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Synthesis report on thermally driven coupled processes (open access)

Synthesis report on thermally driven coupled processes

The main purpose of this report is to document observations and data on thermally coupled processes for conditions that are expected to occur within and around a repository at Yucca Mountain. Some attempt is made to summarize values of properties (e.g., thermal properties, hydrologic properties) that can be measured in the laboratory on intact samples of the rock matrix. Variation of these properties with temperature, or with conditions likely to be encountered at elevated temperature in the host rock, is of particular interest. However, the main emphasis of this report is on direct observation of thermally coupled processes at various scales. Direct phenomenological observations are vitally important in developing and testing conceptual models. If the mathematical implementation of a conceptual model predicts a consequence that is not observed, either (1) the parameters or the boundary conditions used in the calculation are incorrect or (2) the conceptual basis of the model does not fit the experiment; in either case, the model must be revised. For example, the effective continuum model that has been used in thermohydrology studies combines matrix and fracture flow in a way that is equivalent to an assumption that water is imbibed instantaneously from fractures into adjacent, partially …
Date: October 15, 1997
Creator: Hardin, E.L.
System: The UNT Digital Library
Improved Oil Recovery in Fluvial Dominated Deltaic Reservoirs of Kansas - Near-Term (open access)

Improved Oil Recovery in Fluvial Dominated Deltaic Reservoirs of Kansas - Near-Term

The objective of this project is to address waterflood problems of the type found in Morrow sandstone reservoirs in southwestern Kansas and in Cherokee Group reservoirs in southeastern Kansas. Two demonstration sites operated by different independent oil operators are involved in this project. The Stewart Field is located in Finney County, Kansas and is operated by North American Resources Company. The Nelson Lease is located in Allen County, Kansas, in the N.E. Savonburg Field and is operated by James E. Russell Petroleum, Inc. General topics to be addressed are 1) reservoir management and performance evaluation, 2) waterflood optimization, and 3) the demonstration of recovery processes involving off-the-shelf technologies which can be used to enhance waterflood recovery, increase reserves, and reduce the abandonment rate of these reservoir types. In the Stewart Project, the reservoir management portion of the project conducted during Budget Period 1 involved performance evaluation. This included 1) reservoir characterization and the development of a reservoir database, 2) volumetric analysis to evaluate production performance, 3) reservoir modeling, 4) laboratory work, 5) identification of operational problems, 6) identification of unrecovered mobile oil and estimation of recovery factors, and 7) identification of the most efficient and economical recovery process. To accomplish …
Date: July 15, 1997
Creator: Walton, A.; Green, Don W.; Whillhite, G. Paul; Schoeling, L.; Watney, L.; Michnick, M. et al.
System: The UNT Digital Library
Quantifying silica reactivity in subsurface environments: Reaction affinity and solute matrix controls on quartz and SiO{sub 2} glass. 1997 annual progress report (open access)

Quantifying silica reactivity in subsurface environments: Reaction affinity and solute matrix controls on quartz and SiO{sub 2} glass. 1997 annual progress report

'The author reports the preliminary results of the experiments on the dissolution behavior of vitreous silica (v-SiO{sub 2}) into aqueous solutions of variable pH and ionic strength. The experiments are being conducted in mixed flow reactors with a high circulation rate that simulates constant-stirred conditions, the efficacy of which the authors discuss below. The preliminary results indicate that v-SiO{sub 2} dissolves into aqueous solutions approximately two orders of magnitude more quickly than crystalline silica (e.g., quartz). With additional experiments, they will utilize the dissolution rate data as a framework for understanding the behavior of waste glass compositions in the subsurface. In other work related to the studies of glass reactivity, the author has written one book chapter that will be published as part of a proceedings for the CEA/VALRHO international nuclear waste disposal conference held in Mejannes le Clap, France. In separate work, she is presently writing a second book chapter for the volume entitled Adsorption on Silica Surfaces.'
Date: October 15, 1997
Creator: Dove, P.M.
System: The UNT Digital Library
Tank characterization report for single-shell tank 241-U-106 (open access)

