Two short (4 and 6 days) recording periods at The Geysers geothermal field provided useful data on two large refraction explosions and numerous microearthquakes. The vapor-dominated reservoir appears to be characterized by regionally anomalous high P- and S-wave velocities and low attenuation, but the anomaly seems to decrease, possibly reversing, with depth. Microearthquakes occur in a diffuse pattern, with no indication of dominant throughgoing faults and an absence of activity in the main production zone. Mechanisms are generally consistent with NE-SW compression. Occurrence rates indicate a slightly high incidence of smaller magnitude shocks. It is possible that the microearthquake activity is related to an expanding steam zone. While the present anomalies appear to delineate the reservoir, it is not certain that they would have been detectable in an exploration mode, prior to large-scale exploitation of the field.

Various thermodynamic properties are considered for very high-valence 3-2 and 4-2 electrolytes in water at room temperature. These solutions show the behavior described by Davies in which ion pairing arises as the concentration increases follow by re-dissociation at still higher concentrations. Heat of dilution data, which extend below 10{sup -4} M, are interpreted with the same form of equation used earlier for 2-2 electrolytes. Activity and osmotic coefficient data do not extend to low enough concentration for independent, interpretation, but they are treated with the aid of conductance data in the more dilute range. Parameters are reported for A{ell}{sub 2}(SO{sub 4}){sub 3}, La{sub 2}(SO{sub 4}){sub 3}, In{sub 2}(SO{sub 4}){sub 3}, and several cyanoferrates. High-valence electrolytes show a special behavior at very low concentrations which was recognized by Bjerrum who showed in 1926 that purely electrostatic forces would yield an ion association. Davies showed that this association commonly reached a maximum at an intermediate concentration above which there was a re-dissociation. From one viewpoint, this ion association is an artifact of the linearization approximation in the Debye-Hueckel theory since a more exact statistical treatment yields agreement with experiment without assuming a separate associated species. If an association equilibrium is assumed for …