Periodic supplement for "the regular journals of the American Chemical Society," containing annotated bibliographies of chemical documentation literature as well as information about meetings, conferences, awards, scholarships, and other news from the American Chemical Society (ACS) Division of Chemical Literature.

This publication of the Dallas-Fort Worth Section of the American Chemical Society includes information about research, prominent scientist, organizational business, and various other stories of interest to the community.

Periodic supplement for "the regular journals of the American Chemical Society," containing annotated bibliographies of chemical documentation literature as well as information about meetings, conferences, awards, scholarships, and other news from the American Chemical Society (ACS) Division of Chemical Literature.

Nanoporous low-k dielectrics are used for integrated circuit interconnects to reduce the propagation delays, and cross talk noise between metal wires as an alternative material for SiO2. These materials, typically organosilicate glass (OSG) films, are exposed to oxygen plasmas during photoresist stripping and related processes which substantially damage the film by abstracting carbon, incorporating O and OH, eventually leading to significantly increased k values. Systematic studies have been performed to understand the oxygen plasma-induced damage mechanisms on different low-k OSG films of various porosity and pore interconnectedness. Fourier transform infrared spectroscopy, x-ray photoelectron spectroscopy and atomic force microscopy are used to understand the damage kinetics of O radicals, ultraviolet photons and charged species, and possible ways to control the carbon loss from the film. FTIR results demonstrate that O radical present in the plasma is primarily responsible for carbon abstraction and this is governed by diffusion mechanism involving interconnected film nanopores. The loss of carbon from the film can be controlled by closing the pore interconnections, He plasma pretreatment is an effective way to control the damage at longer exposure by closing the connections between the pores.

The design and fabrication of a novel soft landing instrument Soft Landing Ion Mobility (SLIM) is described here. Topics covered include history of soft landing, gas phase mobility theory, the design and fabrication of SLIM, as well as applications pertaining to soft landing. Principle applications devised for this instrument involved the gas phase separation and selection of an ionized component from a multicomponent gas phase mixture as combing technique to optimize coatings, catalyst, and a variety of alternative application in the sciences.

Events that occur early in the life of birds greatly influence social and sexual preferences throughout the course of life. Traditionally, this is explained by a learning process known as imprinting. Young birds are thought to imprint to early stimuli, causing the development of permanent preferences for those stimuli. In the present study, imprinting is examined with respect to behaviors of an adult human-reared pigeon in several conditions. The subject was either presented with no stimulus, a conspecific stimulus, a novel stimulus, a human stimulus, or the human and novel stimuli simultaneously. Several phases within these conditions were employed to pinpoint the variables that produced the most social and sexual behavior. The results showed that while some conditions produced unclear behavior, other conditions produced very clear indications of sexual preference for humans and fear of conspecifics. The results suggest that the concept of imprinting may not be needed to explain the sexual preference of the subject, and that operant contingencies may play a large role in sexual behavior.

This publication of the Dallas-Fort Worth Section of the American Chemical Society includes information about research, prominent scientist, organizational business, and various other stories of interest to the community.

The primary focus of this study is to investigate the effects of social control mechanisms on public order crimes in Turkey. Supporting efforts of parochial control is a rising trend in crime control activities. Statements regarding the relationship between social disorganization variables, parochial control variables, and spatial distribution of crime have long been studied by researchers. Using the same assumptions in this study, I test their applicability to public order crimes in Turkey. The poverty and residential mobility variables had significant positive effect on public order crimes holding other structural and parochial variables constant. The number of public order crimes seems to be higher in provinces where there are more disrupted families. The number of public order crimes seems to be lower in provinces where there are more religious institutions. Overall, the results reveal that social structural variables and parochial control factors affect the institutional bases of provinces and partly affect the occurrence of public order crimes. Based on the study findings, several policy implications and recommendations for future research are suggested.

Copper(I) complexes have been studied through both experimental and computational means in the presented work. Overall, the work focuses on photophysical and photochemical properties of copper(I) complexes. Photophysical and photochemical properties are found to be dependent on the geometries of the copper(I) complexes. One of the geometric properties that are important for both photochemical and photophysical properties is coordination number. Coordination numbers have been observed to be dependent on both ligand size and recrystallization conditions. The complexes geometric structure, as well as the electronic effects of the coordination ligands, is shown both computationally as well as experimentally to affect the emission energies. Two-coordinate complexes are seen to have only weak emission at liquid nitrogen temperature (77 K), while at room temperature (298 K) the two-coordinate complexes are not observed to be luminescent. Three-coordinate complexes are observed to be luminescent at liquid nitrogen temperature as well as at room temperature. The three-coordinate complexes have a Y-shaped ground (S0) state that distorts towards a T-shape upon photoexcitation to the lowest lying phosphorescent state (T1). The geometric distortion is tunable by size of the coordinating ligand. Luminescence is controllable by limiting the amount of non-radiative emission. One manner by which non-radiative emission is …

Semi-weekly newspaper from Flower Mound, Texas that includes local, state, and national news along with advertising.

Quarterly publication of the Alpha Chi Sigma chemistry fraternity containing articles related to chemistry research and the activities of the organization, including local chapters and groups.