Tank characterization report for single-shell tank 241-U-106

One major function of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information, are compiled and maintained in a tank characterization report (TCR). This report and its appendixes serve as the TCR for single-shell tank 241-U-106. The objectives of this report are: (1) to use characterization data in response to technical issues associated with tank 241-U-106 waste, and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. Section 2.0 of this report summarizes the response to technical issues, Section 3.0 shows the best-basis inventory estimate, and Section 4.0 makes recommendations regarding safety status and additional sampling. The appendixes contain supporting data and information. This report also supports the requirements of the Hanford Federal Facility Agreement and Consent Order (Ikology et al. 1996), Milestone M-44-10.
Date: April 15, 1997
Creator: Brown, T.M.
System: The UNT Digital Library
Direct Aromaization of Methane (open access)

Direct Aromaization of Methane

The thermal decomposition of methane offers significant potential as a means of producing higher unsaturated and aromatic hydrocarbons when the extent of reaction is limited. Work in the literature previous to this project had shown that cooling the product and reacting gases as the reaction proceeds would significantly reduce or eliminate the formation of solid carbon or heavier (Clo+) materials. This project studied the effect and optimization of the quenching process as a means of increasing the amount of value added products during the pyrolysis of methane. A reactor was designed to rapidly quench the free-radical combustion reaction so as to maximize the yield of aromatics. The use of free-radical generators and catalysts were studied as a means of lowering the reaction temperature. A lower reaction temperature would have the benefits of more rapid quenching as well as a more feasible commercial process due to savings realized in energy and material of construction costs. It was the goal of the project to identify promising routes from methane to higher hydrocarbons based on the pyrolysis of methane.
Date: January 15, 1997
Creator: Marcelin, George
System: The UNT Digital Library
W-026, acceptance test report manipulator system (open access)

W-026, acceptance test report manipulator system

The purpose of the WRAP Manipulator System Acceptance Test Plan (ATP) is to verify that the 4 glovebox sets of WRAP manipulator components, including rail/carriage, slave arm, master controller and auxiliary equipment, meets the requirements of the functional segments of 14590 specification. The demonstration of performance elements of the ATP are performed as a part of the Assembly specifications. Manipulator integration is integrated in the performance testing of the gloveboxes. Each requirement of the Assembly specification will be carried out in conjunction with glovebox performance tests.
Date: April 15, 1997
Creator: Watson, T.L.
System: The UNT Digital Library
The use of dielectric and NMR measurements to determine the pore-scale location of organic contaminants. 1997 annual progress report (open access)

The use of dielectric and NMR measurements to determine the pore-scale location of organic contaminants. 1997 annual progress report

'The objective of the three-year research project is to investigate the effect of adsorbed organics on the dielectric and nuclear magnetic resonance (NMR) response of porous geological materials. This will allow us to assess the use of dielectric and NMR measurements at a site to determine whether organic contaminants are present in the central volume of the pore space (in a water-wet system) or are adsorbed to the solid surface. In addition, the authors propose to use laboratory dielectric and NMR measurements to study the kinetics of the adsorption and desorption of organics by conducting experiments where the authors control temperature and vary fluid chemistry. This project can be divided into three parts: sample preparation, NMR studies, dielectric studies. Over the past nine months the authors have made significant progress in sample preparation and NMR studies. As the plan is to conduct the NMR and dielectric measurements on the same set of samples, the authors delayed the start of the dielectric measurements until the first stage of NMR measurements were complete. Below the authors summarize the progress in sample preparation and NMR measurements, first briefly introducing the method used for the NMR measurements.'
Date: July 15, 1997
Creator: Knight, R.; Bryar, T. & Caputi, M.
System: The UNT Digital Library
FY 1996 cost savings by program (open access)

FY 1996 cost savings by program

In September 1994 the DOE Richland Operations Office (RL) approved the FY 1995 multi-year baseline that included a cost estimate of $1.9 billion for FY 1996. However, Congress only appropriated $1.3 billion for that year. The shortfall of $600 million resulted in a significant challenge to accomplish the required workscope. Therefore, RL initiated an aggressive cost savings program to eliminate the shortfall by deleting workscope that was unnecessary and performing the remaining workscope more efficiently. RL initiated baseline planning actions (including deletions, deferrals, transfers, and additions) during the FY 1996 multi-year baseline development process to match workscope and anticipated funding and identified $205 million of workscope deletions. CFR (Contract Finance and Review Division) then reviewed over 200 cost baseline change requests during FY 1996 and documented an additional $95 million of FY 1996 cost savings. This included $73 million of workscope deletions and $22 million of efficiencies. Total savings as a result of FY 1996 initiatives, including baseline planning actions and current year initiatives, were $300 million. This report contains tables which enumerate the savings realized within each program at Hanford.
Date: August 15, 1997
Creator: Andrews-Smith, K. L.
System: The UNT Digital Library
Office of Inspector General report on audit of controls over the ADP support services contract (open access)

