Polk County Enterprise (Livingston, Tex.), Vol. 130, No. 74, Ed. 1 Sunday, September 30, 2012 (open access)

Polk County Enterprise (Livingston, Tex.), Vol. 130, No. 74, Ed. 1 Sunday, September 30, 2012

Semi-weekly newspaper from Livingston, Texas that includes local, state and national news along with advertising.
Date: September 30, 2012
Creator: Reddell, Valerie
Object Type: Newspaper
System: The Portal to Texas History
Impact of Contaminants Present in Coal-Biomass Derived Synthesis Gas on Water-gas Shift and Fischer-Tropsch Synthesis Catalysts (open access)

Impact of Contaminants Present in Coal-Biomass Derived Synthesis Gas on Water-gas Shift and Fischer-Tropsch Synthesis Catalysts

Co-gasification of biomass and coal in large-scale, Integrated Gasification Combined Cycle (IGCC) plants increases the efficiency and reduces the environmental impact of making synthesis gas ("syngas") that can be used in Coal-Biomass-to-Liquids (CBTL) processes for producing transportation fuels. However, the water-gas shift (WGS) and Fischer-Tropsch synthesis (FTS) catalysts used in these processes may be poisoned by multiple contaminants found in coal-biomass derived syngas; sulfur species, trace toxic metals, halides, nitrogen species, the vapors of alkali metals and their salts (e.g., KCl and NaCl), ammonia, and phosphorous. Thus, it is essential to develop a fundamental understanding of poisoning/inhibition mechanisms before investing in the development of any costly mitigation technologies. We therefore investigated the impact of potential contaminants (H{sub 2}S, NH{sub 3}, HCN, AsH{sub 3}, PH{sub 3}, HCl, NaCl, KCl, AS{sub 3}, NH{sub 4}NO{sub 3}, NH{sub 4}OH, KNO{sub 3}, HBr, HF, and HNO{sub 3}) on the performance and lifetime of commercially available and generic (prepared in-house) WGS and FT catalysts; ferrochrome-based high-temperature WGS catalyst (HT-WGS, Shiftmax 120™, Süd-Chemie), low-temperature Cu/ZnO-based WGS catalyst (LT-WGS, Shiftmax 230™, Süd-Chemie), and iron- and cobalt-based Fischer-Trospch synthesis catalysts (Fe-FT & Co-FT, UK-CAER). In this project, TDA Research, Inc. collaborated with a team at the University of Kentucky …
Date: September 30, 2012
Creator: Alptekin, Gokhan
Object Type: Report
System: The UNT Digital Library
Mineral Wells Index (Mineral Wells, Tex.), Vol. 113, No. 105, Ed. 1 Sunday, September 30, 2012 (open access)

Mineral Wells Index (Mineral Wells, Tex.), Vol. 113, No. 105, Ed. 1 Sunday, September 30, 2012

Dailly newspaper from Mineral Wells, Texas that includes local, state and national news along with advertising.
Date: September 30, 2012
Creator: May, David
Object Type: Newspaper
System: The Portal to Texas History
Design Concepts for Co-Production of Power, Fuels & Chemicals Via Coal/Biomass Mixtures (open access)

Design Concepts for Co-Production of Power, Fuels & Chemicals Via Coal/Biomass Mixtures

The overall goal of the program is to develop design concepts, incorporating advanced technologies in areas such as oxygen production, feed systems, gas cleanup, component separations and gas turbines, for integrated and economically viable coal and biomass fed gasification facilities equipped with carbon capture and storage for the following scenarios: (i) coproduction of power along with hydrogen, (ii) coproduction of power along with fuels, (iii) coproduction of power along with petrochemicals, and (iv) coproduction of power along with agricultural chemicals. To achieve this goal, specifically the following objectives are met in this proposed project: (i) identify advanced technology options and innovative preliminary design concepts that synergistically integrate plant subsections, (ii) develop steady state system simulations to predict plant efficiency and environmental signature, (iii) develop plant cost estimates by capacity factoring major subsystems or by major equipment items where required, and then capital, operating and maintenance cost estimates, and (iv) perform techno- economic analyses for the above described coproduction facilities. Thermal efficiencies for the electricity only cases with 90% carbon capture are 38.26% and 36.76% (HHV basis) with the bituminous and the lignite feedstocks respectively. For the coproduction cases (where 50% of the energy exported is in the form of electricity), …
Date: September 30, 2012
Creator: Rao, A. D.; Chen, Q. & Samuelsen, G. S.
Object Type: Report
System: The UNT Digital Library