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A Study of Silver: an Alternative Maldi Matrix for Low Weight Compounds and Mass Spectrometry Imaging (open access)

A Study of Silver: an Alternative Maldi Matrix for Low Weight Compounds and Mass Spectrometry Imaging

Soft-landing ion mobility has applicability in a variety of areas. The ability to produce material and collect a sufficient amount for further analysis and applications is the key goal of this technique. Soft-landing ion mobility has provided a way to deposit material in a controllable fashion, and can be tailored to specific applications. Changing the conditions at which soft-landing ion mobility occurs effects the characteristics of the resulting particles (size, distribution/coverage on the surface). Longer deposition times generated more material on the surface; however, higher pressures increased material loss due to diffusion. Larger particles were landed when using higher pressures, and increased laser energy at ablation. The utilization of this technique for the deposition of silver clusters has provided a solvent free matrix application technique for MALDI-MS. The low kinetic energy of incident ions along with the solvent free nature of soft-landing ion mobility lead to a technique capable of imaging sensitive samples and low mass analysis. The lack of significant interference as seen by traditional organic matrices is avoided with the use of metallic particles, providing a major enhancement in the ability to analyze low mass compounds by MALDI.
Date: May 2014
Creator: Walton, Barbara Lynn
Object Type: Thesis or Dissertation
System: The UNT Digital Library
The Cuero Record (Cuero, Tex.), Vol. 120, No. 16, Ed. 1 Wednesday, April 16, 2014 (open access)

The Cuero Record (Cuero, Tex.), Vol. 120, No. 16, Ed. 1 Wednesday, April 16, 2014

Weekly newspaper from Cuero, Texas that includes local, state and national news along with advertising.
Date: April 16, 2014
Creator: Rea, Glenn
Object Type: Newspaper
System: The Portal to Texas History
Design Space Exploration of Domain Specific CGRAs Using Crowd-sourcing (open access)

Design Space Exploration of Domain Specific CGRAs Using Crowd-sourcing

CGRAs (coarse grained reconfigurable array architectures) try to fill the gap between FPGAs and ASICs. Over three decades, the research towards CGRA design has produced number of architectures. Each of these designs lie at different points on a line drawn between FPGAs and ASICs, depending on the tradeoffs and design choices made during the design of architectures. Thus, design space exploration (DSE) takes a very important role in the circuit design process. In this work I propose the design space exploration of CGRAs can be done quickly and efficiently through crowd-sourcing and a game driven approach based on an interactive mapping game UNTANGLED and a design environment called SmartBricks. Both UNTANGLED and SmartBricks have been developed by our research team at Reconfigurable Computing Lab, UNT. I present the results of design space exploration of domain-specific reconfigurable architectures and compare the results comparing stripe vs mesh style, heterogeneous vs homogeneous. I also compare the results obtained from different interconnection topologies in mesh. These results show that this approach offers quick DSE for designers and also provides low power architectures for a suite of benchmarks. All results were obtained using standard cell ASICs with 90 nm process.
Date: August 2014
Creator: Sistla, Anil Kumar
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Southwest Retort, Volume 66, Number 6, February 2014 (open access)

Southwest Retort, Volume 66, Number 6, February 2014

This publication of the Dallas-Fort Worth Section of the American Chemical Society includes information about research, prominent scientist, organizational business, and various other stories of interest to the community.
Date: February 2014
Creator: American Chemical Society. Dallas/Fort Worth Section.
Object Type: Journal/Magazine/Newsletter
System: The UNT Digital Library
Synthesis and Characterization of Dimethylbis(2-pyridyl)borate Nickel(II) Complexes: Unimolecular Square-Planar to Square-Planar Rotation around Nickel(II) (open access)

Synthesis and Characterization of Dimethylbis(2-pyridyl)borate Nickel(II) Complexes: Unimolecular Square-Planar to Square-Planar Rotation around Nickel(II)