Office of Inspector General report on audit of controls over the ADP support services contract

In March 1995, the Department awarded a cost-plus-award-fee contract to DynCorp valued at approximately $246 million over 5 years for ADP support services at Headquarters. The performance period for the contract was a 3-year base period with two 1-year options. The contract statement of work identified 24 information management functional areas that required technical support services, including Automated Office Systems Support and Local Area Network support. The purpose of the audit was to evaluate the cost-plus-award-fee contract for ADP support services at Headquarters. The objective was to determine whether the Department`s program offices at Headquarters were managing their ADP support services contract costs.
Date: August 15, 1997
Creator: unknown
System: The UNT Digital Library
SAGE II/Umkehr ozone comparisons and aerosols effects: An empirical and theoretical study. Final report (open access)

SAGE II/Umkehr ozone comparisons and aerosols effects: An empirical and theoretical study. Final report

The objectives of this research were to: (1) examine empirically the aerosol effect on Umkehr ozone profiles using SAGE II aerosol and ozone data; (2) examine theoretically the aerosol effect on Umkehr ozone profiles; (3) examine the differences between SAGE II ozone profiles and both old- and new-format Umkehr ozone profiles for ozone-trend information; (4) reexamine SAGE I-Umkehr ozone differences with the most recent version of SAGE I data; and (5) contribute to the SAGE II science team.
Date: September 15, 1997
Creator: Newchurch, M.
System: The UNT Digital Library
Crystal Ball Single Event Display (open access)

Crystal Ball Single Event Display

The Single Event Display (SED) is a routine that is designed to provide information graphically about a triggered event within the Crystal Ball. The SED is written entirely in FORTRAN and uses the CERN-based HICZ graphing package. The primary display shows the amount of energy deposited in each of the NaI crystals on a Mercator-like projection of the crystals. Ten different shades and colors correspond to varying amounts of energy deposited within a crystal. Information about energy clusters is displayed on the crystal map by outlining in red the thirteen (or twelve) crystals contained within a cluster and assigning each cluster a number. Additional information about energy clusters is provided in a series of boxes containing useful data about the energy distribution among the crystals within the cluster. Other information shown on the event display include the event trigger type and data about {pi}{sup o}`s and {eta}`s formed from pairs of clusters as found by the analyzer. A description of the major features is given, along with some information on how to install the SED into the analyzer.
Date: October 15, 1997
Creator: Grosnick, D.; Gibson, A.; Allgower, C. & Alyea, J.
System: The UNT Digital Library
Electric utility applications of hydrogen energy storage systems (open access)

Electric utility applications of hydrogen energy storage systems

This report examines the capital cost associated with various energy storage systems that have been installed for electric utility application. The storage systems considered in this study are Battery Energy Storage (BES), Superconducting Magnetic Energy Storage (SMES) and Flywheel Energy Storage (FES). The report also projects the cost reductions that may be anticipated as these technologies come down the learning curve. This data will serve as a base-line for comparing the cost-effectiveness of hydrogen energy storage (HES) systems in the electric utility sector. Since pumped hydro or compressed air energy storage (CAES) is not particularly suitable for distributed storage, they are not considered in this report. There are no comparable HES systems in existence in the electric utility sector. However, there are numerous studies that have assessed the current and projected cost of hydrogen energy storage system. This report uses such data to compare the cost of HES systems with that of other storage systems in order to draw some conclusions as to the applications and the cost-effectiveness of hydrogen as a electricity storage alternative.
Date: October 15, 1997
Creator: Swaminathan, S. & Sen, R.K.
System: The UNT Digital Library
HIGH SO2 REMOVAL EFFICIENCY TESTING (open access)

