Nickel-plated uranium corrosion samples, 1 inch dia. X 0.180 inch thick, press-clad with 30-mil aluminum at both 10 and 15 thousand psi, show improved corrosion resistance over samples press-clad at 6 thousand psi with the same time-temperature conditions. Design of equipment for the internal cladding of uranium tubes is progressing. The basic tools will be applicable to several variations of the proposed method of {open_quotes}inverse die sinking.{close_quotes} Analyses of double and triple melted Horizons` electrolytic thorium show a significant increase of H{sub 2} and O{sub 2}, upon remelting with a corresponding increase in the hardness of the metal.

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In a previous study the trimer of rhenium tetracarbonyl was found to be diamagnetic, suggesting the presence of hydrogen in the compound. This was supported by chemical analysis, which indicated about one hydrogen per rhenium, and the compound was formulated as [Re(C0)4H] 3• Subsequently a proton resonance was observed on a broad line spectrometer. In the original work the infrared spectra were compared for the hydride and deuteride; cyclohexane solutions were used for the CO stretching region and KBr discs were used for the rest of the spectrum. Surprisingly, the spectra of the hydride and deuteride showed only minor differences, insufficient to confirm the presence of hydrogen. No evidence of a hydrogen stretching frequency was found. In the present work, the previously unobserved Raman spectra were measured for the hydride and deuteride . In the solid state ratber striking shifts were observed in the CO stretching region. Also there is some evidence for a metal-hydrogen stretching band at the rather low frequency of 1100 cm-1. In an attempt to support the interpretation of the Raman spectra more detailed infrared studies of the solid in KBr discs were made. The hope was to observe a metal-hydrogen stretching frequency and to explain …

To address the {sup 65}Zn contamination issue in the TEF, a multi-task experimental program was initiated. The first experimental task was completed and is reported in Ref. 1. The results of the second experimental task are reported here. This task examined the effect of filter temperature on trapping efficiency and deposit morphology. Based on the first experimental tasks that examined filter pore size and trapping efficiency, stainless steel filter media with a 20 {micro}m pore size was selected. A series of experiments using these filters was conducted during this second task to determine the effect of filter temperature on zinc vapor trapping efficiency, adhesion and morphology. The tests were conducted with the filters heated to 60, 120, and 200 C; the zinc source material was heated to 400 C for all the experiments to provide a consistent zinc source. The samples were evaluated for mass change, deposit adhesion and morphology. As expected from the physical vapor deposition literature, a difference in deposit morphology and appearance was observed between the three filter temperatures. The filter held at 60 C had the largest average mass gain while the 120 and 200 C filters exhibited similar but lower weight gains. The standard deviations …

The Graphite Isotope Ratio Method (GIRM) is a technique used to estimate the total plutonium production in a graphite-moderated reactor. The cumulative plutonium production in that reactor can be accurately determined by measuring neutron irradiation induced isotopic ratio changes in certain impurity elements within the graphite moderator. The method does not require detailed knowledge of a reactor's operating history, although that knowledge can decrease the uncertainty of the production estimate. The basic premise of the Graphite Isotope Ratio Method is that the fluence in non-fuel core components is directly related to the cumulative plutonium production in the nuclear fuel.

Summary of research carried out under Interagency Agreement DE-AI02-07ER64355 with the USDA Forest Service at the Howland Forest AmeriFlux site in central Maine. Includes a list of publications resulting in part or whole from this support.

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The Blake Rhometer operating range was extended from 600 to 1000 deg F and a variable-orifice plugging meter was developed. Both instruments were evaluated in the Atomic Power Development Associates Scdium Technology Loop against weighed or metered contaminants. The loop injection series included: water, hydrogen, carbon monoxide, carbon dioxide, and methane gases; and tea bag injections of sodium carbonate, sodium hydride, sodium hydroxide, and sodium monoxide. Cover gas was monitored and temperature varied during and after each injection run, and the test loop cleaned by cold trapping after each run. A Continuous Hydrogen Monitor attached to the loop cover gas system and a Nickel Diffusion-Tube Hydrogen Monitor connected to the loop proper were evaluated for sensitivity and response. (auth)