This article reports the synthesis, characterization, and solution dynamics of the novel nickel(II) complexes (dimethylbis(2-pyridyl)borate)(triphenylphosphine)nickel(II) chloride (4) and (dimethylbis(2-pyridyl)borate)nickel(II) acetylacetonate (6).
Date: April 7, 2014
Creator: Celaje, Jeff A.; Pennington-Boggio, Megan K.; Flaig, Robinson W.; Richmond, Michael G. & Williams, Travis J.
Object Type: Article
System: The UNT Digital Library
Meta-discoveries from a synthesis of satellite-based land-cover mapping research (open access)

Meta-discoveries from a synthesis of satellite-based land-cover mapping research

This article provides a spatialized database of scientific literature in English about land-cover mapping.
Date: June 19, 2014
Creator: Yu, Le; Liang, Lu; Wang, Jie; Zhao, Yuanyuan; Cheng, Qu; Hu, Luanyun et al.
Object Type: Article
System: The UNT Digital Library
The North Texan, Volume 64, Number 4, Winter 2014 (open access)

The North Texan, Volume 64, Number 4, Winter 2014

The North Texan includes articles and notes about University of North Texas students, faculty, and alumni activities.
Date: Winter 2014
Creator: University of North Texas. Division of University Relations, Communications and Marketing.
Object Type: Journal/Magazine/Newsletter
System: The UNT Digital Library
Archer County News (Archer City, Tex.), Vol. 106, No. 49, Ed. 1 Thursday, December 4, 2014 (open access)

Archer County News (Archer City, Tex.), Vol. 106, No. 49, Ed. 1 Thursday, December 4, 2014

Weekly newspaper from Archer City, Texas that includes local, state and national news along with advertising.
Date: December 4, 2014
Creator: Phillips, Barbara
Object Type: Newspaper
System: The Portal to Texas History
The Hexagon, Volume 105, Number 4, Winter 2014 (open access)

The Hexagon, Volume 105, Number 4, Winter 2014

Quarterly publication of the Alpha Chi Sigma chemistry fraternity containing articles related to chemistry research and the activities of the organization, including local chapters and groups.
Date: Winter 2014
Creator: Alpha Chi Sigma
Object Type: Journal/Magazine/Newsletter
System: The UNT Digital Library
Rediscovery of the Elements: Joseph Black. Magnesia and Fixed Air (open access)

Rediscovery of the Elements: Joseph Black. Magnesia and Fixed Air

Article describing Joseph Black and his discovery of magnesia and fixed air. The authors toured Edinburgh, Scotland in search of locations important to Black, providing the reader with maps and historical information regarding the sites.
Date: Autumn 2014
Creator: Marshall, James L., 1940- & Marshall, Virginia R.
Object Type: Article
System: The UNT Digital Library
Texas Parks & Wildlife, Volume 72, Number 7, August/September 2014 (open access)

Texas Parks & Wildlife, Volume 72, Number 7, August/September 2014

Monthly magazine discussing natural resources, parks, hunting and fishing, and other information related to the outdoors in Texas.
Date: September 2014
Creator: Texas. Parks and Wildlife Department.
Object Type: Journal/Magazine/Newsletter
System: The Portal to Texas History
The Effect of Plasma on Silicon Nitride, Oxynitride and Other Metals for Enhanced Epoxy Adhesion for Packaging Applications (open access)

The Effect of Plasma on Silicon Nitride, Oxynitride and Other Metals for Enhanced Epoxy Adhesion for Packaging Applications

The effects of direct plasma chemistries on carbon removal from silicon nitride (SiNx) and oxynitride (SiOxNy ) surfaces and Cu have been studied by x-photoelectron spectroscopy (XPS) and ex-situ contact angle measurements. The data indicate that O2,NH3 and He capacitively coupled plasmas are effective at removing adventitious carbon from silicon nitride (SiNx) and Silicon oxynitride (SiOxNy ) surfaces. O2plasma and He plasma treatment results in the formation of silica overlayer. In contrast, the exposure to NH3 plasma results in negligible additional oxidation of the SiNx and SiOxNy surface. Ex-situ contact angle measurements show that SiNx and SiOxNy surfaces when exposed to oxygen plasma are initially more hydrophilic than surfaces exposed to NH3 plasma and He plasma, indicating that the O2 plasma-induced SiO2 overlayer is highly reactive towards ambient corresponding to increased roughness measured by AFM. At longer ambient exposures (>~10 hours), however surfaces treated by either O2, He or NH3 plasma exhibit similar steady state contact angles, correlated with rapid uptake of adventitious carbon, as determined by XPS. Surface passivation by exposure to molecular hydrogen prior to ambient exposure significantly retards the increase in the contact angle upon the exposure to ambient. The results suggest a practical route to enhancing …
Date: August 2014
Creator: Gaddam, Sneha Sen
Object Type: Thesis or Dissertation
System: The UNT Digital Library
The Altus Times (Altus, Okla.), Vol. 115, No. 10, Ed. 1 Tuesday, May 13, 2014 (open access)

