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Re-examination of the N2O+O reaction (open access)

Re-examination of the N2O+O reaction

This article is about how the reaction of N20 with O is a key step in consumption of nitrous oxide in thermal processes. In the present work ,the authors re-examined a wide range of experiments relevant for the N2O+O reaction through kinetic modeling, paying attention to the impact of artifacts such as impurities and surface reactions.
Date: July 27, 2023
Creator: Glarborg, Peter; Allingham, Johanne S.; Skov, Alexander B.; Hashemi, Hamid & Marshall, Paul
Object Type: Article
System: The UNT Digital Library
Reactions of hydrazine with the amidogen radical and atomic hydrogen (open access)

Reactions of hydrazine with the amidogen radical and atomic hydrogen

Article describes how the rate coefficient k1 for NH2 + N2H4 was measured to be (5.4 ± 0.4) × 10−14 cm3 molecule−1 s−1 at 296 K. The authors then describe how a combination of experiment and theory leads to a recommended rate coefficient for hydrogen abstraction of k1 = 6.3 × 10−23 T3.44 exp(+289 K/T) cm3 molecule−1 s−1.
Date: June 7, 2023
Creator: Gao, Yide; Alecu, I. M.; Hashemi, Hamid; Glarborg, Peter & Marshall, Paul
Object Type: Article
System: The UNT Digital Library
Probing High-Temperature Amine Chemistry: Is the Reaction NH3 + NH2 ⇄ N2H3 + H2 Important? (open access)

Probing High-Temperature Amine Chemistry: Is the Reaction NH3 + NH2 ⇄ N2H3 + H2 Important?

Article describes how the reaction NH3 + NH2 ⇄ N2H3 + H2 (R1) has been identified as a key step to explain experimental results for pyrolysis and oxidation of ammonia. In the present work, the reaction was studied by ab initio theory and by reinterpretation of experimental data.
Date: March 14, 2023
Creator: Marshall, Paul & Glarborg, Peter
Object Type: Article
System: The UNT Digital Library
Measurement of the Intramolecular Hydrogen-Shift Rate Coefficient for the CH3SCH2OO Radical Between 314 and 433 K (open access)

Measurement of the Intramolecular Hydrogen-Shift Rate Coefficient for the CH3SCH2OO Radical Between 314 and 433 K

Article describes how the intramolecular hydrogen-shift rate coefficient of the CH3SCH2O2 (methylthiomethylperoxy, MSP) radical, a product formed in the oxidation of dimethyl sulfide (DMS), was measured using a pulsed laser photolysis flow tube reactor coupled to a high-resolution time-of-flight chemical ionization mass spectrometer that measured the formation of the DMS degradation end product HOOCH2SCHO. Measurements performed over the temperature range of 314–433 K yielded a hydrogen-shift rate coefficient of k1(T) = (2.39 ± 0.7) × 109 exp(−(7278 ± 99)/T) s–1 Arrhenius expression and a value extrapolated to 298 K of 0.06 s–1.
Date: March 2, 2023
Creator: Assaf, Emmanuel; Finewax, Zachary; Marshall, Paul; Veres, Patrick R.; Neuman, Andrew & Burkholder, James B. (James Bart), 1954-
Object Type: Article
System: The UNT Digital Library
Re-evaluation of rate constants for the reaction N2H4 (+ M) ⇄ NH2 + NH2 (+ M) (open access)

Re-evaluation of rate constants for the reaction N2H4 (+ M) ⇄ NH2 + NH2 (+ M)

Article describes how rate constants for the dissociation/recombination reaction N2H4 (+ M) ⇄ NH2 + NH2 (+ M) are determined by a combination of quantum-chemical calculations and statistical unimolecular rate theory. Implications of the present re-evaluated rate constants for the modeling of high temperature ammonia oxidation kinetics are discussed, showing an only small influence of their precise values on the overall properties of the process.
Date: October 4, 2023
Creator: Cobos, Carlos J.; Glarborg, Peter; Marshall, Paul & Troe, Jürgen
Object Type: Article
System: The UNT Digital Library
Experimental and Modeling Study of Water Time Histories during H2S-N2O Combustion in a Shock Tube (open access)

Experimental and Modeling Study of Water Time Histories during H2S-N2O Combustion in a Shock Tube

