RECYCLE OF UO$sub 2$F$sub 2$ IN THE FLUOROX PROCESS: REACTION OF UO$sub 2$F$sub 2$ WITH HYDROGEN (open access)

RECYCLE OF UO$sub 2$F$sub 2$ IN THE FLUOROX PROCESS: REACTION OF UO$sub 2$F$sub 2$ WITH HYDROGEN

The reaction of U0/sub 2/F/sub 2/ with hydrogen at 700 to 850 deg C was briefly investigated since it could constitute a major step in the recycle of U0/ sub 2/F/sub 2/ in the Fluorox process. The reaction in this temperature range proceeds according to the equation U0/sub 2/F/sub 2/ + H/sub 2/ yields U0/sub 2/ + 2 HF. Rates of the chemical reaction were not obtsined, since, with the thermogravimetric technique used, the rate-controlling process was bed diffusion. However, there is no doubt that the rate of chemical reaction is sufficiently high for the desired application. No significant amount of UF/sub 4/ was formed by the back-reaction, U0/sub 2/ + 4 HF yields UF/sub 4/ + 2 H/sub 2/0. (auth)
Date: July 1, 1959
Creator: Ferris, L.M. & Gardner, R.P.
System: The UNT Digital Library
THE HGCR-1, A DESIGN STUDY OF A NUCLEAR POWER STATION EMPLOYING A HIGH- TEMPERATURE GAS-COOLED REACTOR WITH GRAPHITE-UO$sub 2$ FUEL ELEMENTS (open access)

THE HGCR-1, A DESIGN STUDY OF A NUCLEAR POWER STATION EMPLOYING A HIGH- TEMPERATURE GAS-COOLED REACTOR WITH GRAPHITE-UO$sub 2$ FUEL ELEMENTS

The preliminary design of a 3095-Mw(thermal), helium-cooled, graphite- moderated reactor employing sign conditions, 1500 deg F reactor outlet gas would be circulated to eight steam generators to produce 1050 deg F, 1450-psi steam which would be converted to electrical power in eight 157-Mw(electrical) turbine- generators. The over-all efficiency of this nuclear power station is 36.5%. The significant activities released from the unclad graphite-UO/sub 2/ fuel appear to be less than 0.2% of those produced and would be equivalent to 0.002 curie/ cm/ sup 3/ in the primary helium circuit. The maintenance problems associated with this contamination level are discussed. A cost analysis indicates that the capital cost of this nuclear station per electrical kilowatt would be around 0, and that the production cost of electrical power would be 7.8 mills/kwhr. (auth)
Date: July 28, 1959
Creator: Cottrell, W. B.; Copenhaver, C. M.; Culver, H. N.; Fontana, M. H.; Kelleghan, V. J. & Samuels, G.
System: The UNT Digital Library