HIGH SO2 REMOVAL EFFICIENCY TESTING

This final report describes the results of performance tests at six full-scale wet lime- and limestone-reagent flue gas desulfurization (FGD) systems. The objective of these tests was to evaluate the effectiveness of low capital cost sulfur dioxide (SO{sub 2}) removal upgrades for existing FGD systems as an option for complying with the provisions of the Clean Air Act Amendments of 1990. The upgrade options tested at the limestone-reagent systems included the use of organic acid additives (dibasic acid (DBA) and/or sodium formate) as well as increased reagent ratio (higher excess limestone levels in the recirculating slurry solids) and absorber liquid-to-gas ratio. One system also tested operating at higher flue gas velocities to allow the existing FGD system to treat flue gas from an adjacent, unscrubbed unit. Upgrade options for the one lime-based system tested included increased absorber venturi pressure drop and increased sulfite concentration in the recirculating slurry liquor.
Date: October 15, 1997
Creator: Blythe, Gary M. & Phillips, James L.
System: The UNT Digital Library
Waste compatibility safety issues and final results for tank 241-T-110 push mode samples (open access)

Waste compatibility safety issues and final results for tank 241-T-110 push mode samples

This document is the final laboratory report for Tank 241-T-110. Push mode core segments were removed from risers 2 and 6 between January 29, 1997, and February 7, 1997. Segments were received and extruded at 222-S Laboratory. Analyses were performed in accordance with Tank 241-T-110 Push Mode Core Sampling and analysis Plan (TSAP) and Safety Screening Data Quality Objective (DQO). None of the subsamples submitted for total alpha activity (AT) or differential scanning calorimetry (DSC) analyses exceeded the notification limits stated in DQO.
Date: May 15, 1997
Creator: Nuzum, Jennifer L.
System: The UNT Digital Library
Increased Oil Production and Reserves Utilizing Secondary/Tertiary Recovery Techniques on Small Reservoirs in the Paradox Basin, Utah, Quarterly Report: July-September 1997 (open access)

Increased Oil Production and Reserves Utilizing Secondary/Tertiary Recovery Techniques on Small Reservoirs in the Paradox Basin, Utah, Quarterly Report: July-September 1997

The primary objective of this project is to enhance domestic petroleum production by demonstration and technology transfer of an advanced oil recovery technology in the Paradox basin, southeastern Utah. If this project can demonstrate technical and economic feasibility, the technique can be applied to approximately 100 additional small fields in the Paradox basin alone, and result in increased recovery of 150 to 200 million barrels of oil. This project is designed to characterize five shallow-shelf carbonate reservoirs in the Pennsylvanian (Desmoinesian) Paradox Formation and choose the best candidate for a pilot demonstration project for either a waterflood or carbon dioxide- (CO{sub 2}-) flood project. The field demonstration, monitoring of field performance, and associated validation activities will take place in the Paradox basin within the Navajo Nation. The results of this project will be transferred to industry and other researchers through a petroleum extension service, creation of digital databases for distribution, technical workshops and seminars, field trips, technical presentations at national and regional professional meetings, and publication in newsletters and various technical or trade journals.
Date: October 15, 1997
Creator: Chidsey, Thomas C., Jr.; Lorenz, Douglas M. & Culham, W. E.
System: The UNT Digital Library
The Beam Lifetime and Emittance Growth in RHIC under Normal Operating Conditions and with a Hydrogen Gas Jet (open access)

The Beam Lifetime and Emittance Growth in RHIC under Normal Operating Conditions and with a Hydrogen Gas Jet

This report talks about The Beam Lifetime and Emittance Growth in RHIC under Normal Operating Conditions and with a Hydrogen Gas Jet
Date: October 15, 1997
Creator: D., Trbojevic
System: The UNT Digital Library
Technology development for iron fisher-tropsch catalysis (open access)

Technology development for iron fisher-tropsch catalysis

The goal of the proposed work is the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. the catalyst that is developed will be suitable for testing at the Advanced Fuels Development Facility at LaPorte, Texas or similar sized plant. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the standard-catalyst developed by German workers for slurry phase synthesis, The proposed work will optimize the catalyst composition and pretreatment operation for this low-alpha catalyst. In parallel, work will be conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. the oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studies at the laboratory scale. Catalyst performance will be determined for catalysts synthesized in this program for activity, selectivity, and aging characteristics.
Date: July 15, 1997
Creator: Davis, B. H.
System: The UNT Digital Library
Immigration: The New Affidavit of Support - Questions, Answers, and Issues (open access)

Immigration: The New Affidavit of Support - Questions, Answers, and Issues

Report on the new immigration form issued by the Immigration and Naturalization Service, mostly consisting of a question and answer format.
Date: December 15, 1997
Creator: Vialet, Joyce
System: The UNT Digital Library