Article describes how, in the present study, the water formation was followed by laser absorption with N2O as an oxidant, instead of O2. Three H2S/N2O mixtures diluted in 98% Ar were studied to cover the following range of equivalence ratios: 0.5, 1.0, and 2.0, over a wide range of temperatures (1580–1940 K) around atmospheric pressure.
Date: June 7, 2023
Creator: Cooper, Sean P.; Marshall, Paul; Mathieu, Olivier; Pinzón, Laura T.; Mulvihill, Clayton R. & Glarborg, Peter
Object Type: Article
System: The UNT Digital Library
Dublin Core Metadata Created by Kuwaiti Students: Exploration of Quality in Context (open access)

Dublin Core Metadata Created by Kuwaiti Students: Exploration of Quality in Context

Conference paper reporting results of the examination of metadata records for Arabic-language eBooks to support ongoing metadata education in the Arabian Gulf region. The results are presented in-context, after introducing the metadata teaching practices at this undergraduate program, and the major Dublin Core skill-building assignment. This is a manuscript version of a published work. Citation information is available for the published version of the work.
Date: March 10, 2023
Creator: Aljalahmah, Saleh & Zavalina, Oksana
Object Type: Article
System: The UNT Digital Library
Exploration of Accuracy, Completeness and Consistency in Metadata for Physical Objects in Museum Collections (open access)

Exploration of Accuracy, Completeness and Consistency in Metadata for Physical Objects in Museum Collections

Conference paper for an exploratory study that examined student-created metadata for physical non-text resources. The authors applied in-depth qualitative and quantitative content analysis to the Dublin Core (DCTERMS) metadata created by the graduate students in two sections of an introductory digital library metadata course. Finding of comparative analysis for the asynchronous course section and the section with synchronous class meetings are also presented. Implications are discussed, along with future directions for research. This is a manuscript version of a published work. Citation information is available for the published version of the
Date: March 10, 2023
Creator: Zavalin, Vyacheslav & Zavalina, Oksana
Object Type: Article
System: The UNT Digital Library

Beavers Ben Folk Festival and Craft Show Advertisement

Photograph of the Beavers Ben Folk Festival and Craft Show advertisement.
Date: 2023-11-10/2023-11-12
Creator: unknown
Object Type: Photograph
System: The Gateway to Oklahoma History

Beavers Ben Folk Festival and Craft Show Advertisement

Photograph of the Beavers Ben Folk Festival and Craft Show advertisement.
Date: 2023-11-10/2023-11-12
Creator: unknown
Object Type: Photograph
System: The Gateway to Oklahoma History
Hellcat News (Garnet Valley, Pa.), Vol. 77, No. 4, Ed. 1 Friday, December 1, 2023 (open access)

Hellcat News (Garnet Valley, Pa.), Vol. 77, No. 4, Ed. 1 Friday, December 1, 2023

Monthly newsletter published by the 12th Armored Division Association, discussing news related to the activities of the U.S. Army unit and updates on previous members of the division.
Date: December 1, 2023
Creator: Twelfth Armored Division Association (U.S.)
Object Type: Newspaper
System: The Portal to Texas History
Hellcat News (Garnet Valley, Pa.), Vol. 77, No. 3, Ed. 1 Wednesday, November 1, 2023 (open access)

Hellcat News (Garnet Valley, Pa.), Vol. 77, No. 3, Ed. 1 Wednesday, November 1, 2023

Monthly newsletter published by the 12th Armored Division Association, discussing news related to the activities of the U.S. Army unit and updates on previous members of the division.
Date: November 1, 2023
Creator: Twelfth Armored Division Association (U.S.)
Object Type: Newspaper
System: The Portal to Texas History
Hellcat News (Garnet Valley, Pa.), Vol. 77, No. 2, Ed. 1 Sunday, October 1, 2023 (open access)

Hellcat News (Garnet Valley, Pa.), Vol. 77, No. 2, Ed. 1 Sunday, October 1, 2023

Monthly newsletter published by the 12th Armored Division Association, discussing news related to the activities of the U.S. Army unit and updates on previous members of the division.
Date: October 1, 2023
Creator: Twelfth Armored Division Association (U.S.)
Object Type: Newspaper
System: The Portal to Texas History
Hellcat News (Garnet Valley, Pa.), Vol. 77, No. 1, Ed. 1 Friday, September 1, 2023 (open access)

Hellcat News (Garnet Valley, Pa.), Vol. 77, No. 1, Ed. 1 Friday, September 1, 2023