The Altus Times (Altus, Okla.), Vol. 115, No. 10, Ed. 1 Tuesday, May 13, 2014

Daily newspaper from Altus, Oklahoma that includes local, state, and national news along with advertising.
Date: May 13, 2014
Creator: Bush, Michael
Object Type: Newspaper
System: The Gateway to Oklahoma History
Epigenetics as a Source of Variation in Comparative Animal Physiology - or - Lamarck Is Lookin' Pretty Good These Days (open access)

Epigenetics as a Source of Variation in Comparative Animal Physiology - or - Lamarck Is Lookin' Pretty Good These Days

This article discusses the ecological and and evolutionary significance of such epigenetic inheritance in a comparative physiological context, and provides a number of caveats and warnings regarding the interpretation of transgenerational phenotype modification as a true epigenetic phenomenon.
Date: February 26, 2014
Creator: Burggren, Warren W.
Object Type: Article
System: The UNT Digital Library
Blinn College Request for Legislative Appropriations for Fiscal Years 2016 and 2017 (open access)

Blinn College Request for Legislative Appropriations for Fiscal Years 2016 and 2017

Request for funding by legislative appropriations by Blinn College for FY 2016-2017, submitted to the Governor's Office of Budget, Planning and Policy and the Legislative Budget Board.
Date: August 4, 2014
Creator: Blinn College
Object Type: Legislative Document
System: The Portal to Texas History
Latino Attitudes Toward Abortion and Marriage Equality: Examining the Influence of Religiosity, Acculturation, and Non-Response (open access)

Latino Attitudes Toward Abortion and Marriage Equality: Examining the Influence of Religiosity, Acculturation, and Non-Response

This article seeks to extend literature on Latinos' policy preferences by examining the influence of multiple dimensions of acculturation and religiosity on two contemporary moral policy issues: abortion and same-sex marriage.
Date: 2014
Creator: Branton, Regina; Franco, Ana B.; Wenzel, Jim & Wrinkle, Robert D.
Object Type: Article
System: The UNT Digital Library
The Cuero Record (Cuero, Tex.), Vol. 120, No. 20, Ed. 1 Wednesday, May 14, 2014 (open access)

The Cuero Record (Cuero, Tex.), Vol. 120, No. 20, Ed. 1 Wednesday, May 14, 2014

Weekly newspaper from Cuero, Texas that includes local, state and national news along with advertising.
Date: May 14, 2014
Creator: Rea, Glenn
Object Type: Newspaper
System: The Portal to Texas History
Yorktown News-View (Yorktown, Tex.), Vol. 122, No. 46, Ed. 1 Wednesday, June 4, 2014 (open access)

Yorktown News-View (Yorktown, Tex.), Vol. 122, No. 46, Ed. 1 Wednesday, June 4, 2014

Weekly newspaper from Yorktown, Texas that includes local, state and national news along with advertising.
Date: June 4, 2014
Creator: unknown
Object Type: Newspaper
System: The Portal to Texas History
Guidelines for the standardization of preanalytic variables for blood‐based biomarker studies in Alzheimer's disease research (open access)

Guidelines for the standardization of preanalytic variables for blood‐based biomarker studies in Alzheimer's disease research

Review article which provides (1) a synopsis of selected preanalytical methods utilized in many international AD cohort studies, (2) initial draft guidelines/SOPs for preanalytical methods, and (3) a list of required methodological information and protocols to be made available for publications in the field to foster cross‐validation across cohorts and laboratories.
Date: September 30, 2014
Creator: O'Bryant, Sid E.; Gupta, Veer; Henriksen, Kim; Edwards, Melissa; Jeromin, Andreas; Lista, Simone et al.
Object Type: Article
System: The UNT Digital Library
Final Technical Report for grant entitled "New Horizons in C-F Activation by Main Group Electrophiles" (open access)