Data on the effects of nuclear fuel burnup on dissolution rates and U losses of a few fuel types are summarized. Burnup to the 40% level produced very little effect on the rate of solution of stainless steel-UO/sub 2/ fuel elements in solutions of the Darex type. Beyond passivation, burnup to the 250 Mwd/T level did not produce a large effect on the rate of decladding nor on the U losses in the Sulfex process. Bunnup to the 15% or 4300 Mwd/T level produced little or no effect on the rate of decladding, U losses, or Pu losses in the Zirflex process. Two other effects, air oxidation of irradiated UO/sub 2/ and prolonged contact of this oxide with Sulfex solutions in the absence of actively dissolving stainless steel appeared to be much more serious sources of loss of U. (auth)

In order to establish the feasibility of using two colorimetric met;iods for the determination of uranium interchangeably, according to the interferences encountered in a particular sampte. results were obtained by each of the methods and compared. The dibenzoyl methane method and the ethyl acetate-ammonium thiocyanate procedure were compared on the basis of values secured on the same day. on different days, on an analysis of the variance. and on an analysis of the residual error for the methods on different days. On the basis of the findings of these tests. it is concluded that the two methods can be used interchangeably to determine the uranium content of the ethyl acetate extracts of samples. Since the interferences in the two methods are different. the uranium content of a variety of materials can be determined without additional separations being required. (auth)

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The new sector-focused cyclotrons have more energetic and better focused beams at the extraction radius than do ordinary cyclotrons. While the first characteristic requires a more intense electric field, the second permits this field to extend over a smaller volume. By tailoring the electrode geometry to these characteristics of the beam, the required deflector gap and electrode surface become smaller, and a higher gradient can be held without sparking. A different compromise between radioactivity, power dissipation, and resistance to spark damage must be made in selecting electrode materials. Carefully designed electrostatic deflectors perform very well in sector-focused cyclotrons of intermediate energy. Deflector efficiencies of about 50% and external-beam intensities of 20 {micro}A have been obtained in the Lawrence Laboratory's 88 -Inch Cyclotron.

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The thermal fracture resistance of plutonia Multihundred Watt (MHW) fuel spheres was analyzed assuming boundary conditions of (1) constant heating or cooling rate for the sphere surface, (2) heating or cooling with a constant surface heat transfer coefficient at the sphere surface, and (3) heating or cooling the sphere surface solely by radiation. Thermal damage resistance (mechanical weakening) of MHW spheres was analyzed in terms of the fracture energy and crack system present in the fuel. Using available property data for porous PuO/sub 2/ between 400 and 1200 deg C, and estimating other properties from available data for UO/sub 2/ and ThO/sub 2/ the thermal shock conditions that cause fracture of the fuel sphere were estimated. Experimental values for the tensile fracture strength and the elastic modulus of the fuel as functions of temperature are presently not available and estimates were made of these properties. (auth)

This report was submitted to meet the requirements of Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-26-011. This milestone requires the preparation of an annual report that covers characterization, treatment, storage, minimization, and other aspects of managing land-disposal-restricted mixed waste at the Hanford Facility.

During FY 2001, tank farm operations at Hanford and the Savannah River Site (SRS) continued to be negatively impacted by the unintended formation of solids. At Hanford, the primary solids formation problem involves a series of plugged pipes and pumps during the saltwell pumping activities of the interim stabilization program. For example, transfers of tank S-102 waste were suspended due to a plugged pipeline or a mechanical problem with the transfer pump. The replacement pump then failed within 2 weeks. In contrast, since full-scale waste remediation activities such as vitrification were initiated, the SRS has encountered a wider range of problems due to unwanted solids. The 2H evaporator system was shut down because of the formation of aluminosilicate deposits with enriched uranium in the evaporator pot. While high concentrations of aluminum are expected in the tank waste due to previous canyon operations, the primary source of silicon is the recycle stream from the vitrifier. While solids formation can be expected when waste streams are combined, the formation of the aluminosilicate deposits required an elevated temperature within the evaporator. The shutdown of the 2H evaporator led to a severe shortage of tank space. Therefore, the SRS tank farm was forced to …

Solar One has been instrumented with sensors for weather data system temperatures and pressures, house electrical loads, and photovoltaic system data. An automatic data acquisition and handling system has been designed and installed to gather and then transmit data to a central computer. Programs to summarize these data and tabulate them in convenient forms have been prepared. Initial data have been obtained and analyzed to check the sensor system and to give preliminary performance characteristics of the solar system. (WDM)

The three-dimensional mechanical behavior of thick Spectra/epoxy sonar window materials containing various special materials is summarized in this report. Three different materials, which were fabricated by two companies known as `A` and `B` were received from the Naval Warfare Center. The three materials designated `A with microspheres (A micron),` `A without microspheres (A),` and `B` were measured for all properties. The total number of tests was reduced through the assumption that the two orthogonal, in-place directions were identical. Consequently, these materials should have only six independent elastic variables. The measured constants and strengths are given.