This analysis of faunal remains from Goodman Point Pueblo (5MT604), a large village occupied just before the ancestral Puebloans permanently left southwestern Colorado at the end of the thirteenth century, explores the effect of dietary stress during abandonment in the Four Corners region. As archaeologists, we interpret what these former cultures were like and what resources they used through what they left behind. By specifically looking at faunal remains, or remains from food resources, environmental change and dietary stress can be assessed. Identifications of taxa identified at Goodman Point are made explicit via a systematic paleontology. This is followed by site-level taxonomic abundances and spatial analysis. Then, effects of technological innovations, environmental change, and sample quality are examined as alternate explanations of shifts in foraging efficiency, particularly related to animal hunting. Analyzing why and if the availability of faunal resources changes over time helps to clarify why the ancestral Puebloans left southwestern Colorado.

The recent growth in sensor technology allows easier information gathering in real-time as sensors have grown smaller, more accurate, and less expensive. The resulting data is often in a geo-stream format continuously changing input with a spatial extent. Researchers developing geo-streaming management systems (GSMS) require a benchmark system for evaluation, which is currently lacking. This thesis presents GSMark, a benchmark for evaluating GSMSs. GSMark provides a data generator that creates a combination of synthetic and real geo-streaming data, a workload simulator to present the data to the GSMS as a data stream, and a set of benchmark queries that evaluate typical GSMS functionality and query performance. In particular, GSMark generates both moving points and evolving spatial regions, two fundamental data types for a broad range of geo-stream applications, and the geo-streaming queries on this data.

I obtained 182 session graphs from 10 client records from a university-based neurotherapy clinic and from a private practitioner. These graphs were used to examine the relationship of therapeutic crossover activity (defined as at least 3 minutes in duration and at least 1μv in amplitude) with and without predetermined amplitude thresholds of beta (15-20Hz) to client reports of imagery and to treatment outcomes. Crosstab analysis revealed that significantly more reports of imagery were observed in the therapeutic crossover with beta condition and that higher amplitudes of slower brainwave activity correlated with progression to deeper states of consciousness. Multi-level modeling revealed a significant interaction between therapeutic crossover activity, higher beta frequency amplitude, and reported salient imagery. Due to small sample size, significance testing was not deemed appropriate. However, observation in change of pre-post scores suggested that individuals who experienced more therapeutic crossover with sufficient beta amplitude conditions had greater improvements on post-test measures (BAI, BDI, BHS, PSQI and MMPI) than those with no or few crossovers. Higher amplitudes of slower brainwave activity correlated with progression to deeper states of consciousness, with delta amplitude positively correlating with transpersonal states. Reports of imagery and/or biographical memory are much more likely to occur during …

A study was conducted to investigate the relationships between cybergaming treatment groups and the control group (N = 99: ncontrol = 8; nlogic = 29; nspatial = 30; ncombination = 32) with success in the organic chemistry I course as measured by achievement over a 10-week period. The treatment groups included logic training, spatial training, and combination logic-spatial training. Students' ability was measured by pre/post exams using the Group Assessment of Logical Thinking (GALT) to measure logic ability, Purdue Visualizations of Rotations (ROT) test to measure spatial skills, and the General-Organic-Biochemistry (GOB) Exam to measure content attainment. Finally, students' responses about participation in this experience were evaluated using open- and closed-ended questions on a self-developed survey. A second study was conducted to evaluate the relationship between the cybergaming treatment and control groups (N = 88: nexperimental = 27; ncontrol = 61) with success in the general chemistry I course as measured by achievement and final course averages and grades. The cybergaming treatment group underwent intensive combination logic-spatial training for 10 weeks. Students' progress was measured using three pre/post instruments: Group Assessment of Logical Thinking (GALT) measured logic ability, Purdue Visualizations of Rotations (ROT) Test measured spatial skills, and the California …

Coarse-grained fabrics are comprised of multi-bit configurable logic blocks and configurable interconnect. This work is focused on area and energy optimization techniques for coarse-grained reconfigurable fabric architectures. In this work, a variety of design techniques have been explored to improve the utilization of computational resources and increase energy savings. This includes splitting, folding, multi-level vertical interconnect. In addition to this, I have also studied fully connected homogeneous and heterogeneous architectures, and 3D architecture. I have also examined some of the hybrid strategies of computation unit’s arrangements. In order to perform energy and area analysis, I selected a set of signal and image processing benchmarks from MediaBench suite. I implemented various fabric architectures on 90nm ASIC process from Synopsys. Results show area improvement with energy savings as compared to baseline architecture.

Weekly newspaper from Yorktown, Texas that includes local, state and national news along with advertising.

Weekly newspaper from Yorktown, Texas that includes local, state and national news along with advertising.

Weekly newspaper from Yorktown, Texas that includes local, state and national news along with advertising.

Weekly newspaper from Yorktown, Texas that includes local, state and national news along with advertising.

Weekly newspaper from Yorktown, Texas that includes local, state and national news along with advertising.

Weekly newspaper from Yorktown, Texas that includes local, state and national news along with advertising.

Weekly newspaper from Yorktown, Texas that includes local, state and national news along with advertising.

Weekly newspaper from Yorktown, Texas that includes local, state and national news along with advertising.