fields of the lens onto a narrow fixed shelf. These image collapsing subreflectors also compensate for focal shortening with azimuth angle incidence variations over nearly a +-60/sup 0/ sector. Ray tracing on the lens and subreflector provide approximate energy distributions on the absorber shelf over the large acceptance angle intervals. The expected performance characteristics of a solar concentrator using the curved lens with facets on the inside surface are compared with a concentrator employing a straight stepped prism lens with facets cut on the outer lens surface.
Date: January 20, 1980
Creator: Sletten, C.J.
Object Type: Report
System: The UNT Digital Library
Resonance localization in tokamaks excited with ICRF waves (open access)

Resonance localization in tokamaks excited with ICRF waves

Advanced wave models used to evaluate ICRH in tokamaks typically use warm plasma theory and allow inhomogeneity in one dimension. The majority of these calculations neglect the fact that gyrocenters experience the inhomogeneity via their motion parallel to the magnetic field. The non-local effects of rotational transform and toroidicity can play a significant role in both the propagation and the absorption physics. In strongly driven systems, wave damping can distort the particle distribution function supporting the wave and this produces changes in the absorption. The most common approach is to use Maxwellian absorption rates. We have developed a bounce-averaged Fokker-Planck quasilinear computational model which evolves the population of particles on more realistic orbits. Each wave-particle resonance has its own specific interaction amplitude within any given volume element; these data need only be generated once, and appropriately stored for efficient retrieval. The wave-particle resonant interaction then serves as a mechanism by which the diffusion of particle populations can proceed among neighboring orbits. The local specific spectral energy absorption rate is directly calculable once the orbit geometry and populations are determined. The code is constructed in such fashion as to accommodate wave propagation models which provide the wave spectral energy density on …
Date: June 20, 1985
Creator: Kerbel, G. D. & McCoy, M. G.
Object Type: Article
System: The UNT Digital Library
Photocathode transfer and storage techniques using alkali vapor feedback control (open access)

Photocathode transfer and storage techniques using alkali vapor feedback control

Photocathodes of quantum efficiency above 1% at the doubled YAG frequency of 532 nM are very sensitive to the local vacuum environment. These cathodes must have a band gap of less than 2.3 eV, and a work function that is also on the order of {approximately}2 volts or less. As such, these surfaces are very reactive as they provide many surface states for the residual gases that have positive electron affinities such as oxygen and omnipotent water. Attendant to this problem is that the optimal operating point for some of these cesium based cathodes is unstable. Three of the cesium series were tried, the Cs-Ag-Bi-O, the Cs{sub 3}Sb and the K{sub 2}CsSb. The most stable material found is the K{sub 2}CsSb. The vacuum conditions can be met by a variety of pumping schemes. The vacuum is achieved by using sputter ion diode pumps, and baking at 250{degrees}C or less for whatever time is required to reduce the pump currents to below 1 uA at room temperature. To obtain the required partial pressure of cesium, a simple very sensitive diagnostic gauge has been developed that can discriminate between free alkali and other gases present. This Pressure Alkali Monitor (PAM) can be …
Date: December 20, 1991
Creator: Springer, R.W. & Cameron, B.J.
Object Type: Article
System: The UNT Digital Library