New computational physics methods for estimating constitutive property parameterizations in ground water aquifers were developed and demonstrated in this project. The dynamical and statistical axioms of physics, embodied in partial differential equations (PDES) of kinetic theory, are employed to constrain interpolations of hydraulic head (pressure) and transmissivity (permeability) between sparsely measured datum points. These methods can apparently be applied in numerous approaches to parameter estimation. To demonstrate the basic concepts and techniques developed in this work, examples are considered for steady-state, two-dimensional, heterogeneous, ground water flow models, given (i) discrete borehole observations of hydraulic head and transmissivity and (ii) governing kinetic equations for Darcy flow behavior. Estimations of spatially dependent parameters from sparsely measured data are treated as mathematically ill- posed problems because infinitely many parameter distributions (realizations) that are consistent with the data generally exist. Potential difficulties associated with ill-posedness in mean flow realizations are mitigated by requiring that acceptable realizations respect the observed data, are solutions of forward and inverse PDEs for physical continuity, respect information sampling principles, and are distributed by spatial interpolations that themselves are optimal solutions of the governing PDEs between measured datum points. To accomplish these requisites, adaptive numerical grid Galerkin techniques were applied …

This supporting document has been prepared to make the Kaiser Engineers Hanford Company Project W-320 Tank 106-C Waste Retrieval Study Analysis Session Report readily retrievable. This facilitated session was requested by Westinghouse Hanford Company (WHC) to review the characterization data and select the best alternatives for a double-shell receiver tank and for a sluicing medium for Tank 106-C waste retrieval. The team was composed of WHC and Kaiser Engineers Hanford Company (KEH) personnel knowledgeable about tank farm operations, tank 106-C requirements, tank waste characterization and analysis, and chemical processing. This team was assembled to perform a structured decision analysis evaluation and recommend the best alternative-destination double-shell tank between tanks 101-AY and 102-AY, and the best alternative sluicing medium among dilute complexant (DC), dilute noncomplexant (DNC), and water. The session was facilitated by Richard Harrington and Steve Bork of KEH and was conducted at the Bookwalter Winery in Richland from 7:30 a.m. to 4:00 p.m. from July 27 through July 29, 1993. Attachment 1 (Scope Statement Sheet) identifies the team members, scope, objectives, and deliverables for the session.

Engineering Work Requests ESE-48 & 49 established a program for performance of Qualification Approval Tests on RPC`s 0.2 and 40 meghom Carbon Composition Resistors. This report is an accounting of these tests wherein (50) samples of each component were subjected to QA tests per drawings 8O2C250 and 802C251. Tests are explained and results tabulated.

This report itemizes the irradiations performed by Testing and Irradiation Services for Battelle-Northwest. It lists the material being irradiated, awaiting disposition and material shipped during the report period. Specific data given is TISR No., Request number, Material, Piece number, operating time, CMK Absorbed, charge date, location, exposure to date, discharge date and time, and shipping date.

This study was undertaken at the request of the Hanford Works to investigate the possibility of detecting 3/8 inch diameter boron-steel control-balls which become lodged within cracks between the graphite blocks of an atomic pile. The cracks concerned occur radially from 4 3/16 inch diameter holes which pass vertically through the pile. The problem is complicated by the following facts: The graphite blocks are conducting and will therefore give rise to spurious signals primarily due to the cracks between blocks. Numerous aluminum tubes containing water and bars of uranium pass horizontally through the pile at distances closer to the hole than the ball at its extreme position. The vertical holes themselves are warped in an arbitrary manner. Calculations were made to determine theoretically whether or not the ball could be detected. Best operating frequency and coil design were also determined. Tests were made utilizing a specially designed search coil and a test section of graphite pile. Measurements of particle voltage vs. position relative to the coil were made and compared with that resulting from the graphite.