Final Technical Report for grant entitled "New Horizons in C-F Activation by Main Group Electrophiles"

We became interested in developing new methods for hydrodefluorination (HDF) and other types of C-F bond conversion in polyfluoroalkanes under mild conditions. We were attracted to an approach to C-F activation, where the key C-F cleavage proceeds by a Lewis acid abstraction of fluoride rather than a redox event. The efforts during the previous period were aimed at a) advancing the HDF reactivity with improvement in scope and catalyst longevity; b) extending C-F activation beyond HDF; c) generating insight about the elementary steps of the reaction and potential intermediates.
Date: January 16, 2014
Creator: Ozerov, Oleg V & Ozerov, Oleg V.
Object Type: Report
System: The UNT Digital Library
Low neutral genetic diversity in isolated Greater Sage-Grouse (Centrocercus urophasianus) populations in northwest Wyoming (open access)

Low neutral genetic diversity in isolated Greater Sage-Grouse (Centrocercus urophasianus) populations in northwest Wyoming

This article contains an analysis of 16 microstatellite loci from 300 Greater Sage-Grouse individuals to assess genetic structure among populations in Wyoming and southeast Montana.
Date: March 26, 2014
Creator: Schulwitz, Sarah; Bedrosian, Bryan & Johnson, Jeff A.
Object Type: Article
System: The UNT Digital Library
The Cuero Record (Cuero, Tex.), Vol. 120, No. 11, Ed. 1 Wednesday, March 12, 2014 (open access)

The Cuero Record (Cuero, Tex.), Vol. 120, No. 11, Ed. 1 Wednesday, March 12, 2014

Weekly newspaper from Cuero, Texas that includes local, state and national news along with advertising.
Date: March 12, 2014
Creator: Rea, Glenn
Object Type: Newspaper
System: The Portal to Texas History
The Cuero Record (Cuero, Tex.), Vol. 120, No. 22, Ed. 1 Wednesday, June 4, 2014 (open access)

The Cuero Record (Cuero, Tex.), Vol. 120, No. 22, Ed. 1 Wednesday, June 4, 2014

Weekly newspaper from Cuero, Texas that includes local, state and national news along with advertising.
Date: June 4, 2014
Creator: Rea, Glenn
Object Type: Newspaper
System: The Portal to Texas History
Interfacial Characterization of Chemical Vapor Deposition (Cvd) Grown Graphene and Electrodeposited Bismuth on Ruthenium Surface (open access)

Interfacial Characterization of Chemical Vapor Deposition (Cvd) Grown Graphene and Electrodeposited Bismuth on Ruthenium Surface

Graphene receives enormous attention owing to its distinctive physical and chemical prosperities. Growing and transferring graphene to different substrates have been investigated. The graphene growing on the copper substrate has an advantage of low solubility of carbon on the copper which allow us to grow mostly monolayer graphene. Graphene sheet of few centimeters can be transferred to 300nm silicon oxide and quartz crystal pre-deposited with metal like Cu and Ru. Characterization of the graphene has been done with Raman and contact angle measurement and recently quartz crystal microbalance (QCM) has been employed. The underpotential deposition (UPD) process of Bi on Ru metal surface is studied using electrochemical quartz crystal microbalance (EQCM) and XPS techniques. Both Bi UPD and Bi bulk deposition are clearly observed on Ru in 1mM Bi (NO3)3/0.5M H2SO4. Bi monolayer coverage calculated from mass (MLMass) and from charge (MLCharge) were compared with respect to the potential scanning rates, anions and ambient controls. EQCM results indicate that Bi UPD on Ru is mostly scan rate independent but exhibits interesting difference at the slower scan. Bi UPD monolayer coverage calculated from cathodic frequency change (ΔfCathodic) is significantly smaller than the monolayer coverage derived from integrated charge under the cathodic …
Date: May 2014
Creator: Abdelghani, Jafar
Object Type: Thesis or Dissertation
System: The UNT Digital Library