Monthly newsletter published by the 12th Armored Division Association, discussing news related to the activities of the U.S. Army unit and updates on previous members of the division.
Date: September 1, 2023
Creator: Twelfth Armored Division Association (U.S.)
Object Type: Newspaper
System: The Portal to Texas History
Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 12, Ed. 1 Tuesday, August 1, 2023 (open access)

Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 12, Ed. 1 Tuesday, August 1, 2023

Monthly newsletter published by the 12th Armored Division Association, discussing news related to the activities of the U.S. Army unit and updates on previous members of the division.
Date: August 1, 2023
Creator: Twelfth Armored Division Association (U.S.)
Object Type: Newspaper
System: The Portal to Texas History
Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 11, Ed. 1 Saturday, July 1, 2023 (open access)

Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 11, Ed. 1 Saturday, July 1, 2023

Monthly newsletter published by the 12th Armored Division Association, discussing news related to the activities of the U.S. Army unit and updates on previous members of the division.
Date: July 1, 2023
Creator: Twelfth Armored Division Association (U.S.)
Object Type: Newspaper
System: The Portal to Texas History
Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 10, Ed. 1 Thursday, June 1, 2023 (open access)

Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 10, Ed. 1 Thursday, June 1, 2023

Monthly newsletter published by the 12th Armored Division Association, discussing news related to the activities of the U.S. Army unit and updates on previous members of the division.
Date: June 1, 2023
Creator: Twelfth Armored Division Association (U.S.)
Object Type: Newspaper
System: The Portal to Texas History
Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 9, Ed. 1 Monday, May 1, 2023 (open access)

Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 9, Ed. 1 Monday, May 1, 2023

Monthly newsletter published by the 12th Armored Division Association, discussing news related to the activities of the U.S. Army unit and updates on previous members of the division.
Date: May 1, 2023
Creator: Twelfth Armored Division Association (U.S.)
Object Type: Newspaper
System: The Portal to Texas History
Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 8, Ed. 1 Saturday, April 1, 2023 (open access)

Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 8, Ed. 1 Saturday, April 1, 2023

Monthly newsletter published by the 12th Armored Division Association, discussing news related to the activities of the U.S. Army unit and updates on previous members of the division.
Date: April 1, 2023
Creator: Twelfth Armored Division Association (U.S.)
Object Type: Newspaper
System: The Portal to Texas History
Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 5, Ed. 1 Sunday, January 1, 2023 (open access)

Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 5, Ed. 1 Sunday, January 1, 2023

Monthly newsletter published by the 12th Armored Division Association, discussing news related to the activities of the U.S. Army unit and updates on previous members of the division.
Date: January 1, 2023
Creator: Twelfth Armored Division Association (U.S.)
Object Type: Newspaper
System: The Portal to Texas History
Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 6, Ed. 1 Wednesday, February 1, 2023 (open access)

Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 6, Ed. 1 Wednesday, February 1, 2023

Monthly newsletter published by the 12th Armored Division Association, discussing news related to the activities of the U.S. Army unit and updates on previous members of the division.
Date: February 1, 2023
Creator: Twelfth Armored Division Association (U.S.)
Object Type: Newspaper
System: The Portal to Texas History
Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 7, Ed. 1 Wednesday, March 1, 2023 (open access)

Hellcat News (Garnet Valley, Pa.), Vol. 76, No. 7, Ed. 1 Wednesday, March 1, 2023

Monthly newsletter published by the 12th Armored Division Association, discussing news related to the activities of the U.S. Army unit and updates on previous members of the division.
Date: March 1, 2023
Creator: Twelfth Armored Division Association (U.S.)
Object Type: Newspaper
System: The Portal to Texas History

[An ensemble by Missoni]

Photograph of an ensemble by Missoni from the UNT Texas Fashion Collection's permanent collection, mounted in the Neiman Marcus Hub space in Oaklawn in Dallas for the opening of the space.
Date: February 1, 2024
Creator: Becker, Annette
Object Type: Photograph
System: The UNT Digital Library

[Shoes mounted with board and foam sitting on shelves, 2]

Photograph of rows of shoes mounted with board and foam sitting on shelves in the UNT Gloria and Bruzzy Westheimer Texas Fashion Collection Research Gallery in ART 259.
Date: February 1, 2024
Creator: Becker, Annette
Object Type: Photograph
System: The UNT Digital Library